排序方式: 共有22条查询结果,搜索用时 15 毫秒
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Sanford TW Allshouse GO Marder BM Nash TJ Mock RC Spielman RB Seamen JF McGurn JS Jobe D Gilliland TL Vargas M Struve KW Stygar WA Douglas MR Matzen MK Hammer JH De Groot JS Eddleman JL Peterson DL Mosher D Whitney KG Thornhill JW Pulsifer PE Apruzese JP Maron Y 《Physical review letters》1996,77(25):5063-5066
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[structures: see text] The total syntheses of the amaryllidaceae alkaloids haemanthidine, pretazettine, and tazettine as optically pure enantiomers are reported. Using D-mannose as the starting material, the critical relative stereochemical relationships are established with an intramolecular nitrone-alkene cycloaddition reaction. The synthetic route leads successively to (-)-haemanthidine and then to (+)-pretazettine and (+)-tazettine, taking advantage of the well-established complex relationships among these three alkaloids. 相似文献
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[structure: see text] A new series of ligands with a novel phosphine-aminophosphine ligation design as depicted in structure 1 has been prepared on a ferrocenylethyl backbone. These BoPhoz ligands of structure 2 have afforded exceedingly high activity and enantioselectivity in the rhodium-catalyzed asymmetric hydrogenation of dehydro-alpha-amino acid derivatives, itaconic acids, and alpha-ketoesters. These air-stable ligands are readily prepared from cost-effective and non-pyrophoric intermediates. 相似文献
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An integral equation formulation for buoyancy-driven convection problems is developed and illustrated. Buoyancy-driven convection in a bounded cylindrical geometry with a free surface is studied for a range of aspect ratios and Nusselt numbers. The critical Rayleigh number, the nature of the cellular motion, and the heat transfer enhancement are computed using linear theory. Green's functions are used to convert the linear problem into linear Fredholm integral equations. Theorems are proved which establish the properties of the eigenvalues and eigenfunctions of the linear integral operator which appears in these equations. 相似文献
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H. Karami J. Carr N.C. Debenham D.A. Garbutt W.G. Jones D.M. Binnie J. Keyne P. Moissidis H.N. Sarma I. Siotis 《Nuclear Physics B》1979,154(3):503-518
Measurements are reported of the differential cross section for the reaction π?+p→ω+n from threshold to a final-state c.m. momentum . The previously reported fall in total cross section below about 100 MeV/c is again seen. The differential cross section remains close to isotropic over the entire range. A paralle experiment on the variation in the elastic differential cross section across the threshold shows evidence of this threshold. The elastic data cover a range of incident moments from 1010 to 1180 MeV/c in steps of 5 MeV/c. 相似文献
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A. Ertoprak B. Cederwall C. Qi M. Doncel U. Jakobsson B. M. Nyakó G. Jaworski P. Davies G. de France I. Kuti D. R. Napoli R. Wadsworth S. S. Ghugre R. Raut B. Akkus H. Al Azri A. Algora G. de Angelis A. Atac T. Bäck A. Boso E. Clément D. M. Debenham Zs. Dombrádi S. Ertürk A. Gadea F. Ghazi Moradi A. Gottardo T. Hüyük E. Ideguchi H. Li C. Michelagnoli V. Modamio J. Nyberg M. Palacz C. M. Petrache F. Recchia M. Sandzelius M. Siciliano J. Timár J. J. Valiente-Dobón Z. G. Xiao 《The European Physical Journal A - Hadrons and Nuclei》2018,54(9):145
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Fernández P Durand JS Pérez-Conde C Paniagua G 《Analytical and bioanalytical chemistry》2003,375(8):1020-1023
This paper reports a new flow-through fluoroimmunosensor, the function of which is based on antibodies immobilized on an inmunoreactor of controlled-pore glass (CPG), for determination of digoxin, used in the treatment of congestive heart failure and artery disease. The immunosensor has a detection limit of 1.20 microg L(-1) and provides high reproducibility (RSD=4.5% for a concentration of 0.0025 mg L(-1), and RSD=6.7% for 0.01 mg L(-1)). The optimum working concentration range was found to be 1.2 x 10(-3)-4.0 x 10(-2) mg L(-1). The lifetime of the immunosensor was about 50 immunoassays; if stored unused its lifetime can be extended to three months. A sample speed of about 10-12 samples per hour can be attained. Possible interference from substances with structures similar to digoxin (morphine, heroin, tebaine, codeine, pentazocine and narcotine) was investigated. No cross-reactivity was seen at the highest digoxin: interferent ratio studied (1:100). The proposed fluoroimmunosensor was successfully used to determine digoxin concentrations in human serum samples. 相似文献