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Yang Min Dr. Chuandong Dou Prof. Hongkun Tian Prof. Jun Liu Prof. Lixiang Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(13):4364-4372
The B←N unit has a large dipole and it is isoelectronic to C−C moiety with no dipole. Incorporating B←N units into π-conjugated system is a powerful strategy to design organic small molecules and polymers with intriguing opto-electronic properties and excellent opto-electronic device performance. However, it is unclear how the B←N unit affects electronic structures and opto-electronic properties of large π-conjugated molecules. In this work, to address this question, we developed three dibenzo-azaacene molecules in which two B←N units were introduced at different positions. Although the dibenzo-azaacene skeleton is fully π-conjugated, the effect of B←N unit on the electronic structures of the adjacent rings is much stronger than that of the distant rings. As a result, the three molecules with isomerized B←N incorporation patterns possess different electronic structures and exhibit tunable opto-electronic properties. Among the three molecules, the centrosymmetrical molecule exhibits higher LUMO/HOMO energy levels than those of the two axisymmetrical molecules. When used as the active layer in organic field-effect transistors (OFETs), while the two axisymmetrical molecules show unipolar electron transporting property, the centrosymmetrical molecule exhibits ambipolar hole and electron transporting behavior. This work not only deepens our understanding on organoboron π-conjugated molecules, but also indicates a new strategy to tune opto-electronic properties of organic semiconductors for excellent device performance. 相似文献
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Stability criteria in terms of two measures for functional differential equation with variable‐time impulses
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Chao Liu Chuandong Li Tingwen Huang Hui Wang 《Mathematical Methods in the Applied Sciences》2015,38(14):2922-2936
This paper focuses on the stability in terms of two measures for functional differential equation with variable‐time impulses. Being different from most of existing literatures, the impulses of functional differential equation are assumed to be closely associated to the current state. We propose a new comparison principle for the considered systems and establish several stability criteria in terms of two measures. Also, the theoretical results are applied in a class of delayed neural network systems with variable‐tine impulses, and numerical simulations are introduced to illustrate the effectiveness of our results. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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This paper studies the exponential stabilization problem for a class of chaotic systems with delay by means of periodically intermittent control. A unified exponential stability criterion, together with its simplified versions, is established by using Lyapunov function and differential inequality techniques. A suboptimal intermittent controller is designed with respect to the general cost function under the assumption that the control period is fixed. Numerical simulations on two chaotic oscillators are presented to verify the theoretical results. 相似文献
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A shock wave that is characterized by sharp physical gradients always draws the medium out of equilibrium. In this work, both hydrodynamic and thermodynamic nonequilibrium effects around the shock wave are investigated using a discrete Boltzmann model. Via Chapman–Enskog analysis, the local equilibrium and nonequilibrium velocity distribution functions in one-, two-, and three-dimensional velocity space are recovered across the shock wave. Besides, the absolute and relative deviation degrees are defined in order to describe the departure of the fluid system from the equilibrium state. The local and global nonequilibrium effects, nonorganized energy, and nonorganized energy flux are also investigated. Moreover, the impacts of the relaxation frequency, Mach number, thermal conductivity, viscosity, and the specific heat ratio on the nonequilibrium behaviours around shock waves are studied. This work is helpful for a deeper understanding of the fine structures of shock wave and nonequilibrium statistical mechanics. 相似文献
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Visible thermal person re-identification (VT Re-ID) is the task of matching pedestrian images collected by thermal and visible light cameras. The two main challenges presented by VT Re-ID are the intra-class variation between pedestrian images and the cross-modality difference between visible and thermal images. Existing works have principally focused on local representation through cross-modality feature distribution, but ignore the internal connection of the local features of pedestrian body parts. Therefore, this paper proposes a dual-path attention network model to establish the spatial dependency relationship between the local features of the pedestrian feature map and to effectively enhance the feature extraction. Meanwhile, we propose cross-modality dual-constraint loss, which adds the center and boundary constraints for each class distribution in the embedding space to promote compactness within the class and enhance the separability between classes. Our experimental results show that our proposed approach has advantages over the state-of-the-art methods on the two public datasets SYSU-MM01 and RegDB. The result for the SYSU-MM01 is Rank-1/mAP 57.74%/54.35%, and the result for the RegDB is Rank-1/mAP 76.07%/69.43%. 相似文献
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Kelvin−Helmholtz (KH) instability is a fundamental fluid instability that widely exists in nature and engineering. To better understand the dynamic process of the KH instability, the influence of the tangential velocity on the compressible KH instability is investigated by using the discrete Boltzmann method based on the nonequilibrium statistical physics. Both hydrodynamic and thermodynamic nonequilibrium (TNE) effects are probed and analyzed. It is found that, on the whole, the global density gradients, the TNE strength and area firstly increase and decrease afterwards. Both the global density gradient and heat flux intensity in the vertical direction are almost constant in the initial stage before a vortex forms. Moreover, with the increase of the tangential velocity, the KH instability evolves faster, hence the global density gradients, the TNE strength and area increase in the initial stage and achieve their peak earlier, and their maxima are higher for a larger tangential velocity. Physically, there are several competitive mechanisms in the evolution of the KH instability. (i) The physical gradients increase and the TNE effects are strengthened as the interface is elongated. The local physical gradients decrease and the local TNE intensity is weakened on account of the dissipation and/or diffusion. (ii) The global heat flux intensity is promoted when the physical gradients increase. As the contact area expands, the heat exchange is enhanced and the global heat flux intensity increases. (iii) The global TNE intensity reduces with the decreasing of physical gradients and increase with the increasing of TNE area. (iv) The nonequilibrium area increases as the fluid interface is elongated and is widened because of the dissipation and/or diffusion. 相似文献
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用准连续60W的二极管激光列阵侧面泵浦“之”字形Nd:YAG板条激光器,当泵浦功率为45W,脉宽为400μs时,得到3.5mJ的激光输出。用KD*P电光开关调Q,得到18ns(FWHM)、2mJ的脉冲激光输出,用KTP晶体作腔内倍频,得到15ns、0.85mJ的二次谐波激光输出。在腔内无调Q元件且腔长小于5cm时,于近阈值处得到单频绿光输出,而当泵浦功率稍大,腔内有数个纵模振荡时,观察到激光的反相态,并用数值模拟的结果对此作了解释。 相似文献
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Polymer electron acceptors are the key materials in all-polymer solar cells(all-PSCs).In this review,we focused on introducing the principle of boron-nitrogen coordination bond(B←N),and summarizing our recent research on polymer electron acceptors containing B←N unit for efficient all-PSC devices.Two approaches have been reported to design polymer electron acceptors using B←N unit.One is to replace a C-C unit by a B←N unit in conjugated polymers to transform a polymer electron donor to a polymer electron acceptor.The other approach is to construct novel electron-deficient building block based on B←N unit for polymer electron acceptors.The polymer electron acceptors containing B←N unit showed tunable lowest unoccupied molecular orbital(LUMO) energy levels and exhibited excellent all-PSC device performance with power conversion efficiency of exceeding6%.These results indicate that organic boron chemistry is a new toolbox to develop functional polymer materials for optoelectronic device applications. 相似文献