全文获取类型
收费全文 | 1265篇 |
免费 | 56篇 |
国内免费 | 4篇 |
专业分类
化学 | 927篇 |
晶体学 | 14篇 |
力学 | 15篇 |
数学 | 94篇 |
物理学 | 275篇 |
出版年
2023年 | 11篇 |
2022年 | 27篇 |
2021年 | 43篇 |
2020年 | 27篇 |
2019年 | 28篇 |
2018年 | 27篇 |
2017年 | 23篇 |
2016年 | 48篇 |
2015年 | 34篇 |
2014年 | 34篇 |
2013年 | 69篇 |
2012年 | 60篇 |
2011年 | 91篇 |
2010年 | 52篇 |
2009年 | 45篇 |
2008年 | 67篇 |
2007年 | 69篇 |
2006年 | 53篇 |
2005年 | 50篇 |
2004年 | 61篇 |
2003年 | 56篇 |
2002年 | 56篇 |
2001年 | 21篇 |
2000年 | 25篇 |
1999年 | 6篇 |
1998年 | 5篇 |
1997年 | 17篇 |
1996年 | 16篇 |
1995年 | 9篇 |
1994年 | 14篇 |
1993年 | 20篇 |
1992年 | 19篇 |
1991年 | 10篇 |
1990年 | 25篇 |
1989年 | 11篇 |
1988年 | 14篇 |
1987年 | 11篇 |
1986年 | 11篇 |
1985年 | 6篇 |
1983年 | 7篇 |
1982年 | 7篇 |
1981年 | 7篇 |
1980年 | 3篇 |
1979年 | 6篇 |
1978年 | 4篇 |
1977年 | 4篇 |
1976年 | 4篇 |
1974年 | 2篇 |
1973年 | 2篇 |
1972年 | 2篇 |
排序方式: 共有1325条查询结果,搜索用时 31 毫秒
1.
Peralta Cecilia Mariana Acosta Gimena Henestrosa Cecilia Gil Raúl Andrés Fernández Liliana Patricia 《Journal of Analytical Chemistry》2022,77(3):308-317
Journal of Analytical Chemistry - The present development involved a flow injection strategy using a mini-column of multiwalled carbon nanotubes and fluorescent detection (λex of 283 nm,... 相似文献
2.
Ozonolysis of a Series of Methylated Alkenes: Reaction Rate Coefficients and Gas‐Phase Products 下载免费PDF全文
Tristan Braure Véronique Riffault Alexandre Tomas Romeo Iulian Olariu Cecilia Arsene Yuri Bedjanian Patrice Coddeville 《国际化学动力学杂志》2015,47(9):596-605
The gas‐phase ozonolysis of three methylated alkenes, i.e., trans‐2,2‐dimethyl‐3‐hexene (22dM3H), trans‐2,5‐dimethyl‐3‐hexene (25dM3H), and 4‐methyl‐1‐pentene (4M1P), has been investigated in the presence of sufficient hydroxyl radical scavenger in a laminar flow reactor at ambient temperature (296 ± 2 K) and P = 1 atm of dry air (RH ≤ 5%). Ozone levels in the reactor were monitored by an automatic analyzer. Alkene and gas‐phase product concentrations were determined via online sampling either on three‐bed adsorbent cartridges followed by thermodesorption and GC/FID‐MS analysis or on 2,4‐dinitrophenylhydrazine (DNPH) cartridges for subsequent HPLC/UV analysis. Reaction rate coefficients of (3.38 ± 0.12) × 10?17 for 22dM3H and (2.71 ± 0.26) × 10?17 for 25dM3H, both in cm3 molecule?1 s?1 units, have been obtained under pseudo–first‐order conditions. Primary carbonyl products have been identified for the three investigated alkenes, and branching ratios are reported. In the case of 4M1P ozonolysis, the yield of a Criegee intermediate was indirectly determined. Kinetics and product study results are compared to those of literature when available. This work represents the first investigation of reaction products in the ozonolysis of 22dM3H, 25dM3H, and 4M1P in a flow reactor. 相似文献
3.
Gujie Qian S. Baccaro M. Falconieri Jiafang Bei A. Cecilia Guorong Chen 《Journal of Non》2008,354(40-41):4626-4629
Glasses in SiO2–ZnO–BaO system with the different ZnO/BaO ratio were studied. In some cases, BaF2 was introduced to substitute for BaO on the equal base. Photoluminescent spectra showed that ZnO in glass matrices behaved somewhat differently from ZnO crystals. Especially, the introduction of fluorine ions led to dramatic shift of UV emission band of glasses closer to that of ZnO crystals. Raman spectral analysis provided consistent results. In particular, Raman bands in the high frequency region are sensitive to effects of different ZnO/BaO or BaF2/BaO ratio on structure of glasses. 相似文献
4.
The magnetic properties of existing amorphous iron based materials, i.e., Fe--metalloid, Fe--early transition metals and Fe--rare
earth alloys, are briefly discussed for some representative alloys. The spin orientation of amorphous Fe--metalloid alloys
has been determined by the angular dependence of hyperfine interactions. It is shown that in iron--early transition metals
ferromagnetic order is not long-ranged, but determined by magnetic clusters. The magnetic hyperfine field distributions of
Fe-rich iron--early transition metals consist of a high and a low field tail. The magnetic structure has been investigated
for two representative Fe--RE (RE = Er, Ce) amorphous alloys. For the first time, the magnetic coupling phenomenon in amorphous/crystalline
multilayers has been discussed.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
5.
A. Sánchez-Lavega A. Salazar A. Ocariz L. Pottier E. Gomez L.M. Villar E. Macho 《Applied Physics A: Materials Science & Processing》1997,65(1):15-22
Received: 16 September 1996/Accepted: 6 January 1997 相似文献
6.
This study demonstrates the separation of active ingredients in acne formulations (salicylic acid, cloramphenicol and resorcinol in presence of azulene) by capillary zone electrophoresis. Factors affecting their separations were the buffer pH and concentration, applied voltage, sample preparation, and presence of additives. Optimun results were obtained with a 50 mM sodium tetraborate-50 mM sodium phosphate, pH 9.0. The carrier electrolyte gave baseline separation with good resolution, short migration times (<6 min), great reproducibility and accuracy. Calibration plots were linear over at least three orders of magnitude of analyte concentrations, the lower limits of detection being within the range 0.39-1.25 μg ml−1. The procedure was fast and reliable and commercial pharmaceuticals could be analysed without prior sample clean-up procedure. 相似文献
7.
Summary Measurements on sea surface films were conducted during five separate experimental periods in the following marine areas:
the Sicilian Channel, the Gulf of Maine (spring and fall periods), Bermuda, and the Pacific Ocean West of Southern California.
The measurements consisted in surface elevation sampling using an interferential microwave probe with frequency spectra evaluation.
Wave spectra were performed for both clean and film-covered sea surface conditions to determine the wave attenuation ratio
within the 2–20 Hz spectral range. The method is able to detect, chart and characterize sea surface films. Theoretical analyses
of the results yield several viscoelastic film parameters: the modulus of elasticity, the relaxation frequency and the maximum
of the damping ratio as a function of wave frequency. The analysed data are interpreted to infer film weathering effects,
surface concentration of film-forming constituents, and compactness of the organic sea surface film. 相似文献
8.
Soderstrom E McKenna JA Abrams GS Adolphsen CE Averill D Ballam J Barish BC Barklow T Barnett BA Bartelt J Bethke S Blockus D Bonvicini G Boyarski A Brabson B Breakstone A Bulos F Burchat PR Burke DL Cence RJ Chapman J Chmeissani M Cords D Coupal DP Dauncey P DeStaebler HC Dorfan DE Dorfan JM Drewer DC Elia R Feldman GJ Fernandes D Field RC Ford WT Fordham C Frey R Fujino D Gan KK Gero E Gidal G Glanzman T Goldhaber G Gomez Cadenas JJ Gratta G Grindhammer G Grosse-Wiesmann P Hanson G Harr R 《Physical review letters》1990,64(25):2980-2983
9.
Komamiya S Abrams GS Adolphsen CE Averill D Ballam J Barish BC Barklow T Barnett BA Bartelt J Bethke S Blockus D Bonvicini G Boyarski A Brabson B Breakstone A Bulos F Burchat PR Burke DL Cence RJ Chapman J Chmeissani M Cords D Coupal DP Dauncey P DeStaebler HC Dorfan DE Dorfan JM Drewer DC Elia R Feldman GJ Fernandes D Field RC Ford WT Fordham C Frey R Fujino D Gan KK Gatto C Gero E Gidal G Glanzman T Goldhaber G Gomez Cadenas JJ Gratta G Grindhammer G Grosse-Wiesmann P Hanson G Harr R 《Physical review letters》1990,64(24):2881-2884
10.
Stewart C Zieminski A Blessing S Crittenden R Draper P Dzierba A Heinz R Krider J Marshall T Martin J Sambamurti A Smith P Sulanke T Gomez R Dauwe L Haggerty H Malamud E Nikolic M Hagopian S Abrams R Ares J Goldberg H Halliwell C Margulies S McLeod D Salminen A Solomon J Wu G Ellsworth R Goodman J Gupta S Yodh G Watts T Abramov V Antipov Y Baldin B Denisov S Glebov V Gorin Y Kryshkin V Petrukhin A Polovnikov S Sulyaev R 《Physical review D: Particles and fields》1990,42(5):1385-1395