一类具功能反应的食饵——捕食者系统定性分析

研究一类具功能反应的食饵-捕食者系统:x=xg(x)-y(?)(x),y=y(-d+e(?)(x)．在g(x)=α-bxm,(?)(x)=cxθ及m+θ=1,m=1/n,n>2为正整数情形下,分析了该系统的平衡点性态,并得到了系统在正平衡点外围的极限环的不存在性、存在性与唯一性的相关条件．     

Study on the adsorption performance of zeolitic imidazolate framework-8 (ZIF-8) for Co2+ and Mn2+

Journal of Radioanalytical and Nuclear Chemistry - In this work, zeolitic imidazolate framework-8 (ZIF-8) with a microporous structure for 60Co and 54Mn adsorption was prepared at room temperature,...     

Thermoresponsive poly(ionic liquid): Controllable RAFT synthesis,thermoresponse, and application in dispersion RAFT polymerization

The thermoresponsive poly(ionic liquid) of poly[1‐(4‐vinylbenzyl)‐3‐methylimidozolium tetrafluoroborate] trithiocarbonate (P[VBMI][BF₄]‐TTC) showing the soluble‐to‐insoluble phase transition in the methanol/water mixture at the upper critical solution temperature (UCST) was synthesized by solution RAFT polymerization and the synthesized P[VBMI][BF₄]‐TTC was employed as macro‐RAFT agent to mediate the RAFT polymerization under dispersion condition to afford the thermoresponsive diblock copolymer nanoparticles of poly[1‐(4‐vinylbenzyl)‐3‐methylimidozolium tetrafluoroborate]‐b‐polystyrene (P[VBMI][BF₄]‐b‐PS). The controllable solution RAFT polymerization was achieved as indicated by the linearly increasing polymer molecular weight with the monomer conversion and the narrow molecular weight distribution. The P[VBMI][BF₄]‐TTC macro‐RAFT agent mediated dispersion polymerization afforded the P[VBMI][BF₄]‐b‐PS nanoparticles, the size of which was uncorrelated with the polymerization degree of the P[VBMI][BF₄] block. Several parameters including the polymerization degree, the polymer concentration and the water content in the solvent of the methanol/water mixture were found to be correlated with the UCST of the poly(ionic liquid). The synthesized poly(ionic liquid) is believed to be a new thermos‐responsive polymer and will be useful in material science. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 945–954     

基于密度泛函理论研究碱性水溶液中乙内酰脲及其衍生物的结构及性质

乙内酰脲及其衍生物对多种金属离子具有良好的络合效果,是一种有望取代氰化物的绿色电镀络合剂.本文以密度泛函理论(DFT)方法对乙内酰脲及其衍生物的反应活性进行了研究.通过分子极性指数和极性表面积所占总面积百分比研究多种乙内酰脲衍生物在水中的溶解性,理论计算结果与文献报道的实验结果基本一致.通过原子电荷、表面静电势、原子对...     

High-power high-repetition-rate acousto-optically Q-switched 1342 nm laser

A high-power high-repetition-rate acousto-optically Q-switched 1342 nm laser with double Nd:YVO₄ crystals pumped by fiber-coupled laser diodes is presented. The highest output power of 13.7 W was achieved with a total of 42 W pumping power in cw operation, the slope efficiency was measured as 36%, and the optical efficiency was better than 32%. In Q-switchedoperation, the highest pulse repetition rate of 100 kHz was obtained. At 50 kHz repetition rate, the laser exported 11.2 W average output power, with 60 ns average pulse width, ∼5% width stability (RMS) and ∼8% peak-power stability (RMS). At 10 kHz repetition rate, the highest average output power was measured as 6.3 W, single pulse energy was calculated as 0.63 mJ, with pulse width of 19 ns and peak-power higher than 30 kW. Combining the experimental results, we analyze and discuss some problems concerning Nd:YVO₄ crystal working at 1,342 nm wavelength. PACS 42.55.-f; 42.55.Xi; 42.60.Gd     

基于双柱透镜慢轴准直激光二极管堆栈光束匀化系统

为实现高功率激光二极管堆栈光束的匀化与整形,提出基于双柱透镜慢轴准直的匀化系统。利用双柱透镜实现对高填充因子激光二极管慢轴方向光束发散角度的压缩,降低成像型多孔径光束积分器中微透镜的数值孔径,减小匀化系统体积。通过三个限定条件确定了双柱透镜参数取值范围,并通过像差分析对双柱透镜进行了优化,实现慢轴方向光束剩余发散角度1.74。结合成像型多孔径光束积分器,设计了激光二极管堆栈的匀化系统,并进行了实验测试。实验结果表明,在中心光斑尺寸约为6 mm6 mm范围内,光斑不均匀性为8.11%。     

An Original Monomer Sampling from a Ready-Made Aβ42 NMR Fibril Suggests a Turn-β-Strand Synergetic Seeding Mechanism

Aggregation of amyloid beta (Aβ) is a central step of Alzheimer's disease. Aβ42 monomers are building blocks in the formation of both “on pathway” intermediate structures and “off pathway” oligomers. How to sample an Aβ monomer becomes a problem however due to the instinct of Aβ high flexibility and diversity as well as aggregation propensity. Currently, (1) most samplings focus on either the ready-made helix-rich 1Z0Q/1IYT NMR structure, or the completely extended conformation, but (2) few on a ready-made Aβ NMR fibril (i. e., 2BEG). Here we compare the simulation results from sampling in scheme (1) with that in scheme (2), and find that the coil and β-sheet contents in the 1Z0Q-sampled system are comparable to the counterparts in the 2BEG-sampled system, but with a large difference in simulation time and dynamics character. 1Z0Q-sampled system not only takes several times longer than the 2BEG-sampled one, and only β1-seeding dynamics characteristic is observed probably due to far insufficient conformation transition in the limited simulation time. Two dynamics characteristics of Aβ42 folding observed experimentally, that either β1 region or β2 region aggregates first, reproduce in the present simulations for 2BEG-sampled system however, suggesting a preferential sampling in the future simulation. In addition, a turn-β-strand synergetic seeding mechanism of aggregation is first proposed based on the trajectory analyses on the four regions of Aβ42 chain.     

Field enhancement effect of metal probe in evanescent field

Field enhancement effect of metal probe in evanescent field, induced by using a multi-layers structure for exciting surface plasmon resonance （SPR）, is analyzed numerically by utilizing two-dimensional （2D） TM- wave finite difference time-domain （FDTD） method. In this letter, we used a flmdamental mode Gaussian beam to induce evanescent field, and calculated the electric intensity. The results show that compared with the nonmetal probe, the metal probe has a larger field enhancement effect, and its scattering wave induced by field enhancement has a bigger decay coefficient. The field enhancement effect should conclude that the metal probe has an important application in nanolithography.     

声光调Q的Nd:YVO4晶体1342 nm激光器

报道了采用光纤耦合激光二极管(LD)模块端面抽运Nd:YVO4晶体实现高功率、高重复频率声光调Q 1342 nm波长的激光输出,以及采用考虑增益频谱分布的调Q速率方程模型仿真研究该脉冲激光器的结果.在激光器注入总功率40 W的情况下,可得到最高工作重复频率100 kHz;在50 kHz重复频率工作条件下,可得到11.0 W的平均输出功率及稳定的脉冲输出.应用与介质增益频谱相关的调Q速率方程模型对该脉冲激光器进行了仿真研究,得到了脉冲宽度、脉冲峰值功率、脉冲建立时间等计算结果,还给出了输出在频谱上的分布以及谱宽,并与实验结果进行了比较.考虑增益频谱分布的调Q速率方程模型不仅可以应用于分析、设计脉冲激光器的频谱,而且由于考虑了增益在频谱上的实际分布,基于该模型的仿真计算可以获得比传统单频调Q速率方程更为接近实际的结果.