排序方式: 共有17条查询结果,搜索用时 218 毫秒
1.
Karpov V. M. Platonov V. E. Chuikov I. P. Rybalova T. V. Gatilov Yu. V. Shakirov M. M. 《Russian Journal of Organic Chemistry》2004,40(3):421-425
Reactions of 2-amino-3-(1-imino-2,2,2-trifluoroethyl)hexafluoro-1H-indene with carboxylic acid anhydrides and chlorides afforded 2-alkyl(aryl)-4-trifluoromethyl-5,6,7,8,9,9-hexafluoro-1,3-diazafluorenes. The molecular and crystalline structure of the products was studied by NMR spectroscopy and X-ray diffraction. 5,6,7,8,9,9-Hexafluoro-2-phenyl-4-trifluoromethyl-1,3-diazafluorene in crystal gives rise to infinite ladder chains via -stacking interaction between the benzene ring of one molecule and tetrafluorobenzene fragment of the other. 相似文献
2.
Role of the alkyl fragment of initiating alkoxyamine in nitroxide mediated polymerization of styrene
D. P. Zubenko I. A. Kirilyuk S. Marque I. P. Chuikov E. G. Bagryanskaya 《Polymer Science Series B》2010,52(5-6):327-338
The role of the alkyl fragment of alkoxyamine initiating the homopolymerization of styrene is experimentally and theoretically studied in the case of 2,2,6,6-tetramethylpiperidine-1-oxyl derivatives. The rate constants of homolysis and recombination are measured for the alkoxyamines under study. The characteristics of polymerization initiated by these compounds are experimentally examined. The kinetics of polymerization is theoretically calculated with allowance for the measured kinetic parameters and the experimentally detected side reaction of hydrogen-atom transfer to the nitroxide radical during the thermolysis of alkoxyamine 2-cyano-2-isopropyl-TEMPO. 相似文献
3.
I. P. Chuikov V. M. Karpov V. E. Platonov G. G. Yakobson 《Russian Chemical Bulletin》1988,37(8):1645-1650
Conclusions Upon reaction of perfluoro-3-methylindene and perfluoro-1-methyleneindane with hexafluoropropylene oxide at 225°C the corresponding cyclopropane derivatives are formed: perfluoro-la-methyl-1,1a,6,6a-tetrahydrocycloprop[a]indene and perfluorospiro[indane-1,1-cyclopropane], which are transformed during thermolysis in the presence of bromine into 1-bromo-2-difluorobromomethylperfluoro-1-methylindane and 1-bromo-1-(2-bromotetrafluoroethyl)perfluoroindane respectively, and in the absence of bromine into the starting olefins.Deceased.For previous report, see [1].Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1839–1845, August, 1988. 相似文献
4.
Mezhenkova T. V. Karpov V. M. Zonov Ya. V. Chuikov I. P. 《Russian Journal of Organic Chemistry》2019,55(2):193-201
Russian Journal of Organic Chemistry - Perfluoro(alkylbenzocycloalken-1-yl) cations were generated in a SbF5?SO2ClF medium from perfluorinated indane and benzocyclobutene derivatives... 相似文献
5.
I. V. Beregovaya V. M. Karpov T. V. Mezhenkova V. E. Platonov I. P. Chuikov 《Russian Journal of Organic Chemistry》2012,48(4):523-528
Treatment of perfluorinated benzocyclobutene, indan, and tetralin with SbF5-SO2Cl2, as well as of their 1,1-dichloro analogs with SbF5, gave 1-chloropolyfluorobenzocycloalken-1-yl cations whose structure was studied by 19F and 13C NMR and confirmed by their transformations into perfluorinated ketones upon hydrolysis. Dissolution of perfluorinated benzocyclobutene,
indan, and tetralin in excess SbF5 generated perfluorobenzocycloalken-1-yl cations in equilibrium with their precursors. The
relative stability of perfluoro- and 1-chloropolyfluorobenzocycloalken-1-yl cations decreases as the size of the alicyclic
fragment increases. 相似文献
6.
Chemical shifts in 19F and 13C NMR spectra of substituted pentafluorobenzenes are calculated by Hartree-Fock and density functional theory methods. The calculated values are compared with the experimental data known from the literature. It is shown that chemical shifts in non-polar solvents can be predicted sufficiently accurately by the GIAO-DFT(PBE/L22) method. This method is used to predict the 19F and 13C chemical shifts of a heptafluorobenzyl cation in the SbF5 medium. The best agreement between the calculated and experimental values is achieved when the counterion effect is taken into account. 相似文献
7.
8.
Karpov V. M. Platonov V. E. Chuikov I. P. 《Russian Journal of Organic Chemistry》2003,39(8):1151-1153
2-Dimethylamino-3-(1-imino-2,2,2-trifluoroethyl)hexafluoroindene in the presence of DMSO or NEt3 undergoes isomerization into 1-methyl-4-trifluoromethyl-5,6,7,8,9,9-hexafluoro-1,2,3,4-tetrahydro-1,3-diazafluorene, and from 1-(1-amino-2,2,2-trifluoroethylidene)octafluoroindane by the treatment with water solution of NHEt2 2-methyl-4-trifluoromethyl-1-ethyl-5,6,7,8,9,9-hexafluoro-1,2,3,4-tetrahydro-1,3-diazafluorene was obtained. 相似文献
9.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2463–2464, October, 1990. 相似文献
10.
In the reactions with ammonia and alkylamines, perfluoro-3-ethylindene is more reactive than perfluoro-1-ethylideneindan, whereby the last two compounds undergo mutual conversion in the presence of F–. In the interaction of perfluoro-1-ethylideneindan with aqueous amines, products of the substitution of the vinyl F atom in the initial compound are obtained; in the case of dry amines in the presence of CsF, the products of the substitution of the F atom at the double bond of perfluoro-3-ethylindene are chiefly obtained. The monoamino derivatives, which contain an available atom of H, are converted to the disubstituted derivatives by the action of an excess of the amines. Both the amine and the hydroxy anion may thereby emerge as the nucleophile in the reaction of 2-aminoperfluoro-3-ethylindene, as well as perfluoro-1-ethylideneindan, with aqueous dialkylamines. The perfluoro-1-vinylindan and aqueous NH3 yield 1-(aminocyanomethylene)octafluoroindan and 2-amino-3-(iminocyanomethyl)hexafluoroindene; and perfluoro-1-methyleneindan yields 2-amino-3-cyanohexafluoroindene. The last is formed together with 2-aminoperfluoro-3-methylindene in the reaction of perfluoro-3-methylindene with aqueous NH3.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1856–1865, August, 1990. 相似文献