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Neil G. Connelly John G. Crossley A. Guy Orpen Henrietta Salter 《Journal of organometallic chemistry》1994,480(1-2):c12-c13
The reaction of [NBu4n]2Cu(mnt)2] with [Pt(CNMe)4][PF6]2 gives [Pt(mnt)(CNMe)2]·(NC)2C2S2CNMe, an X-ray study of which reveals co-stacking of neutral planar metal and organic molecules. 相似文献
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Razaghi M. Gandomkar M. Ahmadi V. Das N. K. Connelly M. J. 《Optical and Quantum Electronics》2012,44(3-5):255-263
Optical and Quantum Electronics - In this paper, we analyse the picosecond wavelength conversion using semiconductor optical amplifier (SOA) with a novel technique. For an accurate and precise... 相似文献
5.
An experimental study of the thermal decomposition of a β‐hydroxy alkene, 3‐methyl‐3‐buten‐1‐ol, in m‐xylene solution, has been carried out at five different temperatures in the range of 513.15–563.15 K. The temperature dependence of the rate constants for the decomposition of this compound in the corresponding Arrhenius equation is given by ln k (s?1) = (25.65 ± 1.52) ? (17,944 ± 814) (kJ·mol?1)·T?1. A computational study has been carried out at the M05–2X/6–31+G(d,p) level of theory to calculate the rate constants and the activation parameters by the classical transition state theory. There is a good agreement between the experimental and calculated rate constants and activation Gibbs energies. The bonding characteristics of reactant, transition state, and products have been investigated by the natural bond orbital analysis, which provides the natural atomic charges and the Wiberg bond indices. Based on the results obtained, the mechanism proposed is a one‐step process proceeding through a six‐membered cyclic transition state, being a concerted and slightly asynchronous process. The results have been compared with those obtained previously by us (Struct Chem 2013, 24, 1811–1816) for the thermal decomposition of 3‐buten‐1‐ol, in m‐xylene solution. We can conclude that in the compound studied in this work, 3‐methyl‐3‐buten‐1‐ol, the effect of substitution at position 3 by a weakly activating CH3 group is the stabilization of the transition state formed in the reaction and therefore a small increase in the rate of thermal decomposition. 相似文献
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Abstract Due to the wide use of polymers in medicine, researchers are required to solve a very important problem–to understand the interaction between materials of nonphysiological origin and the surrounding biological liquids, and tissues, particularly blood. 相似文献
7.
De Vita R Anghinolfi M Burkert VD Dodge GE Minehart R Taiuti M Weller H Adams G Amaryan MJ Anciant E Armstrong DS Asavapibhop B Asryan G Audit G Auger T Avakian H Bagdasaryan H Ball JP Barrow S Battaglieri M Beard K Bektasoglu M Bianchi N Biselli AS Boiarinov S Bonner BE Bosted P Bouchigny S Branford D Brooks WK Bueltmann S Calarco JR Capitani GP Carman DS Carnahan B Cazes A Ciciani L Cole PL Coleman A Connelly J Cords D Corvisiero P Crabb D Crannell H Cummings JP De Sanctis E Degtyarenko PV 《Physical review letters》2002,88(8):082001
The double spin asymmetry in the (-->)e(-->)p --> e(prime)pi(+)n reaction has been measured for the first time in the resonance region for four-momentum transfer Q2 = 0.35-1.5 GeV(2). Data were taken at Jefferson Lab with the CLAS detector using a 2.6 GeV polarized electron beam incident on a polarized solid NH3 target. Comparison with predictions of phenomenological models shows strong sensitivity to resonance contributions. Helicity-1/2 transitions are found to be dominant in the second and third resonance regions. The measured asymmetry is consistent with a faster rise with Q(2) of the helicity asymmetry A1 for the F(15)(1680) resonance than expected from the analysis of the unpolarized data. 相似文献
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R. W. Connelly R. C. McConkey J. M. Noonan G. H. Pearson 《Journal of Polymer Science.Polymer Physics》1982,20(2):259-268
The effects of copolymerizing small amounts of an ionic moiety (0–7 mol %) into the backbone of a polycondensation polymer have been investigated by a combination of linear viscoelastic, steady-shear, and extensional testing. At a constant viscosity in dilute solution, both the zero-shear-rate viscosity and the maximum relaxation time in the melt increase monotonically with an increase in the ionic character. These effects are present after the data are normalized to remove the increase in the glass transition temperature Tg with increased ionic content. Large-strain, steady-shear flow experiments showed that the viscoelastic memory of the melt is affected by ionic content. An increase in ion content causes a decrease in the effect of strain on the memory function. This effect is not apparent in extensional flow experiments, which indicate that the ionic content does not affect the response if the tests are conducted at a constant temperature above Tg. 相似文献
10.
Fatemi R Skabelin AV Burkert VD Crabb D De Vita R Kuhn SE Minehart R Adams G Anciant E Anghinolfi M Asavapibhop B Audit G Auger T Avakian H Bagdasaryan H Ball JP Barrow S Battaglieri M Beard K Bektasoglu M Bellis M Bertozzi W Bianchi N Biselli AS Boiarinov S Bonner BE Bosted PE Bouchigny S Bradford R Branford D Brooks WK Butuceanu C Calarco JR Carman DS Carnahan B Cetina C Ciciani L Clark R Cole PL Coleman A Connelly J Cords D Corvisiero P Crannell H Cummings JP De Sanctis E Degtyarenko PV 《Physical review letters》2003,91(22):222002
Double-polarization asymmetries for inclusive ep scattering were measured at Jefferson Lab using 2.6 and 4.3 GeV longitudinally polarized electrons incident on a longitudinally polarized NH3 target in the CLAS detector. The polarized structure function g(1)(x,Q2) was extracted throughout the nucleon resonance region and into the deep inelastic regime, for Q(2)=0.15-1.64 GeV2. The contributions to the first moment Gamma(1)(Q2)= integral g(1)(x,Q2) dx were determined up to Q(2)=1.2 GeV2. Using a parametrization for g(1) in the unmeasured low x regions, the complete first moment was estimated over this Q2 region. A rapid change in Gamma(1) is observed for Q2<1 GeV2, with a sign change near Q(2)=0.3 GeV2, indicating dominant contributions from the resonance region. At Q(2)=1.2 GeV2 our data are below the perturbative QCD evolved scaling value. 相似文献