关于开设内光电效应实验的探索与思考

介绍了开设以内光电效应为理论基础的半导体光电器件的重要性和迫切性,并详细介绍了内光电效应的理论与半导体光电器件的分类和应用前景。     

关于强Armendariz环和强拟Armendariz环

提出了强拟Armendariz环的概念,给出了强Armendariz环和强拟Armendariz环上的一些结果.     

Aluminum Complexes with a Donor Polymer: New Route to Organic/Inorganic Polymer Hybrids

The formation of alumina particles from aluminum salts in the presence of poly(1-vinylimidazole) was investigated by quantitative ²⁷Al NMR, potentiometry and FTIR spectra. The interaction of poly(1-vinylimidazole) with aluminum chloride and nitrate in an aqueous medium stabilizes [AlO₄Al₁₂(OH)₂₄]⁷⁺ and less ordered polymeric particles. The addition of NaOH (NaOH: Al 2) results in water-insoluble organic/inorganic hydrogen-bonded composites. Stabilization of the complexes is realized by cooperative hydrogen N···H—O—Al bonds, without N Al donor-acceptor interactions.     

Cationic Complexes of Monovalent Nickel as Catalysts for Styrene Polymerization

The interaction of the [Ni(PPh₃)₃]BF₄ complex with styrene and the products of styrene conversion in the polymerization reaction were studied by EPR and ¹³C NMR spectroscopy. The structure of the σ-carbocationic complex of Ni(I) formed by the interaction of styrene with the [Ni(PPh₃)₃]BF₄ cationic phosphine complex of Ni(I) was characterized in detail. It was found that the reaction of styrene polymerization occurred with the participation of the coordination center of the σ-carbocationic complex (coordination catalysis), whereas the reaction of telomerization occurred with the participation of the cationic center of this complex (ionic catalysis). The resulting polymer contained active terminal double bonds; it is a promising macromonomer for the synthesis of grafted copolymers. The discovered capacity of alcohols to undergo nucleophilic addition to a growing polymer chain offers strong possibilities for preparing functional polymers and block copolymers.     

非晶硅太阳电池的光伏检测磁共振研究

本文利用光伏检测磁共振(PDMR)方法初步研究了p⁺in⁺ a-Si:H太阳电池中与自旋状态有关的复合机制。研究表明太阳电池的制作工艺不同,相应的PDMR共振信号的线型和g因子亦不同,因而起支配作用的复合过程不同。根据PDMR结果讨论了a-Si:H膜的生长速度、衬底温度、本征层厚度等对太阳电池性能的影响。 关键词：     

A new stepwise synthesis of a family of propylamines derived from diatom silaffins and their activity in silicification

A new method for the stepwise synthesis of propylamines containing fragments of N-methyl propylamine as found in diatom bioextracts is presented and their activity in silicic acid condensation is described.     

怀菊花中微量铁的测定

为探讨邻二氮菲分光光度法测定怀菊花中微量元素铁含量的可行性,怀菊花的药理功效、食用营养价值与微量元素含量可能存在的关系,根据铁离子与特定显色剂显色产生可见吸收,采用混合酸y（HNO3）：V（HClO4）=4＋1对怀菊花样品湿法消化处理,在pH2～9的溶液中试剂与铁生成稳定的橙色络合物,并用分光光度法测定了怀菊花中微量元素铁含量。结果表明,所选的怀菊花中铁含量303．9～337．9μg／g,加标回收率为90．2％～100．6％。分光光度法操作简便、干扰离子少,测量快速、结果准确度和灵敏度高,易推广和 普及使用。     

旋流燃烧器复合小火焰模型的大涡模拟

对低旋燃烧器内的流动和燃烧进行了大涡模拟,其中化学反应分别采用传统的扩散小火焰模型和所提出的复合小火焰模型描述。复合小火焰模型借助于燃烧区索引的概念区分当地的燃烧模式,若当地的燃烧为扩散燃烧,则调用扩散小火焰库,否则调用预混小火焰库。数值结果与实验数据的对比表明,采用大涡模拟方法结合小火焰模型能够很好地模拟实验室尺度的低旋燃烧器,且采用复合小火焰模型能够得到更加符合实际的结果。