The bismuth complex with dithiopiperdylcarbamate [Bi(S2CNC5H10)2(NO3)]·[1,10-Phen]·0.5H2O was synthesized. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal belongs to monoiclinic with space group C2/c, a=3.140(2) nm, b=1.176 4(9) nm, c=2.021 6(15) nm, β=103.081(12)°, V=5.713(7) nm3, Z=8, F(000)=3064, Dc=1.815 g·cm-3, μ=6.502mm-1. The final R1=0.0332, wR2=0.040 3. In the complex, the bismuth atom is eight-coordinated in a capped distorted pentagonal bipyramidal geometry. CCDC: 222655. 相似文献
A novel solid ternary complex, [Nd(C6H4NO2)2·C9H6NO·2H2O], was synthesized in a water bath (333.15 K) by three kinds of reagents: neodymium chloride, vitamin B3 (C6H5NO2), and 8-hydroxylquinoline (C9H7NO). Its composition and structure were characterized by elemental analysis, IR spectra, UV spectra, molar conductance, and thermogravimetric analysis. During the process of coordination, C6H5NO2 was bidentate-coordinated with Nd3+ in the form of an acidic group by removing the proton; hydroxyl oxygen atom and heterocyclic nitrogen atom of C9H7NO formed a chelate ring. Particularly, in this article, a thermochemical cycle in the calorimetric solvent (VHCl:VDMF:VEtOH = 3:1:1) was designed on the basis of Hess’s law. At 298.15 K, the dissolution enthalpies of the reactants and products were determined by a advanced solution–reaction isoperibol microcalorimeter, respectively. According to the above results and relevant literature data, the standard molar enthalpy of formation of [Nd(C6H4NO2)2·C9H6NO·2H2O], was estimated to be $ \Updelta_{f} H_{m}^{\Uptheta} $ [[Nd(C6H4NO2)2·C9H6NO·2H2O(s)], 298.15 K] = ?(2,129.1 ± 2.5) kJ mol?1. 相似文献
The μ-oxygen-bis[tri(p-fluorobenzyl)tin] was synthesized. The structure were characterized by elementary analysis, IR and 1H NMR and the crystal structure were determined by X-ray single crystal diffraction. The crystal of the title compound belongs to rhombohedral with space group R, a=1.346 4(4), b=1.346 4(4), c=1.772 9(7) nm, α=90°, β=90°, γ=120°, Z=3, V=2.783 2(15) nm3, Dc=1.625 g·cm-3, μ(Mo Kα)=1.408 mm-1, S=1.088, F(000)=1 350, R1=0.027 5, wR2=0.065 9. In compound, the tin atom has a distorted tetrahedral coordination configuration. CCDC: 257079. 相似文献
In the framework of graded quantum inverse scattering method, we obtain the eigenvalues and the eigenvectors of the Osp(l|2) model with reflecting boundary conditions in FBF background. The corresponding Bathe ansatz equations are obtained. 相似文献
The title complex [(C12H8N2)2Bi(O2NO)3] was synthesized by reaction of 1,10-phenanthroline (phen) and Bi(NO3)3·5H2O. The structure of the complex was characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental analysis. An advanced solution-reaction isoperibol microcalorimeter was applied to determine the standard molar enthalpies of formation at 298.15 K of the complex and Bi(NO3)3·5H2O, giving –(798.92 ± 5.99) and –(1986.87 ± 0.20) kJ mol−1, respectively. The biological effect of the complex was evaluated by microcalorimetry on the growth of Schizosaccharomyces pombe (S. pombe). According to thermogenic curves, the corresponding thermokinetics and thermodynamic parameters were derived. The complex had good bioactivity on the growth metabolism of S. pombe, with the value of IC50 being 2.8 × 10−5 mol L−1.
1 INTRODUCTION The chemistry of organotin(IV) complexes was extensively studied due to their biological activity and coordination chemistry[1~7]. More recently, phar- maceutical properties of alkyltin(IV) complexes with dithiocarbamate ligands have bee… 相似文献
Two dibenzyltin(IV) complexes with thiobenzoate ligand, (PhCH2)2Sn(SOCPh)2 (1) and (PhCH2)2Sn(C1)SOCPh (2), have been synthesized by the reaction of dibenzyltin(IV) dichloride with thiobenzoic acid in the presence of organic base Et3N and characterized by IR, ^1H NMR spectroscopy and elemental analysis. Their crystal structures were determined by X-ray single crystal diffraction analysis. In the crystals of 1, the tin atom is six-coordinated in a distorted octahedron configuration. In the crystals of 2, the molecular packing in unit cell reveals that the two adjacent molecules are symmetrically linked to each other to form a dimer with intermolecular Sn…C1 distances of 0.3591 (2) nm and the tin atom is five-coordinated in a distorted trigonal bipyramid configuration. 相似文献