The cyclodimerisation of 3-methyl-2-butenenitrile

3-Methyl-2-butenenitrile (1) cyclodimerised on treatment with lithium diisopropylamide in dimethoxyethane at temperatures between ?78°C and 0°C to 3-amino-4-cyano-1,5,5-trimethyl-1,3-cyclohexadiene (2) the structure of which was established by acid hydrolysis to the known 4-cyano-1,5,5-trimethyl-1-cyclohexene-3-one (3).     

Atmospheric pressure laser desorption/chemical ionization mass spectrometry: a new ionization method based on existing themes

We have designed and constructed an atmospheric pressure laser desorption/chemical ionization (AP-LD/CI) source that utilizes a laser pulse to desorb intact neutral molecules, followed by chemical ionization via reagent ions produced by a corona discharge. This source employs a heated capillary atmospheric pressure inlet coupled to a quadrupole ion trap mass spectrometer and allows sampling under normal ambient air conditions. Preliminary results demonstrate that this technique provides approximately 150-fold increase in analyte ions compared to the ion population generated by atmospheric pressure infrared matrix-assisted laser desorption/ionization (AP-IR-MALDI).     

Three-alpha force and the 3-α model of12C

We postulate a Gaussian three-body potential amongα particles and adjust its parameters so that, when it is added to the Ali-Bodmerα-α potential, a good fit to experimental energies of low-lying 0⁺ and 2⁺ states of¹²C is achieved. With these potentials we made a linear variational calculation in a basis of harmonic oscillator functions which are translationally invariant, completely symmetric, and have a definite orbital angular momentum. We study the influence of this three-body potential on elastic and inelastic form factors, transition widths, Coulomb energy and charge radius of the 3-α system. The 3-α potential improved results found with the Ali-Bodmer potential alone. We find the 0 ₂ ⁺ state to be a (non-rigid) linear chain and the ground state to be a triangle ofα particles.     

Chemical Derivatization of Peptide Carboxyl Groups for Highly Efficient Electron Transfer Dissociation

The carboxyl groups of tryptic peptides were derivatized with a tertiary or quaternary amine labeling reagent to generate more highly charged peptide ions that fragment efficiently by electron transfer dissociation (ETD). All peptide carboxyl groups—aspartic and glutamic acid side-chains as well as C-termini—were derivatized with an average reaction efficiency of 99 %. This nearly complete labeling avoids making complex peptide mixtures even more complex because of partially-labeled products, and it allows the use of static modifications during database searching. Alkyl tertiary amines were found to be the optimal labeling reagent among the four types tested. Charge states are substantially higher for derivatized peptides: a modified tryptic digest of bovine serum albumin (BSA) generates ~90% of its precursor ions with z? > ?2, compared with less than 40 % for the unmodified sample. The increased charge density of modified peptide ions yields highly efficient ETD fragmentation, leading to many additional peptide identifications and higher sequence coverage (e.g., 70 % for modified versus only 43 % for unmodified BSA). The utility of this labeling strategy was demonstrated on a tryptic digest of ribosomal proteins isolated from yeast cells. Peptide derivatization of this sample produced an increase in the number of identified proteins, a >50 % increase in the sequence coverage of these proteins, and a doubling of the number of peptide spectral matches. This carboxyl derivatization strategy greatly improves proteome coverage obtained from ETD-MS/MS of tryptic digests, and we anticipate that it will also enhance identification and localization of post-translational modifications.

Band offsets, Fermi levels and impurity bands in doped contact layers

A mathematical formalism for use in the study of the temperature dependence of Tsu-Esaki tunneling currents is developed. The discussion includes recently discovered corrections to the Tsu-Esaki tunneling current calculation. These corrections involve emitter and collector electron density effects. The tunneling current is fully amenable to numerical calculation, but some calculations can be facilitated by analytic techniques. An operator technique of Blankenbecler is illustrated and used to generate low temperature series expansions for the tunneling current and emitter-collector electron densities.     

Reworking the Tucson-Melbourne Three-Nucleon Potential

 We introduce new values of the strength constants (i.e., a, b, c, and d coefficients) of the Tucson-Melbourne (TM) 2π-exchange three-nucleon potential. The new values come from contemporary dispersion-relation analyses of meson-factory πN-scattering data. We make variational Monte-Carlo calculations of the triton with the original and updated three-body forces to study the effects of this update. We remove a short-range–π-range part of the potential due to the c coefficient and discuss the effect on the triton binding energy. Received September 11, 1999; revised November 2, 1999; accepted February 23,     

Conical parametric scattering of a single extraordinary beam in BaTiO3 crystal

In this paper, the parametric scattering of a single extraordinary polarized beam of laser in BaTiO₃ photorefractive crystal has been investigated experimentally and theoretically. The resulting pattern consists of beam fanning, isotropic ring, and anisotropic one. Among all parts of scattering pattern, isotropic ring has not been studied as much as beam fanning and anisotropic ring, and there still are some differences in reports about it. Therefore, the study has mainly focused on this part. In this experimental configuration, isotropic ring is just visible in positive angles although the other parts of parametric scattering pattern can be visible from behind and in front of the crystal. In addition to steady state pattern in forward and backward directions, its transient behavior with the rotation of crystal has been studied. The results of experiments have been analyzed carefully, and their theoretical explanations have been presented based on the standard theory of parametric scattering in photorefractive crystals. It has been shown that this configuration corresponds to the so called parametric B-process scattering.     

Three-body forces and4He

Some two-pion exchange three-body forces are examined as effective two-body potentials in the framework of exp(S) many-body theory. Each effective potential is added to the Reid soft core potential and a fully self-consistent calculation carried out. The most reasonable three-body forces give remarkably good agreement with experiment.     

Pion-Nucleon Interaction and Two-Pion-Exchange Three-Nucleon Forces

We compare the πN scattering amplitudes that underlie 2π-exchange three-nucleon forces (TBFs) with the experimental πN amplitudes in the form of partial-wave phase shifts and subthreshold invariant amplitudes. The amplitudes of the Tucson-Melbourne and Brazil TBFs when taken on-pion-mass-shell predict scattering lengths at threshold and phase shifts (slightly) above threshold which are in good agreement with the experimental amplitudes, except for the S-waves. Partial wave amplitudes from separable potentials, recently employed in a 2π-TBF calculation, were continued below threshold, summed into invariant amplitudes, and compared with the experimental amplitudes in this kinematic region, which is most relevant to the kinematics of TBFs. The separable-potential invariant amplitudes, in contrast to those of TM and Brazil TBFs, do not compare well quantitatively with the experimental amplitudes in this region but have a similar qualitative behaviour. The very small TBF effect in the triton of the separable-potential amplitude appears to be due to the πNN vertex function rather than the πN amplitude itself. Received April 27, 1994; revised August 2, 1994; accepted for publication August 31, 1994