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2.
A. Ferreira da Silva I. Pepe S.A. Tomás W.M. de Azevedo R. Ahuja 《Applied Surface Science》2006,252(15):5365-5367
In this paper we present spectroscopic properties of doped and undoped titanium dioxide (TiO2) as nanofilms prepared by the sol-gel process with rhodamine 6G doping and studied by photoacoustic absorption, excitation and emission spectroscopy. The absorption spectra of TiO2 thin films doped with rhodamine 6G at very low concentration during their preparation show two absorption bands, one at 2.3 eV attributed to molecular dimmer formation, which is responsible for the fluorescence quenching of the sample and the other at 3.0 eV attributed to TiO2 absorption, which subsequently yields a strong emission band at 600 nm. The electronic band structure and optical properties of the rutile phase of TiO2 are calculated employing a fully relativistic, full-potential, linearized, augmented plane-wave (FPLAPW) method within the local density approximation (LDA). Comparison of this calculation with experimental data for TiO2 films prepared for undoped sol-gels and by sputtering is performed. 相似文献
3.
For a simple graph of maximum degree Δ, it is always possible to color the edges with Δ + 1 colors (Vizing); furthermore, if the set of vertices of maximum degree is independent, Δ colors suffice (Fournier). In this article, we give a short constructive proof of an extension of these results to multigraphs. Instead of considering several color interchanges along alternating chains (Vizing, Gupta), using counting arguments (Ehrenfeucht, Faber, Kierstead), or improving nonvalid colorings with Fournier's Lemma, the method of proof consists of using one single easy transformation, called “sequential recoloring”, to augment a partial k-coloring of the edges. 相似文献
4.
Vicenç Branchadell Roser Pleixats Claude Commandeur Max Malacria 《Journal of organometallic chemistry》2003,687(2):337-345
Regioselectivity of the Tsuji-Trost reaction on allyl acetates and carbonates substituted with silyl groups at the olefinic moiety has been analyzed. Silicon atom in the central carbon atom increases the stability of the intermediate π-allylpalladium cation with respect to the isomeric π-allylpalladium cation featuring the silicon in a terminal carbon atom. 相似文献
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We study in this Note the continuum (macroscopic) limit for some atomistic models for crystals. The purpose is to derive densities of mechanical energies from microscopic models. In contrast to the setting of a previous study, where the microscopic structure was assumed to be periodic, it is modelled here by a stochastic lattice, which enjoys some stationarity and ergodicity properties, following notions previously introduced elsewhere. To cite this article: X. Blanc et al., C. R. Acad. Sci. Paris, Ser. I 342 (2006). 相似文献
7.
Claude LeBrun 《Mathematische Annalen》1989,284(3):353-376
Research funded in part by NSF grant DMS-8704401 相似文献
8.
Claude A. Pruneau 《Acta Physica Hungarica A》2004,21(2-4):261-266
We present analyses of event-by-event dynamical net charge fluctuations measured in 130 and 200 GeV Au+Au collisions with the STAR detector. The dynamical net charge fluctuations are evaluated using the ν +-,dyn observable. Dynamical fluctuations measured in Au+Au collisions at 130 and 200 GeV are finite, and exceed charge conservation limits. They deviate from a perfect 1/N scaling and provide an indication that the collision dynamics varies with collision centrality. 相似文献
9.
For each infinite cardinal κ, we give examples of 2κ many non‐isomorphic vertex‐transitive graphs of order κ that are pairwise isomorphic to induced subgraphs of each other. We consider examples of graphs with these properties that are also universal, in the sense that they embed all graphs with smaller orders as induced subgraphs. © 2003 Wiley Periodicals, Inc. J Graph Theory 43: 99–106, 2003 相似文献