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1.
Zusammenfassung Durch elektrolytische Oxydation einer Bi-Anode in gesättigter NaCl-Lösung können Bi3+-Ionen in Lösung gebracht werden. Dieser Prozeß ermöglicht die coulometrische Bestimmung anwesender Anionen, die schwerlösliche Bi-Verbindungen bilden.Es wurden Semimikro- und Mikrobestimmungen von Phosphationen durch elektrolytisch erzeugte Bi3+-Ionen bei konstanter Stromstärke ausgeführt. Die Endpunktbestimmung erfolgte amperometrisch bei konstantem Potential mit einer Indikatorelektrode — tropfende Quecksilberelektrode — und mit einer gesättigten Kalomelelektrode als Bezugselektrode. Die coulometrische Wismutometrie bietet eine weitere Möglichkeit der coulometrischen Eichung volumetrischer Lösungen im Sinne des seinerzeitigen Vorschlags vonTutundi.
Vorgetragen beim Symposium für analytische Chemie in Graz, 29. September bis 1. Oktober 1965.
Wir danken Herrn Dipl.-Ing.Vladimir Pantovi für seine Hilfe bei unserer experimentellen Arbeit. 相似文献
Summary Bi3+ ions can be brought into solution through electrolytic oxidation of a Bi-anode in saturated NaCl solution. This process makes possible the coulometric determination of the anions present that yield difficulty soluble bismuth compounds.Semimicro- and micro-determinations of phosphate ions were made via Bi3+-ions produced electrolytically at constant current strength. The endpoint was determined amperometrically at constant potential with an indicator electrode-dropping mercury electrode-and with a saturated calomel electrode as reference electrode. The coulometric bismuthometry affords a further possibility of the coulometric standardization of volumetric solutions in the sense of the proposal previously advanced byTutundi.
Résumé On peut utiliser les ions Bi3+ en solution par oxydation électrolytique d'une anode en bismuth, en solution de chlorure de sodium saturée. Ce procédé permet le dosage coulométrique des anions présents qui forment des composés peu solubles avec le bismuth.On a mis au point le dosage semimicro et micro des ions phosphates par les ions Bi3+ formés électrolytiquement sous intensité constante. On détermine par ampérométrie le point équivalent à potentiel constant à l'aide d'une électrode indicatrice — électrode de mercure à goutte pendante —et avec une électrode au calomel saturée comme électrode de référence. La «bismuthométrie» coulométrique offre de grandes possibilités pour l'étalonnage coulométrique de solutions volumétriques, suivant l'idée queTutundi a émise en son temps.
Vorgetragen beim Symposium für analytische Chemie in Graz, 29. September bis 1. Oktober 1965.
Wir danken Herrn Dipl.-Ing.Vladimir Pantovi für seine Hilfe bei unserer experimentellen Arbeit. 相似文献
2.
On the Harary index for the characterization of chemical graphs 总被引:1,自引:0,他引:1
3.
The construction of the Z-counting polynomial for edge-weighted graphs is discussed.Dedicated to Professor Haruo Hosoya (Tokyo) on the occasion of his 55th birthday for enriching chemical graph theory with the elegant concept of the Z-counting polynomial. 相似文献
4.
Zhu Y Nikolic D Van Breemen RB Silverman RB 《Journal of the American Chemical Society》2005,127(3):858-868
Nitric oxide synthases (NOS) are hemoproteins that catalyze the reaction of L-arginine to L-citrulline and nitric oxide. N-(3-(Aminomethyl)benzyl)acetamidine (1400W) was reported to be a slow, tight-binding, and highly selective inhibitor of iNOS in vitro and in vivo. Previous mechanistic studies reported that 1400W was recovered quantitatively after iNOS fully lost its activity and modification to iNOS was not detected. Here, it is shown that 1400W is a time-, concentration-, and NADPH-dependent irreversible inactivator of iNOS. HPLC-electrospray mass spectrometric analysis of the incubation mixture of iNOS with 1400W shows both loss of heme cofactor and formation of biliverdin, as was previously observed for iNOS inactivation by another amidine-containing compound, N5-(1-iminoethyl)-L-ornithine (L-NIO). The amount of biliverdin produced corresponds to the amount of heme lost by 1400W inactivation of iNOS. A convenient MS/MS-HPLC methodology was developed to identify the trace amount of biliverdin produced by inactivation of iNOS with either 1400W or L-NIO to be biliverdin IXalpha out of the four possible regioisomers. Two mechanisms were previously proposed for iNOS inactivation by L-NIO: (1) uncoupling of the heme peroxide intermediate, leading to destruction of the heme to biliverdin; (2) abstraction of a hydrogen atom from the amidine methyl group followed by attachment to the heme cofactor, which causes the enzyme to catalyze the heme oxygenase reaction. The second mechanistic proposal was ruled out by inactivation of iNOS with d3-1400W, which produced no d2-1400W. Detection of carbon monoxide as one of the heme-degradation products further excludes the covalent heme adduct mechanism. On the basis of these results, a third mechanism is proposed in which the amidine inactivators of iNOS bind as does substrate L-arginine, but because of the amidine methyl group, the heme peroxy intermediate cannot be protonated, thereby preventing its conversion to the heme oxo intermediate. This leads to a change in the enzyme mechanism to one that resembles that of heme oxygenase, an enzyme known to convert heme to biliverdin IXalpha. This appears to be the first example of a compound that causes irreversible inactivation of an enzyme without itself becoming modified in any way. 相似文献
5.
6.
Djordje Vlaović Gordana Ćetković Ivan Juranić Jelica Balaž Stevan Lajšić Dejan Djoković 《Monatshefte für Chemie / Chemical Monthly》1990,121(11):931-939
Summary The syntheses andin vitro antibacterial and antifungal evaluation of certain (5-nitro-2-furyl)azomethines with different heterocyclic nuclei are described.
Die Anwendung von Lävulinsäure und 5-Nitro-2-furylmethylendiacetat in der Totalsynthese einiger neuer biologisch aktiver (5-Nitro-2-furyl)azomethine
Zusammenfassung Es wird die Synthese und diein-vitro-antibakterielle und antifungale Wirksamkeit für bestimmte (5-Nitro-2-furyl)azomethine mit verschiedenen heterocyclischen Kernen beschrieben.相似文献
7.
Milena Jelikić-Stankov Dejan Stankov Dušan Malešev Zorica Radović 《Mikrochimica acta》1991,103(1-2):65-70
By means of spectroscopic methods it has been found that demeclocycline reacts with molybdate ions forming a complex compound [MoO3HDMTC]2–. The relative stability constant of this compound has been determined by applying spectrophotometric methods. Under optimum conditions for complex formation a very sensitive spectrophotometric method for the estimation of demeclocycline in the concentration range 5.0–35.1 g/ml is proposed. The detection limit of the method is 2.5 g/ml of demeclocycline. The relative standard deviation (n=10) varies between 0.76% and 1.46%. The method proved to be accurate and sensitive for the analysis of the demeclocycline content in tablets. 相似文献
8.
Dr. Dongpeng Yan Dr. Dejan‐Krešimir Bučar Dr. Amit Delori Bhavnita Patel Dr. Gareth O. Lloyd Prof. William Jones Prof. Xue Duan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(25):8213-8219
Multi‐component organic nanocrystals that are comprised of two or more supramolecular building blocks can be used to extend the design and assembly scope of solid molecular materials. Herein, we report the use of ultrasonication to prepare halogen‐bonded stilbene‐based nano‐cocrystals that exhibit different photoemission properties, including one‐ and two‐phonon emission and fluorescence lifetimes, relative to those of macrodimensional crystals. The structural transformation from nano‐cocrystals into nanocrystals upon heating results in a luminescence red‐shift from greenish blue to yellow. The temperature‐dependent ratiometric luminescence may allow such nano‐cocrystals to be used as fluorescent sensors and thermosensitive materials. 相似文献
9.
We study well-posedness of a class of nonlocal interaction equations with spatially dependent mobility. We also allow for the presence of boundaries and external potentials. Such systems lead to the study of nonlocal interaction equations on subsets ? of ? d endowed with a Riemannian metric g. We obtain conditions, relating the interaction potential and the geometry, which imply existence, uniqueness and stability of solutions. We study the equations in the setting of gradient flows in the space of probability measures on ? endowed with Riemannian 2-Wasserstein metric. 相似文献