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The quantum yield of the photosubstitution of CO by pyridine in cyclohexane has a value of 0.67 ± 0.02 for [Cr(CO)6] = 3.10?4 mol l? and [pyridine] = 10? mol l?1. 相似文献
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Summary An improved procedure for the determination of the less volatile air pollutants of recycled closed atmospheres by activated carbon-Soxhlet extraction is proposed. After total treatment of desorbate, PAH determination is then accomplished by RP-HPLC using both adsorptiometric and fluorimetric UV detection; phenolic compounds are determined by GC-MS.This technique is suitable for very low levels of PAH and phenolic compounds. 相似文献
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Dr. Kilian Colas A. Catarina V. D. dos Santos Dr. Stefanie V. Kohlhepp Dr. Abraham Mendoza 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(9):e202104053
The synthesis of ketones through addition of organometallic reagents to aliphatic carboxylic acids is a straightforward strategy that is limited to organolithium reagents. More desirable Grignard reagents can be activated and controlled with a bulky aniline-derived turbo-Hauser base. This operationally simple procedure allows the straightforward preparation of a variety of aliphatic and perfluoroalkyl ketones alike from functionalized alkyl, aryl and heteroaryl Grignard reagents. 相似文献
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Leblond Sylvain Fichet Pascal Laumonier Rmi Billon Sophie Sardini Paul Colas Kimberly 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(2):1075-1089
Journal of Radioanalytical and Nuclear Chemistry - A new method has been developed to image surface contamination on-site by short range radiation emitters (such as alpha or beta particle... 相似文献
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This work is concerned with the algorithmic reachability analysis of continuous-time linear systems with constrained initial states and inputs. We propose an approach for computing an over-approximation of the set of states reachable on a bounded time interval. The main contribution over previous works is that it allows us to consider systems whose sets of initial states and inputs are given by arbitrary compact convex sets represented by their support functions. We actually compute two over-approximations of the reachable set. The first one is given by the union of convex sets with computable support functions. As the representation of convex sets by their support function is not suitable for some tasks, we derive from this first over-approximation a second one given by the union of polyhedrons. The overall computational complexity of our approach is comparable to the complexity of the most competitive available specialized algorithms for reachability analysis of linear systems using zonotopes or ellipsoids. The effectiveness of our approach is demonstrated on several examples. 相似文献
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E. Kapon M. Walther J. Christen M. Grundmann C. Caneau D.M. Hwang E. Colas R. Bhat G.H. Song D. Bimberg 《Superlattices and Microstructures》1992,12(4)
Quantum wire (QWR) heterostructures suitable for optoelectronic applications should meet a number of requirements, including defect free interfaces, large subband separation, long carrier lifetime, efficient carrier capture. The structural and opticl properties of GaAs/AlGaAs and InGaAs/GaAs quantum wire (QWR) heterostructures grown by organometallic chemical vapor deposition on nonplanr substrates, which satisfy many of these criteria, are described. These crescent-shaped QWRs are formed in situ during epitaxial growth resulting in virtually defect free interfaces. Effective wire widths as small as 10nm have been achieved, corresponding to electron subband separations greater than KBT at room temperature. The enhanced density of states at the QWR subbands manifests itself in higher optical absorption and emission as visualized in photoluminescence (PL), PL excitation, amplified spontaneous emission and lasing spectra of these structures. Effective carrier capture into the wires via connected quantum well regions, which is important for enhancing the otherwise extremely small capture cross section of these wires, has also been observed. Room temperature operation of GaAs/AlGaAs and strained InGaAs/GaAs QWR lasers with threshold currents as low as 0.6mA has been demonstrated. 相似文献
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Hanane Belghit Cyril Colas Sébastien Bristeau Benoit Maunit 《International journal of environmental analytical chemistry》2015,95(2):93-105
Chlordecone (CLD) is a persistent toxic chlorinated pesticide which contaminates different ecosystems in French West Indies. A soil remediation process including zero-valent iron (ZVI) has produced promising results but failed to completely degrade CLD, and the analytical procedures used yielded little information on the transformation products. To fill these gaps, dechlorination of aqueous CLD by micrometric particles of ZVI has been investigated. Aliquots of water with 25% (v/v) of acetone spiked with 100 ppm CLD were taken at different times during a 30-day ZVI treatment and directly analysed by ultra-high-performance liquid chromatography in negative electrospray ionisation mode. CLD has been totally transformed after 14 days into 14 dechlorinated degradation products, including 9 isomeric compounds. The maximum chloride concentrations appearing in the medium represent 44% of that which would result from total dechlorination of CLD. The CLD transformation products identified by accurate mass measurements on an ultra-high-resolution Q-TOF mass spectrometer (Q-TOF-MS) were C10H3Cl9O2, C10H4Cl8O2, C10H5Cl7O2, C10H6Cl6O2 and C10H7Cl5O2. The results show the interest of LC-Q-TOF-MS for identifying transformation products of organic contaminants, and the effectiveness of micrometric ZVI particles to totally transform CLD into less chlorinated products. 相似文献
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Reducing the ICRH (ion cyclotron range frequency) antenna-plasma interaction is one of the key points for reaching very long tokamak discharges. One problem which limits such discharges, is the appearance of hot spots on the surface of the antenna: Radio Frequency (RF) sheaths modify the properties of the edge plasma by rectifying the RF potential along open magnetic field lines and can induce hot spots. This paper investigates the corrections to sheath potentials introduced by the interactions between adjacent flux tubes. Our theoretical study started from an oscillating double Langmuir probe model, in which a transverse influx of current was included. This model was confronted with 1D PIC simulations along a magnetic field line, and demonstrated that current exchanges can decrease mean potentials. A 2D electrostatic fluid code was then developed, which couples adjacent flux tubes in a poloidal cross section with collisional conductivity or polarization currents. It showed that transverse currents are able to smooth structures smaller than a characteristic size in the sheath potential maps (results for Tore Supra). These computed rectified potentials can be used to obtain the DC electric fields in front of the antenna. And then, it gives an estimate of the particle drift and the energy flux on the antenna structure, which can explain hot spots. 相似文献