排序方式: 共有55条查询结果,搜索用时 15 毫秒
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Ji X Wang C Xu J Zheng J Gattás-Asfura KM Leblanc RM 《Langmuir : the ACS journal of surfaces and colloids》2005,21(12):5377-5382
Trioctylphosphine oxide- (TOPO-) capped (CdSe)ZnS quantum dots (QDs) were prepared through a stepwise synthesis. The surface chemistry behavior of the QDs at the air-water interface was carefully examined by various physical measurements. The surface pressure-area isotherm of the Langmuir film of the QDs gave an average diameter of 4.4 nm, which matched very well with the value determined by transmission electron microscopy (TEM) measurements if the thickness of the TOPO cap was counted. The stability of the Langmuir film of the QDs was tested by two different methods, compression/decompression cycling and kinetic measurements, both of which indicated that TOPO-capped (CdSe)ZnS QDs can form stable Langmuir films at the air-water interface. Epifluorescence microscopy revealed the two-dimensional aggregation of the QDs in Langmuir films during the early stage of the compression process. However, at high surface pressures, the Langmuir film of QDs was more homogeneous and was capable of being deposited on a hydrophobic quartz slide by the Langmuir-Blodgett (LB) film technique. Photoluminescence (PL) spectroscopy was utilized to characterize the LB films. The PL intensity of the LB film of QDs at the first emission maximum was found to increase linearly with increasing number of layers deposited onto the hydrophobic quartz slide, which implied a homogeneous deposition of the Langmuir film of QDs at surface pressures greater than 20 mN.m(-1). 相似文献
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Li Limin Zhao Gaoyang Lei Li Li Chengshan 《Journal of Sol-Gel Science and Technology》2021,100(3):414-422
Journal of Sol-Gel Science and Technology - Herein, the chelated precursor solution (Mg/BzAc) was synthesized using magnesium acetate as raw material and benzoylacetone as chemical modifier. The... 相似文献
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Zong Fujian Ma Honglei Xue Chengshan Zhuang Huizhao Zhang Xijian Ma Jin Ji Feng Xiao Hongdi 《中国科学:物理学 力学 天文学(英文版)》2005,48(2):201-210
Science China Physics, Mechanics & Astronomy - Zinc nitride (Znb3Nb2) powder has been synthesized through the nitridation reaction of Zn powder with NH3 gas (at the flow rate of 500 ml/min) at... 相似文献
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A new frequency-domain channel estimation and equalization (FDE) scheme, combined with a new group-wise phase correction scheme, is proposed for single-carrier (SC) underwater acoustic communications systems employing single transducer and multiple hydrophones. The proposed SC-FDE scheme employs a 2N-point Fast Fourier Transform (FFT) to estimate and equalize the channel in frequency domain, where N is the number of symbols in a data block. Both the frequency-domain channel estimation and equalization are designed by the linear minimum mean square error criterion. Initial channel estimation is performed by a pilot signal block and later updates are achieved using the detected data blocks. The proposed phase correction scheme utilizes a few pilot symbols in each data block to estimate the initial phase shift and then correct it for the block to combat the large phase rotation due to the instantaneous Doppler drifts in the acoustic channels. Time-varying instantaneous phase drifts are re-estimated and compensated adaptively by averaging the phase variation across a group of symbols. The proposed SC-FDE and phase correction method is applied to the AUVFest’07 experimental data measured off the coast of Panama City, Florida, USA, June 2007. With the Quadrature Phase Shift Keying (QPSK) modulation and a symbol rate of 4 ksps, the proposed scheme achieves an average uncoded bit error rate on the order of 1×10?4 for fixed-to-fixed channels with the source–receiver range of 5.06 km. For the moving-to-fixed source–receiver channels where the source–receiver range is 1–3 km, the multipath delay spread is 5 ms, the average Doppler shifts are ±20 Hz, and the maximum instantaneous Doppler drifts from the mean is ±4 Hz, the proposed scheme achieves an average uncoded bit error rate on the order of 1×10?3. 相似文献
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Surface properties of "jellyfish": Langmuir monolayer and Langmuir-Blodgett film studies of recombinant aequorin 总被引:1,自引:0,他引:1
Wang C Micic M Ensor M Daunert S Leblanc RM 《Langmuir : the ACS journal of surfaces and colloids》2007,23(14):7602-7607
In this paper, we studied the surface properties of recombinant aequorin at the air-water interface. Using the Langmuir monolayer technique, the surface properties of aequorin were studied, including the surface pressure and surface potential-area isotherms, compression-decompression cycles, and stability on Trizma Base (Tris/HCl) buffer at pH 7.6. The results showed that aequorin formed a stable Langmuir monolayer and the surface pressure-area isotherms were dependent on both pH and ionic strength. At a pH higher or lower than 7.6, the limiting molecular area decreased. The circular dichroism (CD) spectra of aequorin in aqueous solutions explained this result: when the pH was higher than 7.6, the alpha-helix conformation changed to unordered structures, whereas at a pH lower than 7.6, the alpha-helix conformation changed to beta-sheet. The addition of calcium chloride to the Tris/HCl buffer subphase (pH 7.6) caused an increase of the limiting molecular area of the aequorin Langmuir monolayer. The fluorescence spectra of a Langmuir-Blodgett (LB) film of aequorin in the presence of calcium chloride indicated that the aequorin transformed to the apoaequorin. 相似文献
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Yuewei Wu Chaoxian Yan Dongxu Li Chengshan Yuan Jibin Sun Shuyun Zhou Hao‐Li Zhang Xiangfeng Shao 《化学:亚洲杂志》2019,14(10):1860-1869
Four tetraphenylethylenes ( 2 a – d ) containing an electron‐rich 2,3,4,6‐tetrahydro‐1,6‐dithia‐3a‐azaphenalene (THDTAP) moiety have been synthesized. The 2 a – d show aggregation‐induced emission (AIE) with yellowish green photoluminescence (PL) in THF‐H2O (v/v, 1:9) solution and in the solid state. Compounds 2 a – d undergo 1,2‐migratory shift in oxidative cyclodehydrogenation reactions to afford the unexpected products 3 a – d which display green PL in CH2Cl2 solution and are non‐emissive in the solid state. The PL intensities of 3 a – d are clearly enhanced in the presence of meta‐chloroperoxybenzoic acid (mCPBA) owing to the oxidation of the S‐atoms on the THDTAP moiety. In contrast, the PL of 2 a – d in THF‐H2O (v/v, 1:9) solution is quenched by adding mCPBA, ascribable to the oxidation of the C=C bond on the ethylene moiety. It is found that the absorption of 3 a – d is distinctly red‐shifted from the UV/Vis region to the NIR region upon acidification, arising from the protonation of the N‐atom on the THDTAP moiety. Furthermore, 3 a – d display nonlinear optical response (NLO) and optical limiting (OL) behaviour which is superior to that of the well‐known OL material C60. 相似文献
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光衍射数值模拟中不同抽样方法的适用性分析 总被引:5,自引:2,他引:3
基于标量衍射理论和快速傅里叶变换,分析了光衍射的数值模拟时可以采用的不同抽样方法及其适用性。理论分析表明,按照抽样对象的不同,存在三种适用范围不同的算法:传递函数抽样法、点扩展函数抽样法和加权函数抽样法。其适用范围分别为衍射距离小于、大于和等于特征距离的情况。在Matlab软件环境下给出了三种算法的模拟计算实例,并与相应的实验结果进行了比较,证明了理论分析的正确性。最后还给出了一种无需改变抽样点数和抽样间隔就可计算任意距离衍射过程的自适应抽样算法及其在数字全息再现中的应用实例。 相似文献
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由于铁基超导体含有铁磁性元素以及具有极高的上临界场等特性,引发了科学家对其理论和实用化研究的热潮.铁基超导体主要分为四个体系:“1111”体系、“122”体系、“111”体系和“11”体系.其中,“11”体系中的FeSe基超导材料由于结构简单、单晶制备容易以及不含有毒元素等优势,使其成为了研究铁基超导材料的热门体系,同时也成为了新型实用化超导材料的研究热点.本文在简要介绍铁基超导材料和FeSe基超导材料的基础上,重点介绍了实用化FeSe基超导材料多晶块体、线带材以及薄膜在制备工艺以及性能等方面的研究进展,最后对其相关领域今后的发展做出展望. 相似文献