全文获取类型
收费全文 | 405篇 |
免费 | 129篇 |
国内免费 | 138篇 |
专业分类
化学 | 319篇 |
晶体学 | 25篇 |
力学 | 16篇 |
综合类 | 8篇 |
数学 | 83篇 |
物理学 | 221篇 |
出版年
2023年 | 1篇 |
2022年 | 15篇 |
2021年 | 23篇 |
2020年 | 14篇 |
2019年 | 15篇 |
2018年 | 18篇 |
2017年 | 18篇 |
2016年 | 10篇 |
2015年 | 30篇 |
2014年 | 36篇 |
2013年 | 34篇 |
2012年 | 40篇 |
2011年 | 54篇 |
2010年 | 39篇 |
2009年 | 43篇 |
2008年 | 39篇 |
2007年 | 41篇 |
2006年 | 35篇 |
2005年 | 39篇 |
2004年 | 25篇 |
2003年 | 15篇 |
2002年 | 19篇 |
2001年 | 11篇 |
2000年 | 15篇 |
1999年 | 8篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1995年 | 4篇 |
1993年 | 5篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1976年 | 1篇 |
1965年 | 1篇 |
排序方式: 共有672条查询结果,搜索用时 31 毫秒
1.
The Raman shifts of nanocrystalline GaSb excited by an Ar^ ion laser at wavelengths 514.5, 496.5, 488.0, 476.5,and 457.9nm are studied by an SPEX-1403 laser Raman spectrometer respectively, and they are explained by phonon confinement, tensile stress, resonant Raman scattering and quantum size effects. The Stokes and anti-Stokes Raman spectra of GaSb nanocrystals strongly support the Raman feature of GaSb nanocrystals. The calculated optical spectra compare well with experimental data on Raman scattering GaSb nanocrystals. 相似文献
2.
3.
4.
本文考虑一带有人工粘性的二维定常等熵无旋平面流方程组的初-边值问题. 在一定的假设下,我们证明其驻波解是渐近稳定的. 相似文献
5.
6.
7.
一维链状冠醚配合物:[{Na(18-C-6)}2(H2O)]n[M(SCN)4]n(M=Pd、Pt)的合成与结构 总被引:1,自引:0,他引:1
The reactions of 18-crown-6 with Na2[M(SCN)4] (M= Pd,Pt) were studied and the complex 1 [{Na(18-C-6)}2(H2O)]n[Pd(SCN)4]n and complex 2 [{Na(18-C-6)}2(H2O)]n[Pt(SCN)4]n were characterized by ele-mental analysis, IR and X-ray diffraction analysis. The complexes belong to monoclinic, space group P21/n with cell dimensions, 1:a=1.05734(7),b=1.42250(10),c=1.47762(10) nm,β=107.5330(10)°,V=2.1192(2)nm3,Z=2,Dcalcd=1.460g·cm-3,F(000)=964,R1=0.0406,wR2=0.1264 and 2:a=1.05985(19),b=1.4237(3),c=1.4744(3) nm,β=107. 096(3)°, V=2.1264(7)nm3,Z=2,Dcalcd=1.690g·cm-3,F(000)=1028,R1=0.0292,wR2=0.0859. In the solid state, the complexes 1 and 2 show an one-dimensional chain of [{Na(18-C-6)}2(H2O)]2+ complex cations and [M(SCN)4]2- (M=Pd,Pt) complex anions bridged by Na-N in-teractions. 相似文献
8.
9.
A novel vanadium-phosphate compound [PV_2.5O_8.5]·3.83{H_2O}(1)was obtained from the hydrothermal reac-tion and structurally characterized by elemental analysis and single-crystal X-ray diffraction,which exhibited thatthe title complex crystallized in cubic space group I-43m with crystal data:a=1.6115(1)nm,V=4.1848(1)nm~3,Z=12,D_c=1.783 g/cm~3,F(000)=2278,R_1=0.0528,and wR_2=0.1329[I>2σ(I)](all data).The basic unit of{PV_2.5O_8.5}symmetrically extended to closed sphere-like structure of{P_4V_(10)O_(34)},which was further linked to in-terleaving three-dimensional network via sharing four phosphate through μ_3-oxygen atoms around the closedsphere-like structures. 相似文献
10.
A new polyoxomolybdate complex HNa7[Mo36O112(H2O)16]·47H2O 1 has been prepared in the beaker solution and characterized by single-crystal X-ray diffraction and elemental analyses. Crystal data: H127Mo36Na7O175, Mr = 6542.79, monoclinic, C2/c, a = 40.891(6), b = 17.900(3), c = 25.580(4) , β = 125.673(2)°, V = 15210(4) 3, Z = 4, Dc = 2.857 g/cm3, F(000) = 12464, μ = 3.013 mm-1, R = 0.0633 and wR = 0.1654 (I > 2σ(I)). With the bridging sodium cations, the [Mo36O112(H2O)16]8- units in compound 1 are linked to form a one-dimensional structure, on the basis of which a three-dimensional architecture is further constructed via other sodium cations and complicated hydrogen bonds. 相似文献