Modification of magnetic anisotropy in metallic glasses using high-energy ion beam irradiation

Heavy ion irradiation in the electronic stopping power region induces macroscopic dimensional change in metallic glasses and introduces magnetic anisotropy in some magnetic materials. The present work is on the irradiation study of ferromagnetic metallic glasses, where both dimensional change and modification of magnetic anisotropy are expected. Magnetic anisotropy was measured using Mössbauer spectroscopy of virgin and irradiated Fe₄₀Ni₄₀B₂₀ and Fe₄₀Ni₃₈Mo₄B₁₈ metallic glass ribbons. 90 MeV ¹²⁷I beam was used for the irradiations. Irradiation doses were 5×10¹³ and 7.5×10¹³ ions/cm². The relative intensity ratios D ₂₃ of the second and third lines of the Mössbauer spectra were measured to determine the magnetic anisotropy. The virgin samples of both the materials display in-plane magnetic anisotropy, i.e., the spins are oriented parallel to the ribbon plane. Irradiation is found to cause reduction in magnetic anisotropy. Near-complete randomization of magnetic moments is observed at high irradiation doses. Correlation is found between the residual stresses introduced by ion irradiation and the change in magnetic anisotropy.     

Development of a direct radioimmunoassay for serum progesterone

A direct radioimmunoassay for the measurement of progesterone in human serum is described. Progesterone 11-hemisuccinate was conjugated to tyrosine methyl ester (TME) by the mix anhydride method and then iodinated using chloramine-T. The radiochemical purity of different batches of¹²⁵I-progesterone was greater than 95% and showed 70–75% binding with excess antibody. Progesterone 11-hemisuccinate was coupled with BSA and injected to rabits. Antisera collected after three booster injections and having aK value of 1·10⁹1/M was selected for the assay. Significant reduction in binding with antibody was seen when hormone free serum was used in the assay system. Various blocking agents were tried to reduce the serum effects and none of them were found satisfactory. From a series of optimization experiments, an assay was developed without the use of blocking agents. This assay used a much higher concentration of antibody along with lower amount of serum sample (50 l). The optimized assay has a sensitivity of 0.5 nj/ml and a working range of 0.5 to 100 ng/ml. Serum samples were analyzed analysis showed good correlation between the results obtained from the present system and the DPC kit. (Y=0.93X+0.5,r=0.93, forn=25).     

Epitaxial electrodeposition of Prussian blue thin films on single-crystal Au(110)

Epitaxial Prussian blue (PB) films are deposited electrochemically onto a Au(110) substrate. High-resolution X-ray diffraction shows that the PB films have a [111] out-of-plane orientation. The very large lattice mismatch of 148% is reduced to about 1% by the formation of (1 x 2)PB(111)[onemacr;10]//(6 x 5)Au(110)[onemacr;10] and (1 x 2)PB(111)[01onemacr;]//(6 x 5)Au(110)[onemacr;10] epitaxial relationships. Peaks in the cyclic voltammogram of PB on Au(110) are sharper than those on polycrystalline Au, consistent with higher structural order and a single out-of-plane orientation. The development of epitaxial films of PB and PB analogues will allow the measurement of the orientation-dependent properties of these molecular magnets. It will also open the door to the development of novel molecular spintronic devices, such as those which exhibit spin-dependent electron transfer.     

Synthesis of some newer 5-(5-aryl-2H-tetrazol-2-ylmethyl)-4-substituted-s-triazole-3-thiols as possible antiinflammatory agents

Several 1-(5-aryl-2H-tetrazol-2-ylacetyl)-4-substituted thiosemicarbazides and 5-(5-aryl-2H-tetrazol-2-yl-methyl)-4-substituted-s-triazole-3-thiols were synthesized as possible antiinflammatory agents. These compounds were characterized by their elemental, infrared and nuclear magnetic resonance analysis.     

Use of liquid chromatography for separation and determination of carrier species associated with the synthesis of no carrier-added11C-labelled compounds determination of the specific activity of {11C} urea

An analytical technique using reversed-phase liquid chromatography has been developed for the determination of urea at quantities as low as 1 ng to quantitate the amount of non-labelled urea produced during the synthesis of no-carrier-added {¹¹C}urea starting from¹¹CN^–. As a result, the specific activity of the {¹¹C} urea thus prepared was calculated to be as high as 3.5±0.8 Ci/mol.Research supported in part by PHS Grant NINCDS 1 PO1 NS 15639.     

Experimental investigation of drying of garlic clove in solar dryer using phase change material as energy storage

This investigation deals with thermodynamic analysis, which offers an alternative approach to evaluate the performance of solar dryers and thin-layer drying characteristics of garlic cloves in a developed system. The garlic cloves were dried from a moisture content of 55.5 % (w.b.) to 6.5 % (w.b.) for 8 h. The drying data obtained were fitted to five different drying kinetics models. Of these, the model suggested by Midilli et al. [28] had the best fit with the drying behavior of garlic cloves. The energy efficiency without and with recirculation of the air exiting the drying chamber during the study varied from 43.06 to 83.73 %, and 3.98 to 14.95 %, respectively, while the exergy efficiency corresponding to the energy efficiency of the drying process ranged from 5.01 to 55.30 % and 67.06 to 88.24 %, respectively.     

Correlation analysis of reactivity in the addition of substituted benzylamines to ethyl α-cyanocinnamate

The kinetics of addition of a number of ortho-, meta-, and para-substituted benzylamines to ethyl α-cyanocinnamate (ECC) in acetonitrile have been studied. The reaction is first-order with respect to the amine and ECC. The rates of reaction of meta- and para-substituted benzylamines showed excellent correlations with Taft's σ₁ and σ_R⁰, and with σ₁ and σ_R^BA values, respectively. The reaction of the ortho-compounds showed a very good correlation with Charton's triparametric equation. The reaction is subject to steric hindrance by the ortho-substituents. A mechanism involving formation of a zwitterionic intermediate in a slow step followed by a fast proton transfer has been proposed. © 1996 John Wiley & Sons, Inc.     

Electrical characterization of strontium tartrate single crystals

The a.c. and d.c. conductivity of SrC₄H₄O₆·3H₂O are measured and are found to lie between usual conductivities of semiconductor and insulator. Temperature dependence of d.c. conductivity shows intrinsic conduction, which is confirmed by the slope of versus data. Due to application of thermal energy, noticeable conductivity peaks imply liberation of water molecules during dehydration and the formation of strontium oxalate. The conductivity plot has a nature similar to the intrinsic-to-extrinsic transition found in normal semiconductors. There occurs Efros hopping conduction in our samples.