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Binding energy spectra of the valence electrons of the open shell molecule NO have been obtained up to 55 eV at azimuthal angles of 0° and 7° using binary (e, 2e) spectroscopy at an impact energy of 1200 eV. The momentum distribution has been obtained for the least tightly bound (unpaired) electron, removal of which leads to formation of the X 1Σ+ ground state of NO+. Momentum distributions have also been measured at 21.0 and 40.5 eV. The measured momentum distributions are compared with several literature wavefunctions of varying complexity. They are found to be in excellent agreement with those calculated using the natural spin orbital wavefunctions of Kouba and Ohrn. 相似文献
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Michael Cook 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》1994,106(7):836-837
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P. Guenoun M. Delsanti D. Gazeau J.W. Mays D.C. Cook M. Tirrell M. Tirrell L. Auvray 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,1(1):77-86
Aqueous micellar solutions of ionic/neutral block copolymers have been studied by light scattering, small angle neutron scattering
and small angle X-ray scattering. We made use of a polymer comprised of a short hydrophobic block (polyethylene-propylene)
PEP and of a long polyelectrolytic block (polystyrene-sulfonate) PSSNa which has been shown previously to micellize in water.
The apparent polydispersity of these micelles is studied in detail, showing the existence of a few large aggregates coexisting
with the population of micelles. Solutions of micelles are found to order above some threshold in polymer concentration. The
order is liquid-like, as demonstrated by the evolution with concentration of the peak observed in the structure factor (), and the degree of order is found to be identical over a large range of concentrations (up to 20 wt%). Consistent values
of the aggregation number of the micelles are found by independent methods. The effect of salt addition on the order is found
to be weak.
Received: 19 June 1997 / Received in final form: 4 September 1997 / Accepted: 9 October 1997 相似文献
5.
Chvátal introduced the idea of viewing cutting planes as a system for proving that every integral solution of a given set of linear inequalities satisfies another given linear inequality. This viewpoint has proven to be very useful in many studies of combinatorial and integer programming problems. The basic ingredient in these cutting-plane proofs is that for a polyhedronP and integral vectorw, if max(wx|x P, wx integer} =t, thenwx t is valid for all integral vectors inP. We consider the variant of this step where the requirement thatwx be integer may be replaced by the requirement that
be integer for some other integral vector
. The cutting-plane proofs thus obtained may be seen either as an abstraction of Gomory's mixed integer cutting-plane technique or as a proof version of a simple class of the disjunctive cutting planes studied by Balas and Jeroslow. Our main result is that for a given polyhedronP, the set of vectors that satisfy every cutting plane forP with respect to a specified subset of integer variables is again a polyhedron. This allows us to obtain a finite recursive procedure for generating the mixed integer hull of a polyhedron, analogous to the process of repeatedly taking Chvátal closures in the integer programming case. These results are illustrated with a number of examples from combinatorial optimization. Our work can be seen as a continuation of that of Nemhauser and Wolsey on mixed integer cutting planes.Supported by Sonderforschungsbereich 303 (DFG) and by NSF Grant Number ECS-8611841.Supported by NSF Grant Number ECS-8418392 and Sonderforschungsbereich 303 (DFG), Institut für Ökonometrie und Operations Research, Universität Bonn, FR Germany. 相似文献
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Adler J Becker JJ Blaylock GT Bolton T Brient J Browder T Brown JS Bunnell KO Burchell M Burnett TH Cassell RE Coffman D Cook V Coward DH DeJongh F Dorfan DE Drinkard J Dubois GP Eigen G Einsweiler KF Eisenstein BI Freese T Gatto C Gladding G Grab C Hamilton RP Hauser J Heusch CA Hitlin DG Izen JM Kim PC Köpke L Li A Lockman WS Mallik U Matthews CG Mincer AI Mir R Mockett PM Mozley RF Nemati B Odian A Parrish L Partridge R Pitman D Plaetzer SA Richman JD Sadrozinski HF Scarlatella M Schalk TL 《Physical review letters》1989,62(16):1821-1824
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Blaylock GT Bolton T Brown JS Bunnell KO Burnett TH Cassell RE Coffman D Cook V Coward DH Dorfan DE Dubois GP Eigen G Eisenstein BI Freese T Gladding G Grab C Heusch CA Hitlin DG Izen JM Köpke L Li A Lockman WS Mallik U Matthews CG Mir R Mockett PM Mozley RF Nemati B Odian A Parker J Parrish L Partridge R Pitman D Sadrozinski HF Scarlatella M Schalk TL Schindler RH Seiden A Simopoulos C Stockdale IE Stockhausen W Thaler JJ Toki W Tripsas B Villa F Wasserbaech S Wattenberg A Weinstein AJ 《Physical review letters》1987,58(21):2171-2174