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排序方式: 共有105条查询结果,搜索用时 15 毫秒
1.
Motohiro Mizuno Yoji Aoki Darius Greenidge 《Journal of Physics and Chemistry of Solids》2006,67(4):705-709
The angular dependence of the 27Al NMR spectrum was measured for single crystals of smoky and colorless topaz, Al2SiO4(F,OH)2. Smoky topaz was obtained by irradiating high energy neutrons to colorless topaz. The quadrupole coupling constant e2Qq/h and the asymmetry parameter η were obtained from the analysis of the angular dependences of quadrupole splitting of the 27Al NMR spectrum. The local structures around the aluminum atoms in smoky and colorless topaz were discussed from the magnitude and the direction of the electric field gradient. The directions of principal axes of the EFG tensor of 27Al were close to the directions of Al-O and Al-F bonds. The difference in the bond lengths between Al(1)-F(1) and Al(1)-F(2) was found to affect the x and y components of the EFG tensor. 相似文献
2.
Colette Deschamps-Vallet Jean-Baptiste Ilots Michle Meyer-Dayan Darius Molho 《Journal of heterocyclic chemistry》1982,19(1):97-101
3-Phenyl-1-benzopyrylium percholorates 1a, 1i react exculusively at C-2 with ethanol and isopropyl alcohol, affording mixed acetals 2a, 3a, 3i . Aqueous ammonia gives symmetrical secondary amines 4a, 4b or bis(3-phenyl-2H-1-benzopyran-2-yl)amines, while with aqueous aliphatic amines (40%) bis-acetals 5a, 5b or 2,2′-oxy-bis(3-phenyl-2H-1-benzopyrans) are characterized. In some other acidic conditions, 5a and 5b are also obtained. 相似文献
3.
Mickevicius Saulius Stepsys Augustinas Germanas Darius Kalinauskas Ramutis Kazys 《Physics of Atomic Nuclei》2018,81(6):899-906
In this paper we present an independent scheme for constructing fractional parentage coefficients using symmetry group apparatus in translationally invariantmodel space, suitable for the six-particle system composed of three-particle bi-clusters, where the presented subsystems have their own intrinsic clusterization. Simple expressions for corresponding antisymmetrization procedure are presented as well as computational results.
相似文献4.
Ultrasound velocity measurements in medicine and biology usually are performed using relatively small measurement chambers. When the pulse-echo method is used, the presence of the reflector close to the transducer can cause essential diffraction errors. These errors may be reduced using an additional buffer rod as a waveguide between the transducer and the measurement chamber. The objective of the presented work was analysis of diffraction errors in measurement chambers with a buffer rod. The work was performed in two steps. In the first stage propagation of transient ultrasonic waves in a buffer rod was analysed using an axisymmetric finite element model. This approach enables all dimensions of the measurement chamber and the waveguide to be taken into account, but is less accurate in the time domain. In the second step the absolute values of diffraction errors were evaluated using a mixed analytic-numeric disk shaped transducer diffraction model. In this case only the dimensions of the waveguide and measurement chamber along the wave propagation direction were taken into account. Diffraction errors were calculated by simulating small changes of ultrasound velocity in the liquid under investigation. The simulation performed allowed optimisation of the dimensions of the measurement chamber and a buffer rod thus minimising measurement errors. 相似文献
5.
In the case of ultrasonic measurements in aggressive media piezoelectric elements of ultrasonic transducers are separated from a medium by thick protective layers, which may posses nonparallel front and back surfaces. This enables to reduce significantly the amplitude of multiple reflections, but the structure of the ultrasonic field radiated through a layer with nonparallel boundaries becomes complicated. The main objective of this paper is to present a method suitable for simulation of ultrasonic fields radiated through a layer with nonparallel boundaries in a transient mode. The proposed simulation method is based on the transformation of a multilayered medium into a virtual one without internal boundaries, equivalent to the actual medium from the point of a view of the relative times of arrival of direct and edge waves. The simulated ultrasonic fields in water are compared with the measurement results and a good correspondence between calculated and measured fields is obtained. 相似文献
6.
7.
Darius H. Torchinsky David Hsieh J.L. Luo Nuh Gedik 《Journal of Physics and Chemistry of Solids》2011,72(5):519-522
We report on band-dependent quasiparticle dynamics in the hole-doped Ba-122 pnictides measured by ultrafast pump-probe spectroscopy. In the superconducting state of the optimal and over hole-doped samples, we observe two distinct relaxation processes: a fast component whose decay rate increases linearly with excitation density and a slow component whose relaxation is independent of excitation strength. We argue that these two components reflect the recombination of quasiparticles in the two hole bands through intraband and interband processes. We also find that the thermal recombination rate of quasiparticles increases quadratically with temperature in all samples. The temperature and excitation density dependence of the decays indicates fully gapped hole bands and nodal or very anisotropic electron bands. 相似文献
8.
Björn Bieniek Darius Pohl Ludwig Schultz Bernd Rellinghaus 《Journal of nanoparticle research》2011,13(11):5935-5946
The near-surface oxidation-induced lattice relaxation and compositional changes of FeNi alloy nano-particles are investigated.
Using a newly developed transfer system, the particle structure was characterised by means of aberration-corrected HR-TEM
prior to exposing the particles to ambient air. This allows for a comparison of oxidised and un-oxidised particles, respectively.
Independent of the oxidation, the surface-near and/or interface-near metal lattice was found to be expanded by up to 3%. EELS
profiles clearly reveal an enrichment of Fe at the particle surfaces. MD simulations in combination with HR-TEM contrast simulations
were conducted to investigate the effect of the Fe enrichment on the structural relaxation. The results show that a surface-near
over-stoichiometric enrichment of Fe indeed causes a dilation that counteracts a compression of the lattice at the particle
surface as obtained for homogeneously alloyed particles. Besides, the large lattice mismatch between the metallic cores and
the NiFe2O4 shells causes the formation of step dislocations in the close vicinities of the interface. In essence, the surface-near lattice
relaxation in oxide free particles is found to be due to a segregation of Fe to the surface, whereas in the case of shell–core
particles, no systematic influence of the oxide on the lattice relaxation was found. 相似文献
9.
Darius Virzonis Gailius Vanagas Almira Ramanaviciene Asta Makaraviciute Dovydas Barauskas Arunas Ramanavicius Weijia Wen Rimantas Kodzius 《Mikrochimica acta》2014,181(13-14):1749-1757
High-frequency (40 MHz) and low-frequency (7 MHz) capacitive micromachined ultrasound transducers (CMUT) were fabricated and tested for use in gravimetric detection of biomolecules. The low-frequency CMUT sensors have a gold-coated surface, while the high-frequency sensors have a silicon nitride surface. Both surfaces were functionalized with bovine leukemia virus antigen gp51 acting as the antigen. On addition of an a specific antibody labeled with horseradish peroxidase (HRP), the antigen/antibody complex is formed on the surface and quantified by HRP-catalyzed oxidation of tetramethylbenzidine. It has been found that a considerably smaller quantity of immuno complex is formed on the high frequency sensor surface. In parallel, the loading of the surface of the CMUT was determined via resonance frequency and electromechanical resistance readings. Following the formation of the immuno complexes, the resonance frequencies of the low-frequency and high-frequency sensors decrease by up to 420 and 440 kHz, respectively. Finite element analysis reveals that the loading of the (gold-coated) low frequency sensors is several times larger than that on high frequency sensors. The formation of the protein film with pronounced elasticity and stress on the gold surface case is discussed. We also discuss the adoption of this method for the detection of DNA using a hybridization assay following polymerase chain reaction. Figure
Resonant gravimetric immunosensing with six-channel, 7 MHz capacitive micromachined ultrasound transducer (CMUT). Initial modification by antigen gp51 builds the protein layer with 13.2 GPa elasticity modulus. This increases the resonance frequency of CMUT, which is decreasing after immune complex with antibody is established. 相似文献
10.
Adaptive optimizations performed using a genetic algorithm are employed to construct optimal laser pulse configurations that separate spectroscopic features associated with the two main energy-transfer pathways in the third-order nonlinear optical response simulated for the Fenna-Matthews-Olson (FMO) photosynthetic complex from the green sulfur bacterium Chlorobium tepidum. Superpositions of chirality-induced tensor components in both collinear and noncollinear pulse configurations are analyzed. The optimal signals obtained by manipulating the ratios of various 2D spectral peaks reveal detailed information about the excitation dynamics. 相似文献