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The synthesis of 6-selenophenyl derivatives of β-1,3 and β-1,4 disaccharides has been explored for the purpose of extending our epoxide fluoridolysis methodology to the synthesis of 5-fluoro analogues of N-acetyl isolactosamine (isoLacNAc, lacto-N-biose) and N-acetyl lactosamine (LacNAc) glycosides. Successful synthesis of the C-6 selenium-containing disaccharides was achieved via Lewis acid-mediated donor and acceptor substrates, the latter containing a selectively protected C-6 hydroxyl group for ultimate conversion to the desired 6-selenophenyl disaccharides. In contrast, the use of selenium-containing acceptor substrates under a variety of conditions failed to yield the desired selenium-containing disaccharides. Oxidation of the 6-selenophenyl derivatives to the corresponding selenoxides followed by thermal elimination yielded the exocyclic olefins, which were converted to the 5,6-epoxides. Epoxide fluoridolysis yielded the desired target compounds, 5-fluoro β-octyl glycoside analogues of type 1 and type 2 glycans. The newly synthesized fluorine-containing disaccharides have potential application as fucosyltransferase substrates, both for mechanistic studies and in the chemoenzymatic synthesis of fluorine-containing oligosaccharides.  相似文献   
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The interfacial stability of rotating core-annular flows is investigated. The linear and nonlinear effects are considered for the case when the annular region is very thin. Both asymptotic and numerical methods are used to solve the flow in the core and film regions which are coupled by a difference in viscosity and density. The long-time behavior of the fluid-fluid interface is determined by deriving its nonlinear evolution in the form of a modified Kuramoto-Sivashinsky equation. We obtain a generalization of this equation to three dimensions. The flows considered are applicable to a wide array of physical problems where liquid films are used to lubricate higher- or lower-viscosity core fluids, for which a concentric arrangement is desired. Linearized solutions show that the effects of density and viscosity stratification are crucial to the stability of the interface. Rotation generally destabilizes nonaxisymmetric disturbances to the interface, whereas the centripetal forces tend to stabilize flows in which the film contains the heavier fluid. Nonlinear effects allow finite-amplitude helically traveling waves to exist when the fluids have different viscosities.This research was partially supported by the National Aeronautics and Space Administration under NASA Contract No. NAS1-18605 while the second author was in residence at the Institute for Computer Applications in Science and Engineering (ICASE), NASA Langley Research Center, Hampton, VA 23665. This work was also supported by the Science and Engineering Research Council.  相似文献   
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