The covalent triazine framework CTF-1 as a member of the two-dimensional covalent organic frameworks(COFs) is a category of novel metal-free photocatalysts for water splitting. The large band gap severely restricts its energy conversion efficiency. By means of the first-principles calculations, we proposed the decoration of CTF-1 by anchoring halogen atoms onto benzene moieties for improving the solar-to-hydrogen(STH) efficiency. The electronic structures reveal that the halogen substitution successfully decreases the band gap of CTF-1. Meanwhile, the calculated free energy changes along the reaction pathway indicate that all these COFs can spontaneously drive overall water splitting under light irradiation in a specific acid-base environment. The time-dependent ab initio non-adiabatic molecular dynamics simulations suggest that the electron-hole recombination periods of these COFs fall in a few to tens of nanoseconds. Excitingly, CTF-1 modified by linking six iodine atoms onto the benzene ring in the para-position(CTF-1-6I) shows a quite low band gap of 2.81 eV, indicating that it is a visible-light driven COF for overall photocatalytic water splitting. Correspondingly, CTF-1-6I also exhibits an extraordinarily promising STH efficiency of 3.70%, which is an order magnitude higher than that of the pristine CTF-1. 相似文献
Vibration isolation is one of the most efficient approaches to protecting host structures from harmful vibrations, especially in aerospace, mechanical, and architectural engineering, etc. Traditional linear vibration isolation is hard to meet the requirements of the loading capacity and isolation band simultaneously, which limits further engineering application, especially in the low-frequency range. In recent twenty years, the nonlinear vibration isolation technology has been widely investigated to broaden the vibration isolation band by exploiting beneficial nonlinearities. One of the most widely studied objects is the “three-spring” configured quasi-zero-stiffness (QZS) vibration isolator, which can realize the negative stiffness and high-static-low-dynamic stiffness (HSLDS) characteristics. The nonlinear vibration isolation with QZS can overcome the drawbacks of the linear one to achieve a better broadband vibration isolation performance. Due to the characteristics of fast response, strong stroke, nonlinearities, easy control, and low-cost, the nonlinear vibration with electromagnetic mechanisms has attracted attention. In this review, we focus on the basic theory, design methodology, nonlinear damping mechanism, and active control of electromagnetic QZS vibration isolators. Furthermore, we provide perspectives for further studies with electromagnetic devices to realize high-efficiency vibration isolation.
本文研究了保费收入过程是泊松过程和聚合理赔过程中理赔间隔时间和个别理赔额之间具有Boudreault et al.(2006)中所描述的相依结构的一类更新风险模型.运用生成函数、离散形式的Dickson-Hipp算子和反Z变换等一系列方法,推导出了该模型的Gerber-Shiu函数的生成函数的精确表达式,以及它所满足的瑕疵更新方程. 相似文献
By applying the method of variational wavefunction and adopting the approximation of 3D-Frohlich Hamiltonian for electron-LO phonon interaction in a spherical quantum dot (SQD), we have calculated the ground-state energy E, and binding energy Eg of a bound polaron confined in a GaAs/GaχAl1-χSQD. These energies vary as the value of the boundary potential of the SQD and the deviation of the position of the hydrogenic impurity from the centre of the sphere. In this system of concern, R = 2a*, a* is the effective Bohr radius, is an appropriate criterion for the radius R of an SQD when the effect of quantum confinement has to be considered. 相似文献