全文获取类型
收费全文 | 875篇 |
免费 | 35篇 |
国内免费 | 1篇 |
专业分类
化学 | 566篇 |
力学 | 24篇 |
数学 | 160篇 |
物理学 | 161篇 |
出版年
2023年 | 12篇 |
2022年 | 9篇 |
2021年 | 5篇 |
2020年 | 11篇 |
2019年 | 7篇 |
2018年 | 11篇 |
2017年 | 16篇 |
2016年 | 30篇 |
2015年 | 24篇 |
2014年 | 24篇 |
2013年 | 54篇 |
2012年 | 58篇 |
2011年 | 62篇 |
2010年 | 44篇 |
2009年 | 37篇 |
2008年 | 46篇 |
2007年 | 52篇 |
2006年 | 45篇 |
2005年 | 41篇 |
2004年 | 38篇 |
2003年 | 45篇 |
2002年 | 18篇 |
2001年 | 18篇 |
2000年 | 10篇 |
1999年 | 9篇 |
1998年 | 11篇 |
1997年 | 5篇 |
1996年 | 14篇 |
1995年 | 8篇 |
1994年 | 13篇 |
1993年 | 9篇 |
1992年 | 7篇 |
1991年 | 8篇 |
1990年 | 5篇 |
1989年 | 5篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1985年 | 9篇 |
1984年 | 4篇 |
1983年 | 8篇 |
1981年 | 9篇 |
1980年 | 3篇 |
1979年 | 5篇 |
1976年 | 4篇 |
1969年 | 3篇 |
1968年 | 3篇 |
1957年 | 3篇 |
1956年 | 3篇 |
1925年 | 2篇 |
1924年 | 2篇 |
排序方式: 共有911条查询结果,搜索用时 16 毫秒
1.
2.
We determine the stationary two-point correlation function of the one-dimensional KPZ equation through the scaling limit of a solvable microscopic model, the polynuclear growth model. The equivalence to a directed polymer problem with specific boundary conditions allows one to express the corresponding scaling function in terms of the solution to a Riemann–Hilbert problem related to the Painlevé II equation. We solve these equations numerically with very high precision and compare our, up to numerical rounding exact, result with the prediction of Colaiori and Moore(1) obtained from the mode coupling approximation. 相似文献
3.
4.
The purpose of this paper is to establish universality of the fluctuations of the largest eigenvalue for some non-necessarily
Gaussian complex Deformed Wigner Ensembles. The real model is also considered. Our approach is close to the one used by A.
Soshnikov (cf. [11]) in the investigations of classical real or complex Wigner Ensembles. It is based on the computation of
moments of traces of high powers of the random matrices under consideration. 相似文献
5.
6.
Akutsu H Akutsu-Sato A Turner SS Le Pevelen D Day P Laukhin V Klehe AK Singleton J Tocher DA Probert MR Howard JA 《Journal of the American Chemical Society》2002,124(42):12430-12431
Normal state conductivity and superconductivity together with bulk magnetic susceptibility and magnetization measurements have been measured for two molecular charge-transfer salts: beta' '-(ET)4[(H3O)Ga(C2O4)3]G (ET = bis(ethylenedithio)tetrathiafulvalene, G = pyridine for compound I and nitrobenzene for compound II). With the exception of the included guest molecules (G) the crystal structures are almost identical. Both show minima in their electrical transport at 130 K for I and at 160 K for II, but at lower temperatures their behaviors differ markedly. The resistance of I reaches a maximum at 50 K with a further small peak at 2 K and possible superconductivity only below 2 K, whereas that of II increases continuously down to 7.5 K, where an abrupt transition to a superconducting state occurs. 相似文献
7.
A comparison of different nebulisers for direct hyphenation of capillary and nano liquid chromatography (Cap-LC, Nano-LC) and quadrupole-based collision cell inductively coupled plasma mass spectrometry (CC-ICP–MS) for phosphorylation profiling of tryptic protein digests is described. Helium was used as cell gas and specially tuned instrumental conditions were used to achieve background minimisation at the mass of phosphorus, because of kinetic energy discrimination of the interfering polyatomic ions. The proposed set-up is based on a modified capillary electrophoresis interface and a home-made 4 mL spray chamber. It enables the use of gradient conditions with a highly concentrated organic mobile phase as often used in protein phosphorylation analysis, without the need to apply membrane desolvation for removal of the organic phase or further background minimisation. No significant signal suppression or other negative effects caused by the organic mobile phase occur, because of the low flow rates used in Cap-LC and the robust plasma conditions of the CC-ICP–MS instrument. A tryptic digest of beta-casein was investigated as model compound to demonstrate the applicability of the proposed set-up for phosphorylation profiling in protein analysis using quadrupole based collision-cell ICP–MS as phosphorus-specific detector. Detection limits for phosphorylated peptides down to the sub picomole level were obtained. As a complementary technique, electrospray ionisation tandem mass spectrometry (ESI–MS–MS) with data base searching was used for further characterisation of the phosphorylated peptides detected. 相似文献
8.
Dieter Seebach Laurent Schaeffer Franois Gessier Pascal Bindschdler Corinna Jger Delphine Josien Sascha Kopp Grald Lelais YogeshR. Mahajan Peter Micuch Radovan Sebesta BerndW. Schweizer 《Helvetica chimica acta》2003,86(6):1852-1861
Multigram amounts of suitably protected β2‐amino acids with 17 of the 20 proteinogenic side chains are prepared by diastereoselective reactions of Li, B, or Ti enolates of the corresponding 3‐acyl‐4‐isopropyl‐5,5‐diphenyloxazolidin‐2‐ones (acyl‐DIOZ; 1 ) with appropriate electrophiles (amidomethylation, hydroxyalkylation, (benzyloxycarbonyl)methylation) in yields of 55–90% and with diastereoselectivities of 80 to >97% (Scheme). The primary products 2 – 8 thus obtained are converted to protected β2‐amino acids by standard procedures (Table 1). Many of the DIOZ derivatives are highly crystalline compounds (31 X‐ray crystal structures in Table 2). The chiral auxiliary DIOZ, readily prepared in either enantiomeric form, is recovered with high yield. 相似文献
9.
[reaction: see text] A simple procedure for the cleavage of triethylsilyl (TES) ethers in the presence of 10 wt % Pd/C in methanol or 95% ethanol is reported. This method allows selective removal of alkyl TES ethers in the presence of aromatic TES ethers or tert-butyldimethylsilyl (TBS) protecting groups. 相似文献
10.
The origin of radiative background in GD-OES is discussed, in connection with the problem of multi-matrix measurements in depth profile analysis. Backed by some experimental evidence in the form of line scans, it is argued that line emission from sample material and the plasma gas (Ar) make up the dominating contributions to the radiative background. The contribution from Ar, in this work termed Matrix-independent Background (MIB), is investigated in more detail. It is shown that, at constant voltage and current, the Ar emission intensity is nearly constant and independent of the pressure, but somewhat matrix-dependent. It is suggested that the MIB can be expressed as a linear function of the intensity of an Ar reference line. This idea is tested experimentally by making intensity measurements on a large set of calibration standards of varying composition. The results are fitted to a calibration function which allows optional definitions of the MIB. It is shown that with a MIB defined as a linear function of the Ar intensity, the different contributions to the spectral background can be more accurately determined than with the MIB defined as a constant. 相似文献