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The strength and stability properties of hierarchical load-bearing networks and their strengthened variants have been discussed
in a recent work. Here, we study the avalanche time distributions on these load-bearing networks. The avalanche time distributions
of the V-lattice, a unique realization of the networks, show power-law behaviour when tested with certain fractions of its
trunk weights. All other avalanche distributions show Gaussian peaked behaviour. Thus the V-lattice is the critical case of
the network. We discuss the implications of this result. 相似文献
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The reaction of unsymmetrical phenylmethyltin dihydride (PhMeSnH2), phenylethyltin dihydride (PhEtSnH2), phenylbutyltin dihydride (PhBuSnH2) and butylmethyltin dihydride (BuMeSnH2) with biuret (HAL) proceeds via SnH/NH dehydrocoupling to afford the corresponding tetra-coordinate cyclic products. The reactions in the molar ratios of 1 : 1, 2 : 1 and 1 : 2 have been studied. The yellow derivatives so isolated were soluble in polar solvents and insoluble in nonpolar solvents. It was found that 1 : 1 reaction went to completion while 2 : 1 and 1 : 2 did not go to completion. The derivatives had been characterized by elemental analysis and spectroscopic techniques viz. IR, ^1H NMR, ^13C NMR, ^119Sn NMR. DSC and TGA of the reaction products have also been studied. All the derivatives were thermally stable upto (1904- 10)℃ and degradation occurred after that. 相似文献
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Curing kinetics of diglycidyl ether of bisphenol-A (DGEBA) in the presence of varying molar ratios of derivatives of stannanes to 4,4'-diaminodiphenylsulfone (DDS) was investigated by the dynamic differential scanning calorimetry. The derivatives were synthesized by reacting 1 mole of biguanide (B) with 1 mole of phenylethyltindihydride (PETH) or phenylmethyltindihydride (PMTH) or phenylbutyltindihydride (PBTH) and designated as BPETH or BPMTH or BPBTH respectively. These derivatives were characterized by elemental analysis and spectroscopic techniques such as IR, 1H NMR, 13C NMR and 119Sn NMR. The mixtures of these derivatives to DDS at ratios of 0∶1, 0.25∶0.75, 0.5∶0.5, 0.75∶0.25 and 1∶0 were used to investigate the curing behaviour of DGEBA. The multiple heating rate method (5, 10, and 15 and 20 ℃•min-1) was used to study the curing kinetics of epoxy resins. The thermal stability of the isothermally cured resins was also evaluated using dynamic thermogravimetry in a nitrogen atmosphere. 相似文献
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