S‐Alkylation of Soft Scorpionates

The alkylation reactions of soft scorpionates are reported. The hydrotris(S‐alkyl‐methimazolyl)borate dications (alkyl=methyl, allyl, benzyl), which were prepared by the reaction of Tm^Me anion and primary alkyl halides, have been isolated and structurally characterised. The reaction is, however, not universally successful. DFT analysis of these alkylation reactions (C?S versus B? H alkylation) indicates that the observed outcome is driven by kinetic factors. Extending the study to incorporate alternative imine thiones (mercaptobenzothiazole, bz; thiazoline, tz) led to the structural characterisation of di[aquo‐μ‐aquohydrotris(mercaptobenzothiazolyl)boratosodium], which contains sodium atoms in the κ³‐S,S,S coordination mode. Alkylation of Na[Tbz] and Na[tzTtz] leads to decomposition resulting in the formation of the simple S‐alkylated heterocycles. The analysis of the species involved in these reactions shows an inherent weakness in the B? N bond in soft scorpionates, which has implications for their use in more advanced chemistry.     

Overtone spectroscopy of some benzaldehyde derivatives

Overtone spectrum of o, m and p-nitrobenzaldehydes and p-chlorobenzaldehyde has been studied in 2000–12000 cm⁻¹ region. Vibrational frequencies and anharmonicity constants for aryl as well as alkyl CH stretch vibrations have been determined. We have also determined the internuclear distances for the aryl CH bond in the different molecules. The small variation observed in these distances is an indication of the substitution effect. It is observed that in the case of p-disubstituted benzens, the shift in aryl CH bond is proportional to sum of the Hammet σ of the substituents. However in the case of o-disubstituted benzenes it is only 80% of the para-substituted shift.     

Analyzing adhesion in microstructured systems through a robust computational approach

Analyzing surface forces for myriad geometric structures facilitates the design of properties in interacting interfacial systems. Along these lines, we demonstrate a generalized technique that can be utilized to evaluate the orientation dependence of a particle interacting with multiple finite or semi‐infinite objects. Specifically, the surface element integration technique is modified to account for surface elements of a particle not directly adjacent to the object with which it is interacting; this facilitates the analysis of objects with finite shape and with arbitrary orientations. Furthermore, as a technology‐relevant proof‐of‐concept demonstration, the influence of van der Waals (vdW) forces on the performance and reliability of microstructured systems used for the collection of trace particles is reported. The importance of the location of the particle contact with the microstructure and the independence of vdW forces generated by each microstructure is demonstrated using the developed computational approach. Thus, the methodology presented here can ultimately be utilized for a variety of interfacial forces generated by nontrivial systems with heterogeneous properties in order to provide design motifs in a low‐cost, high‐throughput manner.     

Connecting mem-models with classical theories

A family of mem-models, including the mem-dashpots, mem-springs, and most recently, mem-inerters, is emerging as a new and powerful way of capturing complex nonlinear behaviors of materials and systems under various types of dynamic loads involving different frequency, amplitude, and loading histories (e.g., hysteresis). Under the framework of nonlinear state-space representation and hybrid dynamical systems, mem-springs may be formulated to effectively represent an inherent degradation of material state. It is shown in this study, for the first time, how the absement (time integral of strain/displacement), a signature state variable for a mem-spring, can be connected with the damage variable, a key quantity in continuum damage mechanics. The generalized momentum (time integral of stress), on the other hand, is shown to be efficient in modeling strain ratcheting via the concept of mem-dashpot. It is also shown in this study, for the first time, how two formulations of the memcapacitive system models (for mem-springs) are special cases of the Preisach model.

     

Gauge models with Majorana fields

Restrictions imposed on the construction of gauge models with Majorana fields are discussed. An example is given for a model with right-handed weak currents where lepton number violation is required.     

A gauge model without parity violation in heavy atoms

We address the question: “are weak right-handed non-singlet representations of quarks and leptons necessary?” An extension of the Weinberg-Salam model to SU(2) ? U(1) ? U(1) is found to adequately describe all existing weak interaction data including the lack of parity violation in atomic physics experiments. These data tightly constrain the additional parameters introduced by adding the second weak hypercharge. Although such a model may seem regressive when considered from the standpoint of “simple” unification schemes, we feel that it is aesthetics rather than experiment which leads to non-trivial right-handed multiplet structure. In contrast to most other models, ours predicts a substantial parity-violation effect in atomic experiments on hydrogen. We note that the second weak boson in our model is not constrained to be heavy by existing data and thus might already by accessable in pp → μ⁺μ^?X or possibly in the next generation of colliding beam facilities through e⁺e^? → μ⁺μ^?.     

Arytenoid dislocation

Arytenoid dislocation is a common yet infrequently diagnosed complication of laryngeal trauma. It may result in various symptoms, including permanent dysphonia, although immediate voice change is not always present. Early reduction is the treatment of choice; however, late reduction is often successful in restoring voice. A high index of suspicion based on the history of the patient is necessary to recognize arytenoid dislocation. Thorough physical examination and objective tests are helpful in confirming this diagnosis.     

Detection of faceting on (hk0) surfaces of thin gold films by diffraction in the electron microscope at 100 kV

A series of single crystal thin films of gold with (hk0) surfaces ranging between (100) and (310), grown by vapor deposition, was studied in transmission in the electron microscope at 100 kV. For specimens intermediate between (100) and (310) both bright and dark field images contained line structure running parallel to [001]. In certain cases segments were observed lying at 45° and 90° to these lines. Diffraction patterns from these specimens revealed relrods at each reciprocal lattice point running parallel to [100] and [310]. In certain cases [301] and [301?] relrods were also present. No line structure or relrods were detectable for the specimens with (100) or (310) surfaces. The results are consistent with a model in which the (100) and (310) surfaces are essentially flat but surfaces with intermediate orientations consist of appropriate mixtures of (100) and (310) facets plus (301) and (301?) facets in certain cases. The line structure in the images is attributed to “thickness contrast” arising from variations in the specimen thickness due to the facets. The relrods are well explained by the specimen form factor as originally proposed by von Laue. The results prove that faceted structures on thin film surfaces can be conveniently and systematically studied under certain conditions by conventional transmission electron microscopy at 100 kV.