首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1529篇
  免费   142篇
  国内免费   110篇
化学   970篇
晶体学   35篇
力学   64篇
综合类   8篇
数学   370篇
物理学   334篇
  2023年   23篇
  2022年   50篇
  2021年   45篇
  2020年   57篇
  2019年   58篇
  2018年   61篇
  2017年   52篇
  2016年   86篇
  2015年   66篇
  2014年   84篇
  2013年   145篇
  2012年   85篇
  2011年   117篇
  2010年   70篇
  2009年   65篇
  2008年   68篇
  2007年   72篇
  2006年   73篇
  2005年   63篇
  2004年   42篇
  2003年   29篇
  2002年   27篇
  2001年   17篇
  2000年   24篇
  1999年   22篇
  1998年   18篇
  1997年   18篇
  1996年   23篇
  1995年   24篇
  1994年   12篇
  1993年   17篇
  1992年   16篇
  1991年   20篇
  1990年   14篇
  1989年   7篇
  1988年   6篇
  1987年   7篇
  1986年   7篇
  1985年   9篇
  1984年   7篇
  1983年   9篇
  1982年   8篇
  1981年   4篇
  1980年   7篇
  1978年   8篇
  1977年   7篇
  1976年   7篇
  1974年   8篇
  1973年   6篇
  1972年   2篇
排序方式: 共有1781条查询结果,搜索用时 31 毫秒
1.
Zhan  Yang  Dang  Chuangyin 《Mathematical Programming》2021,190(1-2):585-613
Mathematical Programming - In the general equilibrium with incomplete asset markets (GEI) model, the excess demand functions are typically not continuous at the prices for which the assets have...  相似文献   
2.
Partially fluorinated poly(arylene ether sulfone) multiblock copolymers bearing perfluorosulfonic functions (ps‐PES‐FPES), with ionic exchange capacity (IEC) ranging between 0.9 and 1.5 meq H+/g, are synthesized by regioselective bromination of partially fluorinated poly(arylene ether sulfone) multiblock copolymers (PES‐FPES), followed by Ullman coupling reaction with lithium 1,1,2,2‐tetrafluoro‐2‐(1,1,2,2‐tetrafluoro‐2‐iodoethoxy)ethanesulfonate. The PES‐FPES are prepared by aromatic nucleophilic substitution reaction by an original approach, that is, “one pot two reactions synthesis.” The chemical structures of polymers are analyzed by 1H and 19F NMR spectroscopy. The resulted ionomers present two distinct glass transitions and α relaxations revealing phase separation between the hydrophilic and the hydrophobic domains. The phase separation is observed at much lower block lengths of ps‐PES‐FPES as compared with the literature. AFM and SANS observations supported the phase separation, the hydrophilic domains are well dispersed but the connectivity to each other depends on the ps‐PES block lengths. The thermomechanical behavior, the water up‐take, and the conductivity of the ps‐PES‐FPES membranes are compared with those of Nafion 117® and randomly functionalized polysulfone (ps‐PES). Conductivities close or higher to those of Nafion 117® are obtained. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1941–1956  相似文献   
3.
Journal of Statistical Physics - In this paper, we will study the long time behavior of the simple symmetric exclusion process in the “channel” $$\varLambda _N=[1,N]\cap \mathbb {N}$$...  相似文献   
4.
5.
We study stability radii of linear Volterra-Stieltjes equations under multi-perturbations and affine perturbations. A lower and upper bound for the complex stability radius with respect to multi-perturbations are given. Furthermore, in some special cases concerning the structure matrices, the complex stability radius can precisely be computed via the associated transfer functions. Then, the class of positive linear Volterra-Stieltjes equations is studied in detail. It is shown that for this class, complex, real and positive stability radius under multi-perturbations or multi-affine perturbations coincide and can be computed by simple formulae expressed in terms of the system matrices. As direct consequences of the obtained results, we get some results on robust stability of positive linear integro-differential equations and of positive linear functional differential equations. To the best of our knowledge, most of the results of this paper are new.  相似文献   
6.
This paper proposes a floating-point genetic algorithm (FPGA) to solve the unit commitment problem (UCP). Based on the characteristics of typical load demand, a floating-point chromosome representation and an encoding–decoding scheme are designed to reduce the complexities in handling the minimum up/down time limits. Strategic parameters of the FPGA are characterized in detail, i.e., the evaluation function and its constraints, population size, operation styles of selection, crossover operation and probability, mutation operation and probability. A dynamic combination scheme of genetic operators is formulated to explore and exploit the FPGA in the non-convex solution space and multimodal objective function. Experiment results show that the FPGA is a more effective technique among the various styles of genetic algorithms, which can be applied to the practical scheduling tasks in utility power systems.  相似文献   
7.
Using Fourier integral operators with special amplitude functions, we analyze the stabilization of the wave equation in a three-dimensional bounded domain on which exists a trapped ray bouncing up and down infinitely between two parallel parts of the boundary.  相似文献   
8.
Transformations of chemical species formed by the reaction of gaseous BF3 with high pressure and silica preheated at 473 and 1093 K were studied with the use of infrared absorption spectrometry. The species containing -BF2 and the species containing >BF were transformed to each other on the highly-reacted silica depending on the pressure of BF3 in cell, and some of the species containing -BF2 were also desorbed without their transformations to the species containing >BF. H2O played important roles in these transformations.  相似文献   
9.
The purpose of this work was to investigate the effects of physical aging on the kinetics of yielding in polycarbonate. PC samples were annealed over a wide range of aging times and temperatures. Both tensile and compressive tests were performed over various loading rates and temperatures to analyze the effects of aging time and aging temperature on yielding kinetics. Two grades of polycarbonate, Makrolon, of different molecular weights, PC-2608 (low Mw), and PC-3208 (high Mw), supplied by Bayer were analyzed. In unaged condition, PC is hard and tough, but after aging, it becomes more brittle. In terms of molecular movement, the yielding process is a thermally activated process involving inter- and intra-molecular motions. The time–temperature dependence of yielding behavior can be separated into two regions. Aging does not affect localized molecular motions of the β process during yielding. Physical aging in PC results in a slower jump rate of the main segments of macromolecules between two equilibrium positions. It reduces the flexibility of the macromolecules and thus, makes the polymer more brittle. Heat aging also causes a decrease of the entropy (ΔS) in polycarbonate, and this decrease is more important when the molecular weight is reduced. Increasing the annealing time and temperature results in a continuous reduction of ΔS. The rate of aging decreases with decreasing annealing temperature and below about 30 °C, no aging takes place. Annealing also strongly affects the excess of enthalpy in PC. However the effect of physical aging on yielding differs to that on enthalpy excess. The kinetics of yielding and aging processes in polycarbonate are also different. An increase in the strain rate does not have the same effect on the yield stress as an increase in the aging time by a same factor.  相似文献   
10.
In this paper we introduce a new notion of infine nonsmooth functions and give several characterizations of infineness property. We prove alternative theorems with mixed constraints (i.e., inequality and equality constraints) being described by invex-infine nonsmooth functions. We establish a necessary and sufficient condition for a solution of a vector optimization problem involving mixed constraints to be a properly efficient solution.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号