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排序方式: 共有56条查询结果,搜索用时 31 毫秒
1.
Diaryliodonium salts react with lithium acyltetracarbonylferrates to give aryl ketones and iodides in high yield, provided the THF medium contains a large proportion of pentane. 相似文献
2.
A range of 1-(2-propenyl) alcohols was transformed in good yields into vinyl-oxiranes via the allylic bromide. 相似文献
3.
Halotriazolium Axle Functionalised [2]Rotaxanes for Anion Recognition: Investigating the Effects of Halogen‐Bond Donor and Preorganisation
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James M. Mercurio Richard C. Knighton Dr. James Cookson Prof. Paul D. Beer 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(37):11740-11749
The anion‐templated synthesis of three novel halogen‐bonding 5‐halo‐1,2,3‐triazolium axle containing [2]rotaxanes is described, and the effects of altering the nature of the halogen‐bond donor atom together with the degree of inter‐component preorganisation on the anion‐recognition properties of the interlocked host investigated. The ability of the bromotriazolium motif to direct the halide‐anion‐templated assembly of interpenetrated [2]pseudorotaxanes was studied initially; bromide was found to be the most effective template. As a consequence, bromide anion templation was used to synthesise the first bromotriazolium axle containing [2]rotaxane, the anion‐binding properties of which, determined by 1H NMR spectroscopic titration experiments, revealed enhanced bromide and iodide recognition relative to a hydrogen‐bonding protic triazolium rotaxane analogue. Two halogen‐bonding [2]rotaxanes with bromo‐ and iodotriazolium motifs integrated into shortened axles designed to increase inter‐component preorganisation were also synthesised. Anion 1H NMR spectroscopic titration experiments demonstrated that these rotaxanes were able to bind halide anions even more strongly, with the iodotriazolium axle integrated rotaxane capable of recognising halides in aqueous solvent media. Importantly, these observations suggest that a halogen‐bonding interlocked host binding domain, in combination with increased inter‐component preorganisation, are requisite design features for a potent anion receptor. 相似文献
4.
Gang Chen Wenhua Yu Dileep Singh David Cookson Jules Routbort 《Journal of nanoparticle research》2008,10(7):1109-1114
Knowledge of the size and distribution of nanoparticles in solution is critical to understanding the observed enhancements
in thermal conductivity and heat transfer of nanofluids. We have applied small-angle X-ray scattering (SAXS) to the characterization
of SiO2 nanoparticles (10–30 nm) uniformly dispersed in a water-based fluid using the Advanced Photon Source at Argonne National
Laboratory. Size distributions for the suspended nanoparticles were derived by fitting experimental data to an established
model. Thermal conductivity of the SiO2 nanofluids was also measured, and the relation between the average particle size and the thermal conductivity enhancement
was established. The experimental data contradict models based on fluid interfacial layers or Brownian motion but support
the concept of thermal resistance at the liquid–particle interface. 相似文献
5.
R. F. Cookson J. W. James R. E. Rodway R. G. Simmonds 《Journal of heterocyclic chemistry》1972,9(3):475-480
The alkylation of phenanthridone and some nuclear-substituted phenanthridones using sodium hydride in DMF/benzene is reported. Various 5-cyanoalkylphenanthridones were converted to further derivatives by either hydrolysis or reduction. 相似文献
6.
Justin T. Russell Yao Lin Alexander Bker Long Su Philippe Carl Heiko Zettl Jinbo He Kevin Sill Ravisubhash Tangirala Todd Emrick Kenneth Littrell Pappannan Thiyagarajan David Cookson Andreas Fery Qian Wang Thomas P. Russell 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2005,117(16):2472-2478
7.
8.
Robert T. Parfitt David E. Games Ronald F. Cookson Alan C. Richards Norman Lynaugh 《Journal of mass spectrometry : JMS》1978,13(6):341-343
A combination of electron impact, chemical ionization, field desorption and field ionization mass spectrometry has been employed to demonstrate that the LAH reduction product of 3H-1,2-benzodithiole-3-thione is the dimer, dibenzo[c,h]-3H,10H-dihydro-1,2,8,9-tetrathiecine. 相似文献
9.
Lin Y Böker A Skaff H Cookson D Dinsmore AD Emrick T Russell TP 《Langmuir : the ACS journal of surfaces and colloids》2005,21(1):191-194
The self-assembly of nanoparticles at fluid interfaces, driven by the reduction in interfacial energy, was investigated. With spherical, tri-n-octyl-phosphine-oxide covered cadmium selenide (CdSe) nanoparticles (1-8 nm), thermal fluctuations compete with the interfacial segregation giving rise to a size-dependent self-assembly of the particles. The structure of the nanoparticle assembly was studied using electron microscopy, atomic force microscopy, and X-ray scattering in situ, which indicate that the particles form a densely packed monolayer. The energetics of the adsorption of nanoparticles onto the interface was revealed by time-dependent fluorescence studies on a mixture of two different sized nanoparticles at the interface. The dynamics of the nanoparticles at the fluid interface, probed using fluorescence photobleaching methods, suggests a liquid-like behavior. The results have implications in the design of hierarchical self-assemblies of nanoparticles for the one-step fabrication of devices on multiple length scales. 相似文献
10.
Citral (I) is cyclized by UV irradiation1 to 2-isopropenyl-5-methylcyclopentane-carboxaldehyde (II), containing the carbon skeleton of the monoterpenes of ants and catmint. 1,6,6-Trimethylbicyclo[2,1,1]hexane-2-carboxaldehyde (XII, R = H), produced in lesser amount at the same time, was synthesized from camphor. The two photocitrals may, perhaps, come from a common intermediate containing the cyclopentane ring. 相似文献