全文获取类型
收费全文 | 1163篇 |
免费 | 44篇 |
国内免费 | 2篇 |
专业分类
化学 | 819篇 |
晶体学 | 5篇 |
力学 | 11篇 |
数学 | 69篇 |
物理学 | 305篇 |
出版年
2022年 | 6篇 |
2021年 | 18篇 |
2020年 | 13篇 |
2019年 | 16篇 |
2018年 | 10篇 |
2017年 | 13篇 |
2016年 | 38篇 |
2015年 | 23篇 |
2014年 | 30篇 |
2013年 | 65篇 |
2012年 | 62篇 |
2011年 | 87篇 |
2010年 | 45篇 |
2009年 | 45篇 |
2008年 | 66篇 |
2007年 | 64篇 |
2006年 | 77篇 |
2005年 | 70篇 |
2004年 | 40篇 |
2003年 | 39篇 |
2002年 | 38篇 |
2001年 | 15篇 |
2000年 | 23篇 |
1999年 | 16篇 |
1998年 | 13篇 |
1997年 | 12篇 |
1996年 | 17篇 |
1995年 | 13篇 |
1994年 | 11篇 |
1993年 | 13篇 |
1992年 | 17篇 |
1991年 | 12篇 |
1990年 | 19篇 |
1989年 | 15篇 |
1988年 | 13篇 |
1987年 | 16篇 |
1986年 | 13篇 |
1985年 | 12篇 |
1984年 | 9篇 |
1983年 | 4篇 |
1982年 | 12篇 |
1981年 | 8篇 |
1979年 | 4篇 |
1978年 | 5篇 |
1977年 | 8篇 |
1976年 | 4篇 |
1975年 | 5篇 |
1974年 | 5篇 |
1973年 | 5篇 |
1914年 | 2篇 |
排序方式: 共有1209条查询结果,搜索用时 46 毫秒
1.
Svetlakova A. V. Mendez M. Sanchez Tuchin E. S. Khodan A. N. Traore M. Azouani R. Kanaev A. Tuchin V. V. 《Optics and Spectroscopy》2021,129(8):846-850
Optics and Spectroscopy - We study the photocatalytic activity of nanocomposites based on θ-phase alumina (Al2O3) with different TiO2 concentrations for heterogeneous photocatalysis and... 相似文献
2.
We investigate the dynamics of the Λ system driven by two resonant laser fields in presence of dissipation for coupling strengths where the rotating‐wave approximation starts to break down. This regime is characterised by Rabi frequencies being approximately equal or smaller than the field frequencies. A systematic procedure to obtain an expansion for the solution of the Bloch evolution equations of the system is presented. The lowest contribution results to be the well‐known rotating‐wave approximation. The method is based on a semi‐classical treatment of the problem, and its predictions are interpreted fully quantum mechanically. The theory is illustrated by a detailed study of the disappearance of coherent population trapping as the intensities of the fields increase. 相似文献
3.
J. Saunier F. Alloin J. Y. Sanchez B. Barrire 《Journal of Polymer Science.Polymer Physics》2004,42(3):544-552
Some microporous poly(vinylidene fluoride) (PVdF) separators for lithium‐ion batteries, used in liquid organic electrolytes based on a mixture of carbonate solvents and lithium salt LiPF6, were characterized by the study of the swelling phenomena on dense PVdF membranes. Various aspects of the kinetics of the carbonate solvents and the solvent mixture sorption in dense PVdF slabs were studied at different temperatures. Non‐Fickian behavior, characterized by S‐shaped sorption curves, was highlighted, and a salt effect, which resulted in two‐stage sorption, was studied. Diffusion coefficients and activation energies were calculated for the Fickian portions of the sorption curves, that is, at short times and low swelling ratios. A strong influence of the different interaction parameters was shown for the swelling kinetics. This study proved that the swelling of microporous PVdF membranes could be considered instantaneous. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 544–552, 2004 相似文献
4.
J. Saunier F. Alloin J. Y. Sanchez L. Maniguet 《Journal of Polymer Science.Polymer Physics》2004,42(12):2308-2317
Microporous poly(vinylidene fluoride) (PVdF) separators for lithium-ion batteries, used in liquid organic electrolytes, have been characterized with respect to the swelling phenomena on dense PVdF membranes (obtained through hot pressing). In the first and second parts of this study, we have described the swelling equilibria and swelling kinetics of dense PVdF. Here the thermal properties of PVdF gels and their irreversible modifications induced by swelling are characterized. Particular attention is paid to crystallinity modifications, polymer plasticization, and membrane degradation. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2308–2317, 2004 相似文献
5.
P. Bonville M. Rams K. Królas J.-P. Sanchez P. C. Canfield O. Trovarelli C. Geibel 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,55(1):77-84
We have examined the magnetic properties of the heavy electron compounds
YbAgGe and YbPtIn by 170Yb M?ssbauer spectroscopy down to 0.1 K, and
the crystal field properties of YbAgGe by Perturbed Angular Correlations
(PAC) measurements up to 900 K. In YbAgGe, we show that each of the two
magnetically ordered phases below 0.8 K involves a specific incommensurate
modulation of the Yb moment. An analysis of existing low temperature specific
heat data suggests the
persistence of fluctuations of the correlated Yb spins down to 0.1 K.
The PAC data allow to discriminate among proposed Yb3+ crystal field
level schemes. In YbPtIn, we show that the low temperature magnetic order
phase has an antiferro-para structure, where zero moment Yb ions coexist with
large moment ones, and that a 90° moment reorientation occurs at
1.4 K. 相似文献
6.
Sol-gel chemistry of transition metal oxides 总被引:9,自引:0,他引:9
7.
8.
Heilemann M Tinnefeld P Sanchez Mosteiro G Garcia Parajo M Van Hulst NF Sauer M 《Journal of the American Chemical Society》2004,126(21):6514-6515
We demonstrate the synthesis and spectroscopic characterization of an unidirectional photonic wire based on four highly efficient fluorescence energy-transfer steps (FRET) between five spectrally different chromophores covalently attached to double-stranded DNA. The DNA-based modular conception enables the introduction of various chromophores at well-defined positions and arbitrary interchromophore distances. While ensemble fluorescence measurements show overall FRET efficiencies between 15 and 30%, single-molecule spectroscopy performed on four spectrally separated detectors easily uncovers subpopulations that exhibit overall FRET efficiencies of up to approximately 90% across a distance of 13.6 nm and a spectral range of approximately 200 nm. Fluorescence trajectories of individual photonic wires show five different fluorescence intensity patterns which can be ascribed to successive photobleaching events. 相似文献
9.
C. Joly S. Goizet J. C. Schrotter J. Sanchez M. Escoubes 《Journal of membrane science》1997,130(1-2):63-74
The effect of introduction of silica particles prepared by the sol-gel technique on the gas transport properties of a polyimide film was studied. The sorption and permeation of N2, O2, CO2, H2 and CH4 were studied and correlated with morphological changes in the polymer structure. From sorption isotherms, we observed that the composite membrane presents higher solubility coefficients than the polyimide one. The solubility coefficient ratio between the composite and the polyimide is about 1.5–2.0. The isotherms were analyzed in terms of the dual mode sorption. The Henry's coefficient and the Langmuir's affinity and saturation constants were obtained allowing to calculate the Langmuir to Henry concentration ratios as function of the gas pressure. These ratios decrease until zero within a certain pressure range as long as the Langmuir's mode is acting and they are higher for the polyimide membrane when compared with the composite one. This study was completed with calorimetric measurements during the sorption. The gas interaction energy in kJ/mol decreases within the same pressure range as previously described. The measured energies are higher for the polyimide film when compared with the composite one because the polyimide membrane presents a stronger energetic effect caused by a higher Langmuir's contribution. From permeation studies at 3.155 Pa, the composite membrane showed higher permeability coefficients and permselectivities than the polyimide one. All these results were explained, taking into account the difference on the imidization degree of both membranes and the morphological changes which may be induced by the silica nodules in the organic/inorganic interphases. 相似文献
10.
Kujawa P Moraille P Sanchez J Badia A Winnik FM 《Journal of the American Chemical Society》2005,127(25):9224-9234
The layer-by-layer growth of multilayer assemblies of two polysaccharides, the polyanion hyaluronan (HA) and the polycation chitosan (CH), was investigated using atomic force microscopy (AFM) and surface plasmon resonance (SPR) spectroscopy, with primary emphasis on the effect of the polysaccharide molecular weights on the film thickness and surface morphology. The HA/CH multilayers exhibit an exponential increase of the optical film thickness with the number of deposited bilayers. We show that the multilayer thickness at a given stage depends on the size of both CH, the diffusing polyelectrolyte, and HA, the non-diffusing species. Assemblies (12 bilayers) of high molecular weight polysaccharides (HA, 360,000; CH, 160,000) were twice as thick (approximately 900 nm vs approximately 450 nm) as those obtained with low molecular weight polymers (HA, 30,000; CH, 31,000), as assessed by AFM scratch tests. The exponential growth rate is the same for the high and low molecular weight pairs; the larger film thicknesses observed by SPR and by AFM arising from an earlier onset of the steep exponential growth phase in the case of the high molecular weight pair. In all cases, isolated islets form during the deposition of the first CH layer onto the underlying HA. Upon further film growth, individual islets coalesce into larger vermiculate features. The transition from distinct islands to vermiculate structures depends on the molecular weights of the polysaccharides and the lower molecular weight construct presents larger worm-like surface domains than the high molecular weight pair. 相似文献