Liquid chromatographic determination of 4,4'-dinitrocarbanilide, the active component of the infertility agent nicarbazin, in chicken, duck, goose, and snake eggs

4,4'-Dinitrocarbanilide (DNC) was extracted from chicken, duck, goose, and snake eggs and isolated by reversed-phase liquid chromatography. DNC was detected by ultraviolet absorbance at 347 nm and quantitated by comparison with a calibration standard. Recoveries of DNC from fortified control chicken, duck, goose, and snake egg samples were determined for DNC levels of 0.16, 10, and 16 microg/g. The mean recoveries from chicken, duck, goose, and snake eggs were 92 +/- 4, 88 +/- 9, 87 +/- 7, and 95 +/- 6%, respectively. The method limits of detection for DNC in chicken, duck, goose, and snake eggs ranged from 0.015 to 0.035 microg/g. The reported method is much simpler than and equally efficient as previous methods developed for the determination of DNC residues in egg contents.     

Chemical Composition of Volatile Compounds in Apis mellifera Propolis from the Northeast Region of Pará State,Brazil

Propolis is a balsamic product obtained from vegetable resins by exotic Africanized bees Apis mellifera L., transported and processed by them, originating from the activity that explores and maintains these individuals. Because of its vegetable and natural origins, propolis is a complex mixture of different compound classes; among them are the volatile compounds present in the aroma. In this sense, in the present study we evaluated the volatile fraction of propolis present in the aroma obtained by distillation and simultaneous extraction, and its chemical composition was determined using coupled gas chromatography, mass spectrometry, and flame ionization detection. The majority of compounds were sesquiterpene and hydrocarbons, comprising 8.2–22.19% α-copaene and 6.2–21.7% β-caryophyllene, with additional compounds identified in greater concentrations. Multivariate analysis showed that samples collected from one region may have different chemical compositions, which may be related to the location of the resin’s production. This may be related to other bee products.     

Linearization of the interaction principle: Analytic Jacobians in the “Radiant” model

In this paper we present a new linearization of the Radiant radiative transfer model. Radiant uses discrete ordinates for solving the radiative transfer equation in a multiply-scattering anisotropic medium with solar and thermal sources, but employs the adding method (interaction principle) for the stacking of reflection and transmission matrices in a multilayer atmosphere. For the linearization, we show that the entire radiation field is analytically differentiable with respect to any surface or atmospheric parameter for which we require Jacobians (derivatives of the radiance field). Derivatives of the discrete ordinate solutions are based on existing methods developed for the LIDORT radiative transfer models. Linearization of the interaction principle is completely new and constitutes the major theme of the paper. We discuss the application of the Radiant model and its linearization in the Level 2 algorithm for the retrieval of columns of carbon dioxide as the main target of the Orbiting Carbon Observatory (OCO) mission.     

Low-loss chalcogenide waveguides on lithium niobate for the mid-infrared

We demonstrate low-loss chalcogenide (As(2)S(3)) waveguides on a LiNbO(3) substrate for the mid-IR wavelength (4.8 μm). Designed for single-mode propagation, they are fabricated through photolithography and dry-etching technology and characterized on a mid-IR measurement setup with a quantum cascade laser. For straight waveguides, propagation loss as low as 0.33 dB/cm is measured and low-loss bends on the order of 100 μm are simulated, with measurement results showing <3 dB for a 250 μm bend radius. The coupling efficiency is estimated to be 81%. In addition, the influences of variations in width and bend radius are also investigated.     

Structure, morphology, and thermal properties of nanocomposites based on polyamido imide and hydrosilicate nanotubes

New nanocomposites based on heat-resistant poly[(diphenyl oxide)amido-N-phenylphthalimide] with Mg₃Si₂O₅(OH)₄ hydrosilicate nanoparticles of tubular structure were prepared. The structure, morphology, and thermal properties of the nanocomposites were studied in relation to the content of hydrosilicate nanotubes.     

Calculation of Jacobians for inverse radiative transfer: An efficient hybrid method

We present an accurate and numerically efficient procedure of calculating Jacobians by finite difference that consists of two components: (1) a method employing the saving of atmospheric layers that accelerates the solution to the equation of radiative transfer for solvers that use the Discrete Space formulation and (2) a method of perturbing the eigenmatrix spectrum associated with a reduced attenuation matrix. The procedure eliminates the need to call the eigenmatrix package, here, LAPACK a second time and provides insights into the fundamental properties of the attenuation matrix, useful for characterizing the accuracy of the derivatives calculated by finite difference methods. The computational complexity of the perturbation method is 8n³+22n², where n is one half the number of streams in the radiance field as opposed to 16n³ using LAPACK. The method is not limited to the calculation of base state radiances I(ω) and those associated with an ‘infinitesimal’ perturbation I(ω+δω) (from which the numerical derivative of I(ω+δω) with respect to δω may be approximated), but is also useful in the calculation of radiances associated with a ‘finite’ perturbation I(ω+Δω) from which a sensitivity can be calculated.     

Note on wavefront dislocation in surface water waves

At singular points of a wave field, where the amplitude vanishes, the phase may become singular and wavefront dislocation may occur. In this Letter we investigate for wave fields in one spatial dimension the appearance of these essentially linear phenomena. We introduce the Chu-Mei quotient as it is known to appear in the ‘nonlinear dispersion relation’ for wave groups as a consequence of the nonlinear transformation of the complex amplitude to real phase-amplitude variables. We show that unboundedness of this quotient at a singular point, related to unboundedness of the local wavenumber and frequency, is a generic property and that it is necessary for the occurrence of phase singularity and wavefront dislocation, while these phenomena are generic too. We also show that the ‘soliton on finite background’, an explicit solution of the NLS equation and a model for modulational instability leading to extreme waves, possesses wavefront dislocations and unboundedness of the Chu-Mei quotient.     

The acoustic and perceptual effects of two noise-suppression algorithms

Internal noise generated by hearing-aid circuits can be audible and objectionable to aid users, and may lead to the rejection of hearing aids. Two expansion algorithms were developed to suppress internal noise below a threshold level. The multiple-channel algorithm's expansion thresholds followed the 55-dB SPL long-term average speech spectrum, while the single-channel algorithm suppressed sounds below 45 dBA. With the recommended settings in static conditions, the single-channel algorithm provided lower noise levels, which were perceived as quieter by most normal-hearing participants. However, in dynamic conditions "pumping" noises were more noticeable with the single-channel algorithm. For impaired-hearing listeners fitted with the ADRO amplification strategy, both algorithms maintained speech understanding for words in sentences presented at 55 dB SPL in quiet (99.3% correct). Mean sentence reception thresholds in quiet were 39.4, 40.7, and 41.8 dB SPL without noise suppression, and with the single- and multiple-channel algorithms, respectively. The increase in the sentence reception threshold was statistically significant for the multiple-channel algorithm, but not the single-channel algorithm. Thus, both algorithms suppressed noise without affecting the intelligibility of speech presented at 55 dB SPL, with the single-channel algorithm providing marginally greater noise suppression in static conditions, and the multiple-channel algorithm avoiding pumping noises.