全文获取类型
收费全文 | 1589篇 |
免费 | 65篇 |
国内免费 | 4篇 |
专业分类
化学 | 1020篇 |
晶体学 | 9篇 |
力学 | 60篇 |
数学 | 244篇 |
物理学 | 325篇 |
出版年
2024年 | 6篇 |
2023年 | 14篇 |
2022年 | 38篇 |
2021年 | 59篇 |
2020年 | 47篇 |
2019年 | 35篇 |
2018年 | 33篇 |
2017年 | 25篇 |
2016年 | 79篇 |
2015年 | 52篇 |
2014年 | 48篇 |
2013年 | 88篇 |
2012年 | 118篇 |
2011年 | 143篇 |
2010年 | 64篇 |
2009年 | 58篇 |
2008年 | 70篇 |
2007年 | 90篇 |
2006年 | 77篇 |
2005年 | 84篇 |
2004年 | 56篇 |
2003年 | 56篇 |
2002年 | 38篇 |
2001年 | 15篇 |
2000年 | 22篇 |
1999年 | 7篇 |
1998年 | 10篇 |
1997年 | 8篇 |
1996年 | 20篇 |
1995年 | 15篇 |
1994年 | 11篇 |
1993年 | 9篇 |
1992年 | 8篇 |
1991年 | 12篇 |
1990年 | 11篇 |
1989年 | 9篇 |
1988年 | 7篇 |
1986年 | 6篇 |
1985年 | 9篇 |
1984年 | 5篇 |
1983年 | 6篇 |
1982年 | 6篇 |
1981年 | 9篇 |
1980年 | 8篇 |
1978年 | 4篇 |
1977年 | 5篇 |
1974年 | 5篇 |
1973年 | 3篇 |
1966年 | 3篇 |
1934年 | 6篇 |
排序方式: 共有1658条查询结果,搜索用时 15 毫秒
1.
R. Pizzoferrato L. Lagonigro T. Ziller A. Di Carlo R. Paolesse F. Mandoj A. Ricci C. Lo Sterzo 《Chemical physics》2004,300(1-3):217-225
We study the infrared emission at 1.54 μm of an organolanthanide complex, Er(III)-tetraphenylporphyrin [Er(TPP)acac], both as a result of direct optical excitation and via energy transfer from host π-conjugate polymers of type poly(arylene–ethynylene) [PAE]. In the first case, the emission of the neat complex is characterized in inert transparent materials and a value of the quantum yield at 1.54 μm φIR=4×10−4 is measured. Then, fluorescence resonance transfer is investigated in blends of Er(TPP)acac with PAEs by monitoring the quenching of the polymer fluorescence along with the enhancement of both the visible emission of the ligand and the near-infrared band of Er3+. These different procedures allow a detailed analysis of the transfer efficiency within a specific implementation of the Förster model for polymeric donors. The experimental values of the critical radius R0, ranging from 1.3 to 2.5 nm for the different blends, are in good agreement with theory for a wide interval of the physical and spectroscopic parameters. This suggests that other mechanisms for excitation transfer do not play a significant role in these materials. 相似文献
2.
Some nickel, copper, and silver salts or complexes are efficient catalysts for the oxidation of benzylic ethers with oxygen in 1,2-dimethoxyethane. Salts of the weakly coordinating anion trifluoroacetate are particularly efficient, approaching (and, in some cases, improving) the yields obtained with cobalt(II) chloride, the best catalyst so far reported. 相似文献
3.
D. Guidotti J. G. Wilman A. J. Ricci 《Applied Physics A: Materials Science & Processing》1992,54(6):570-573
An instrument is described that can be used to monitor, with unprecedented sensitivity, changes in the optical reflectivity due to crystailine damage incurred during ion implantation. It is shown that at the shot-noise limit, changes in the optical reflectivity of silicon as small as 5·10–7 can be measured in a 10 Hz bandwidth with a signal-to-noise ratio of 100, corresponding to an extrapolated uniform implantation dose of 5·108 cm–2 for 11B+ at 50 keV in silicon. 相似文献
4.
Giovanni Tartarini Alessandra Lena Davide Passaro Lorenzo Rosa Stefano Selleri Pier Faccin Enrico Maria Fabbri 《Optical and Quantum Electronics》2006,38(9-11):869-876
A comprehensive numerical tool has been developed for the evaluation of the performances of Radio over Fiber (RoF) links intended for wireless signal distribution.At the transmitter end an appropriate set of rate equations allows to model the optical source as a solitary laser or as an appropriately injection locked laser. The optical channel is modeled putting into account the combined effect of fiber dispersion, laser source non ideal performances (e.g. non-linear effects, frequency chirp), and quadratic detection of the receiving photodiode. The simulation model developed can be a useful tool at the design stage allowing a preliminary evaluation of the characteristics of real RoF links. 相似文献
5.
Davide Guzzetti 《纯数学与应用数学通讯》2002,55(10):1280-1363
6.
J. Walz S. B. Ross C. Zimmermann L. Ricci M. Prevedelli T. W. Hänsch 《Hyperfine Interactions》1996,100(1):133-144
Experiments with electrons and ions in a combined trap are reported. The unique capability to confine particles with opposite charge and very different mass simultaneously in the same spatial region makes the combined trap a promising device for future synthesis of antihydrogen. 相似文献
7.
P. Boccaccio L. Vannucci R.A. Ricci G. Vannini R. Dona I. Massa J.P. Coffin P. Fintz G. Guillaume F. Jundt F. Rami P. Wagner 《The European Physical Journal A - Hadrons and Nuclei》1998,1(4):399-406
We studied the sequential binary decay of the systems 32S+45Sc, 76Ge, 89Y, 59Co, 63Cu and 19F+63Cu induced by collisions at ≃6 MeV·A. The two stages of the process have reaction-times compatible with the dynamics of different mechanisms. The study of the
excitation energy partition shows that the reaction mechanism of the first step has influence on the de-excitation of the
primary fragments producing two decay components which have different time scale.
Received: 25 March 1997 / Revised version: 2 December 1997 相似文献
8.
Andrea Lodi Monica Caselli Alessandro Casnati Fabio Momicchioli Francesco Sansone Davide Vanossi Glauco Ponterini 《Journal of Molecular Structure》2007,846(1-3):49-54
The sulfonated calixarene I8C12 acts as a host for homologous merocyanines Mc1 and Mc2 in organic solvents, exhibiting neither selectivity towards the guest dyes nor solvent dependence of the complexation equilibria. In water, on the contrary, only the lower homologue, Mc1, is solubilized in the presence of the calixarene. A combination of UV–visible and fluorescence spectroscopic and photophysical analysis and MD structural simulation of the calixarene-dye complexes was employed to account for the observations, and suggests that a radical change in the complexation mode occurs upon moving from an organic to an aqueous environment. 相似文献
9.
L. Pistelli C. Noccioli M. Martera L. Giamperi A. Bucchini D. Fraternale D. Ricci 《Chemistry of Natural Compounds》2006,42(3):281-284
Seven flavonol glycosides were isolated and identified from the aerial parts of Dorycnium hirsutum, together with catechin, D-pinitol, β-sitosterol, and stearic acid. The extracts and the isolated flavonol glycosides were
evaluated for their antioxidant activity, using the DPPH test (radical scavenging) and the lipoxygenase assay (lipid peroxidation).
Dedicated to the memory of Prof. I. Morelli.
Published in Khimiya Prirodnykh Soedinenii, No. 3, pp. 233–235, May–June, 2006. 相似文献
10.
Thomas P J Linsinger Alexander Bernreuther Philippe Corbisier Marta Dabrio Håkan Emteborg Andrea Held Andrée Lamberty Gaida Lapitajs Marina Ricci Gert Roebben Stefanie Trapmann Franz Ulberth Hendrik Emons 《Accreditation and quality assurance》2007,12(3-4):167-174
The potential approaches for third-party assessment of reference material producers are revisited and the activities of the
Reference Materials (RM) Unit of the Institute for Reference Materials and Measurements (IRMM) to obtain accreditation to
ISO Guide 34 and ISO 17025 are described. Accreditation was related to the Unit as all matrix RM activities of the institute
are concentrated there. A management system was established that allows sufficient flexibility to be applicable to a wide
range of RMs while being precise enough to ensure compliance with ISO Guides 30, 31 and especially 34 and 35. Accreditation
was achieved in 2004 with independent scopes for testing and RM production and was confirmed and extended in 2005. The key
aspects of the RM Unit's management system for RM production are presented.
Presented at BERM-10, April 2006, Charleston, SC, USA 相似文献