全文获取类型
收费全文 | 411篇 |
免费 | 6篇 |
国内免费 | 1篇 |
专业分类
化学 | 243篇 |
晶体学 | 4篇 |
力学 | 25篇 |
数学 | 40篇 |
物理学 | 106篇 |
出版年
2023年 | 6篇 |
2022年 | 9篇 |
2021年 | 12篇 |
2020年 | 5篇 |
2019年 | 9篇 |
2018年 | 7篇 |
2017年 | 7篇 |
2016年 | 6篇 |
2015年 | 7篇 |
2014年 | 6篇 |
2013年 | 24篇 |
2012年 | 24篇 |
2011年 | 23篇 |
2010年 | 14篇 |
2009年 | 11篇 |
2008年 | 21篇 |
2007年 | 17篇 |
2006年 | 25篇 |
2005年 | 19篇 |
2004年 | 14篇 |
2003年 | 16篇 |
2002年 | 9篇 |
2001年 | 4篇 |
2000年 | 6篇 |
1997年 | 7篇 |
1996年 | 6篇 |
1995年 | 9篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1992年 | 6篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1987年 | 4篇 |
1985年 | 8篇 |
1984年 | 10篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 6篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 3篇 |
1972年 | 2篇 |
1913年 | 2篇 |
1912年 | 2篇 |
1890年 | 2篇 |
1889年 | 1篇 |
排序方式: 共有418条查询结果,搜索用时 46 毫秒
1.
We report on the realization and characterization of electro-responsive and pressure sensitive polydimethylsiloxane (PDMS) conductive photonic structures combined with the reconfigurable properties of short pitch cholesteric liquid crystals (aligned in Grandjean configuration). By combining ion-implantation process and surface chemistry functionalization, we have overcome the insulating properties of PDMS and induced long range organization of cholesteric liquid crystals, thus controlling both diffraction and selective Bragg reflection of light by means of external perturbations (electric field, pressure). We have characterized our devices in terms of morphological, optical and electro-optical properties. 相似文献
2.
3.
4.
Demetrio Pitea Laura Bonati Elena Collina Ugo Cosentino Marina Lasagni Giorgio Moro Roberto Todeschini 《Fresenius' Journal of Analytical Chemistry》1994,348(1-2):111-120
Summary The role of multivariate analysis methods in evaluating, rationalizing, and working out complex environmental problems is discussed. The discussion is organized in two sections; a literature analysis of the application of chemometric methods to PCDD/PCDF data interpretation and source correlation and a review of the role of chemometric methods in analysing the results obtained by the Authors studying PCDD/PCDF formation and destruction mechanisms in MSW combustion processes. 相似文献
5.
Substrate relaxation is shown to play an important role in the 1 : 2 regular chemisorption of hydrogen atoms above alternate carbon atoms in a graphite monolayer. Binding energy, population analysis and electron density maps show that the direct HC bond is strengthened on relaxation. 相似文献
6.
7.
8.
Coppola L Gianferri R Oliviero C Ranieri GA 《Journal of colloid and interface science》2003,264(2):554-557
We report on the first rheological study of the structural relaxations in a nematic liquid crystalline phase. Linear dynamic and transient shear experiments were applied to a polydomain nematic phase of the CTAB/water system: a liquid crystalline mixture composed of 28 wt% CTAB at 35 degrees C. The decay of the shear modulus, G(t), was analyzed using the CONTIN inverse Laplace transform to obtain a distribution of relaxation times which were compared with ones from the usual fitting procedure based on a generalized Maxwell model. The behavior of the nematic lyotropic structure of the CTAB/water system is characterized by the presence of both slow and fast relaxation times. These were interpreted as being due to a progressive loss of the lyotropic domain orientation and to the breaking/reforming process of the cylindrical aggregates, respectively. 相似文献
9.
Kashiwada Y Chiyo J Ikeshiro Y Nagao T Okabe H Cosentino LM Fowke K Morris-Natschke SL Lee KH 《Chemical & pharmaceutical bulletin》2000,48(9):1387-1390
3-Alkylamido-3-deoxy-betulinic acids were synthesized and evaluated for anti-HIV activity as part of the structure-activity relationship study of the potent anti-HIV agent 3-O-(3',3'-dimethyl)-succinyl-betulinic acid (DSB) (2). 3Alpha-diglycorylamide-3-deoxy-betulinic acid demonstrated relatively potent anti-HIV activity (EC50 0.24 microm, TI 728). However, replacing the ester group at C-3 in 2 and its analogues with an amido group yielded inactive or much less potent compounds against HIV replication, indicating that the ester group at C-3 in 2-4 is essential for potent anti-HIV activity. 相似文献
10.
Cesare Oliva Anatoli V. Vishniakov Ivan E. Mukovozov Giorgio Termignone Lucio Forni 《Radiation Physics and Chemistry》1995,45(6):945-948
Evidence of quantum spin fluid and of quantum spin glass behaviour has been detected by extended EPR analysis in some La-cuprate catalysts of general formula La2−xEuxCuO4 + δ. Some features of the EPR spectrum, appearing in a few cases, are also discussed and attributed to a pseudo Jahn-Teller effect due to a particular coordination of up to five oxygen ions around surface copper ions at low temperature. 相似文献