Vortices with fractional circulation quantum in superfluid He---A2

Due to the specific discrete symmetry of the superfluid ³He---A₂ order parameter, linear singularities can exist which are characterized by a quarter-integer quantum of superflow velocity circulation. Some consequences of this observation are analyzed.     

Magnetic inelastic scattering of neutrons by a ferromagnetic crystal

This paper deals with a theoretical investigation of the energy spectrum of thermal neutrons inelastically scattered by a ferromagnetic crystal. The method of double-time temperature-dependent Green’s functions is used. Formulæ are derived for the line width and for an asymmetry parameter leading to a deviation from the Lorentzian form. The results are discussed and compar d with earlier work. Special attention is paid to the question of the deviation of the energy distribution from the purely Lorentzian form.     

(TTT)2I3+δ compounds--superconducting fluctuations?

We suggest that the high conductivity observed in non-stoichiometric (TTT)₂I_3+δ samples is a consequence of the suppression of 3D corrections by the incommensurate iodine chains which produce a random potential on the conducting TTT chains. As a result, the TTT chains can act as an array of independent 1D conductors for which it is known that superconducting fluctuations, suppressed in the 3D case, are strong and lead to high conductivity.     

New amino acid based biodegradable poly(ester amide)s via bis-azlactone chemistry

Abstract

Three new classes of the amino acid based biodegradable (AABB) polymers were synthesized via step growth polymerization of bis-azlactones and amino acid based diamine-diesters with activated fatty diester and alkylenediamine: a) poly(ester amide)s (PEAs) were obtained by polymerization of bis-azlactones with diamine-diesters, b) hydrophobically modified co-poly(ester amide)s (co-PEAs) were synthesized by copolymerization of activated fatty diacid diester and bis-azlactones with diamine-diesters, and c) poly(ester amide-co-amide)s (PEA-co-PAs) were obtained by copolymerization of alkylene diamine and diamine-diesters with bis-azlactones. The new poly(ester amide)s showed relatively low-molecular-weights (M_w within 2,800–19,600?Da, GPC in DMF), whereas the new co-poly(ester amide)s and poly(ester amide-co-amide)s exhibited high-molecular-weights (M_w within 40–100?kDa) leading to good mechanical properties. Incorporation of the bis-azlactone fragments into the poly(ester amide)s backbone increased hydrophobicity and thermal stability, whereas incorporation of diamine-diester units into the backbone of the bis-azlactone based polyamides rendered them biodegradable. Synthesized AABB polymers are potential candidates for constructing resorbable surgical and pharmaceutical devices.     

Superfluid properties of magnetized 3He-B in a disordered medium

The influence of nonmagnetic impurity scattering on the anisotropy of the magnetized B phase of superfluid ³He is investigated theoretically. The contribution of the impurity-induced spin-singlet superfluid correlations in the presence of the p-wave Cooper pairing is revealed. Pis’ma Zh. éksp. Teor. Fiz. 63, No. 2, 95–100 (25 January 1996) Published in English in the original Russian journal. Edited by Steve Torstveit.     

New Unsaturated Biodegradable Poly(ester amide)s Composed of Fumaric Acid,L-leucine and α,ω-Alkylene Diols

The synthesis of α-amino acid L-leucine (Leu) based high-molecular-weight and biodegradable unsaturated poly(ester-amide)s (PEAs) was reported. Amino acid L-phenylalanine (Phe) was used to synthesize some copolymers for a comparative study. The syntheses of three types of new unsaturated PEA polymers were explored – (i) Unsaturated PEA homopolymers (UPEAs) composed of fumaric acid, aliphatic diol and one alpha-amino acid: L-Leu or L-Phe; (ii) L-Leu-based unsaturated-saturated copolymers (USPEAs) composed of aliphatic diol, fumaric and saturated fatty diacid, and (iii) L-Leu- and L-Phe-based copolymers (co-UPEAs) composed of 100% fumaric acid, aliphatic diol and combinations of both amino acids. Many of the targeted unsaturated polymers were soluble in common organic solvents and showed good film-forming property. The unsaturated PEA polymers were further chemically modified into functional derivatives and subjected to thermal and photochemical transformations (curing) that substantially expand material properties and, hence, the scopes of potential applications as absorbable surgical devices and drug carriers.     

Superfluidity of 3He in aerogel at T=0 in a magnetic field

The transition of liquid ³He to the superfluid B phase in aerogel at T=0 is considered. It is shown that in a magnetic field, the quantum phase transition with respect to pressure is split in two. The amount of splitting δP is estimated. The components of the superfluid density tensor are calculated near the critical pressures. Zh. éksp. Teor. Fiz. 115, 754–762 (February 1999) Published in English in the original Russian journal. Reproduced here with stylistic changes by the Translation Editor.