Facile fabrication of pomponlike microarchitectures of lanthanum molybdate via an ultrasound route

Pomponlike La₂(MoO₄)₃ microstructures assembled with single-crystalline nanoflakes have been facilely fabricated via a surfactant-assisted ultrasound route for the first time. Various synthesis conditions were examined, such as the surfactant concentration, the molecular structure of surfactants, and the pH value. The obtained pomponlike microstructures were characterized by X-ray diffraction (XRD), (field-emission) scanning electron microscopy [(FE)SEM], transmission electron microscopy (TEM), and nitrogen adsorption/desorption isotherms. It has been revealed that a minimum concentration of sodium dodecylsulfate (SDS) was required for the formation of pomponlike La₂(MoO₄)₃ microstructures. When the SDS concentration is above 0.02 mol L⁻¹, the pomponlike microstructures become more perfect, and the size is also increased with the increasing SDS concentration. Under the same sonication, similar pomponlike microstructures were obtained when a cationic surfactant, cetyltrimethyl ammonium bromide (CTAB), was used instead of the anionic surfactant SDS, indicating that the hydrophobic alkyl chains are an important factor for the formation of the pomponlike La₂(MoO₄)₃ microstructures. It is also found that the pomponlike La₂(MoO₄)₃ microstructures can only be obtained within an optimal pH range of 8.0–9.0 under sonication. Based on TEM, Fourier transform infrared spectroscopy (FT-IR) and solubilization experiment, a formation mechanism of pomponlike La₂(MoO₄)₃ microstructures was proposed, in which the collaborative action of surfactants and sonication plays a key role. Furthermore, the porosity of the pomponlike La₂(MoO₄)₃ microstructures were discussed.     

基于MXenes的功能纤维的制备及其在智能可穿戴领域的应用

在电子信息和物联网技术的推动下,人类对可穿戴电子器件和智能织物的需求愈发突出,功能纤维作为智能可穿戴设备的重要载体,近年来获得快速发展。功能纤维的性能很大程度上取决于纤维的基础构筑单元。过渡金属碳/氮化物(MXenes)作为一种新兴的二维材料,凭借其高电导率、优异的可加工性能、可调节的表面特性以及出色的机械强度等优点,受到了极大的关注,也逐渐成为构筑功能纤维的重要单元。本文将主要综述MXenes的湿化学、熔融盐、无氟试剂刻蚀等方法和力学、电学、光学和化学稳定性等性能,阐述基于该材料制备的功能纤维在传感、储能以及其他智能领域的应用,最后讨论了基于MXenes材料的功能纤维的未来应用前景和技术挑战。     

Insulating Polymers as Additives to Bulk-Heterojunction Organic Solar Cells: The Effect of Miscibility

Adding insulating polymers to conjugated polymers is an efficient strategy to tailor their mechanical properties for flexible organic electronics. In this work, we selected two insulating polymers as additives for high-performance photoactive layers and investigated the mechanical and photovoltaic properties in organic solar cells (OSCs). The insulating polymers were found to reduce the electron mobilities in the photoactive layers, and hence the power conversion efficiencies were significantly decreased. More importantly, we found that the insulating polymers exhibited negative effect on the mechanical properties of the photoactive layers, with reduced Young's modulus and low crack onset strains. Further studies revealed that the insulating polymers had poor miscibility with the photoactive layers, providing large domains and more cavities in blend thin films, which act as negative effect for the tensile test. The studies indicate that rational selection of insulating polymers, especially enhancing the non-covalent interaction with the photoactive layers, will be critically important for the stretchable OSCs.     

UV-light irradiation preparation of soybean residue-based hydrogel composite from inorganic/organic hybrids for degradable slow-release N-fertilizer

Research on Chemical Intermediates - Biomass waste, which was the by-product generated along with the production of food, was transformed into high-value constituent in slow-release fertilizers....     

一维亚波长周期结构物成像的光子学研究

当用波长为λ的单色平行光垂直照射到光栅常数d<λ的亚波长周期结构衍射物时,会产生隐失波。由于快速衰减,这种亚波长周期物是不能成像的。但是,通过对亚波长周期结构物进行适当的编码后可得到均匀波,使这种携带了隐失波信息的均匀波通过经特别设计的光学系统并被放大到CCD所能识别的像素大小后,再进行必要的解码以滤掉编码波,即可得到原亚波长周期结构衍射物的像,最终达到超分辨的目的。基于这种新颖的成像技术,用常规仪器就实现了对亚波长周期结构物的成像。在运用光子学方法对实验和成像过程进行较为详尽的理论分析的同时,对编码器、解码器的位置以及它们相对物光栅的取向给出了设计性研究,对滤波器的选择给予了必要的说明。实验结果验证了该设计理论的正确性。     

废旧隔膜衍生碳负极的电化学储锂性能

以废隔膜为前体,通过一步热解碳化制备碳负极材料,考察了温度和时间对碳化产物的影响,并研究了碳负极材料的电化学储锂性能.结果 表明,废隔膜的最佳碳化温度为420℃,碳化时间为120 min;用作锂离子电池负极材料时,在50 mA/g低电流密度充/放电时的可逆放电比容量高达543.8 mAh/g;即使在高电流密度2000 mA/g循环1000圈后,可逆放电比容量仍可稳定在125.0 mAh/g左右,表现了良好的电化学储锂性能.该研究结果不仅有助于缓解废旧隔膜对环境产生的危害,而且能充分发挥废弃资源中的利用价值、降低电极材料的制备成本.     

梯度折射率棒透镜的色差模型

本文提出一个梯度折射率棒透镜(GRIN－RodLens)的色差模型,并运用本模型合理地解释了在色差测量过程发现的各类色差现象.     

基于叠栅技术的二维亚波长周期结构成像设计

用光子学方法研究了叠栅技术中,当试件光栅被拉压和旋转后,叠栅条纹的空间周期和相对于基准光栅的取向,试件光栅被拉压后的节距等相关问题。根据衍射光波的空间周期可能大于试件光栅空间周期的特点,对二维亚波长周期结构衍射成像进行了设计研究。首先,对二维亚波长周期结构衍射物进行编码,以获得包含编码光栅空间信息的均匀波;其次,使编码得到的均匀波通过光学系统,并被放大到CCD相机所能辨识的大小;再次,经解码光栅解码,滤掉编码波,最终获得二维亚波长周期结构物的空间结构信息,达到超分辨的目的。同时,对成像过程进行了较为详尽的分析,对编码器、解码器的位置以及它们相对衍射物的取向进行了设计研究,对滤波器的选择给予了必要的说明,指出了取得超分辨成像的关键。     

A Schr(o)idinger formulation research for light beam propagation

The wave equation of light beam propagation was written in the form of an axial-coordinate-dependent Schrdinger equation, and the expectation value of a dynamical variable, the trial function of variational approach and the ABCD law were discussed by use of quantum mechanics approach. In view of the evolution equations of expectation values of dynamical variables in the framework of quantum mechanics, the definition of a potential function representing the beam propagation stability and its universal formula with the quality factor, the universal formula of beam width and curvature radius for a paraxial beam and cylindrically symmetric non-paraxial beam, the general formula of second derivative of beam width with respect to the axial coordinate of beam for a paraxial beam, and the general criteria of the conservation of beam quality factor and the existence of a potential well of a potential function for a paraxial beam, were given or derived, respectively. Starting with the same trial function, the comparative research of our formulation with variational approach was done, which gave some further insight into the physical nature of a beam propagation parameters. The ABCD law of non-paraxial beam was discussed in terms of the definition of the non-paraxial expectation value of a dynamical variable for the first time. The applications to the media of constant second derivative of beam width with respect to the axial coordinate of a beam, square law media and the media of constant refractive index in the momentum representation were discussed, respectively.