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Fernández-g Juan M. Acevedo-Arauz Elias Cetina-Rosado Raúl Toscano Rubén A. Macías-ruvalcaba Norma Aguilar-martínez Martha 《Transition Metal Chemistry》1999,24(1):18-24
Three Schiff base ligands and their corresponding copper(II) complexes have been prepared and characterized. Elemental analyses, mass spectra, i.r., electronic spectra, eff and the X- ray crystal structure for one of the complexes, as well as elemental analyses, mass spectra, i.r., electronic and 1H n.m.r. spectra of the ligands, have been obtained. The X-ray study shows that the geometry around the metal atom is intermediate between square planar and tetrahedral. Electrochemical studies on the complexes reveal a dependence of the CuII/CuI potentials on the extent of distortion of the planar structure observed in solid state. 相似文献
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