全文获取类型
收费全文 | 1119篇 |
免费 | 59篇 |
国内免费 | 1篇 |
专业分类
化学 | 764篇 |
晶体学 | 6篇 |
力学 | 40篇 |
数学 | 163篇 |
物理学 | 206篇 |
出版年
2024年 | 2篇 |
2023年 | 14篇 |
2022年 | 20篇 |
2021年 | 26篇 |
2020年 | 40篇 |
2019年 | 29篇 |
2018年 | 32篇 |
2017年 | 26篇 |
2016年 | 58篇 |
2015年 | 55篇 |
2014年 | 45篇 |
2013年 | 82篇 |
2012年 | 79篇 |
2011年 | 96篇 |
2010年 | 66篇 |
2009年 | 44篇 |
2008年 | 75篇 |
2007年 | 56篇 |
2006年 | 41篇 |
2005年 | 42篇 |
2004年 | 42篇 |
2003年 | 50篇 |
2002年 | 40篇 |
2001年 | 15篇 |
2000年 | 14篇 |
1999年 | 10篇 |
1997年 | 4篇 |
1996年 | 6篇 |
1994年 | 6篇 |
1993年 | 6篇 |
1992年 | 3篇 |
1991年 | 5篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 5篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1982年 | 1篇 |
1981年 | 7篇 |
1980年 | 3篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1975年 | 4篇 |
1974年 | 1篇 |
1938年 | 1篇 |
排序方式: 共有1179条查询结果,搜索用时 15 毫秒
1.
Dr. Felipe L. Coelho Eduarda S. Gil Dr. Paulo F. B. Gonçalves Dr. Leandra F. Campo Dr. Paulo H. Schneider 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(34):8157-8162
In this work, a series of 2-chalcogenylindoles was synthesized by an efficient methodology, starting from chalcogenoalkynes, including a previously unreported tellurium indole derivative. For the first time, these 2-substituted chalcogenylindoles were obtained in the absence of metal catalyst or base, under thermal conditions only. In addition, the results described herein represent a methodology with inverse regioselectivity for the chalcogen functionalization of indoles. 相似文献
2.
3.
J. C. Fabris S. V. B. Gonçalves P. E. de Souza 《General Relativity and Gravitation》2002,34(12):2111-2126
The mass power spectrum for a Universe dominated by the Chaplygin gas is evaluated numerically from scales of the order of the Hubble horizon to 100 Mpc. The results are compared with a pure baryonic Universe and a cosmological constant model. In all three cases, the spectrum increases with k, the wavenumber of the perturbations. The slope of the spectrum is higher for the baryonic model and smaller for the cosmological constant model, the Chaplygin gas interpolating these two models. The results are analyzed in terms of the sound velocity of the Chaplygin gas and the moment the Universe begins to accelerate. 相似文献
4.
D. C. Oliveira Y. Messaddeq K. Dahmouche S. J. L. Ribeiro R. R. Gonçalves A. Vesperini D. Gindre J.-M. Nunzi 《Journal of Sol-Gel Science and Technology》2006,40(2-3):359-363
Organic-inorganic hybrid materials were prepared from an ureasil precursor (ureapropyltriethoxysilane designated as UPTES)
and acrylic acid modified zirconium (IV) n-propoxide. Thin films containing rhodamine 6G (Rh6G) were prepared by spin-coating on glass substrates with different Zr:Si molar ratios (Zr:Si = 75:25, 50:50 and 25:75). Refractive
index, thickness, number of propagating modes and attenuation coefficient were measured at 543.5, 632.8 and 1550 nm wavelengths
by the prism coupling technique. Distributed feedback (DFB) laser effect was observed and studied as a function of films thickness
and refractive index. 相似文献
5.
Given a map f: X→Y and a Nielsen root class, there is a number associated to this root class, which is the minimal number of points among all
root classes which are H-related to the given one for all homotopies H of the map f. We show that for maps between closed surfaces it is possible to deform f such that all the Nielsen root classes have cardinality equal to the minimal number if and only if either N R[f]≤1, or N R[f]>1 and f satisfies the Wecken property. Here N R[f] denotes the Nielsen root number. The condition “f satisfies the Wecken property is known to be equivalent to |deg(f)|≤N R[f]/(1−χ(M
2)−χ(M
10/(1−χ(M
2)) for maps between closed orientable surfaces. In the case of nonorientable surfaces the condition is A(f)≤N R[f]/(1−χ(M
2)−χ(M
2)/(1−χ(M
2)). Also we construct, for each integer n≥3, an example of a map f: K
n
→N from an n-dimensionally connected complex of dimension n to an n-dimensional manifold such that we cannot deform f in a way that all the Nielsen root classes reach the minimal number of points at the same time. 相似文献
6.
E. de A. Gonçalves V. M. de Oliveira A. Rosas P. R.A. Campos 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,59(1):127-132
Adaptation of populations takes place with the occurrence and subsequent fixation of mutations that confer some selective
advantage
to the individuals which acquire it. For this reason, the study of the process of fixation of advantageous mutations has a
long history
in the population genetics literature. Particularly, the previous investigations aimed to find out the main evolutionary forces
affecting the strength of natural selection in the populations.
In the current work, we investigate the dynamics of fixation of beneficial mutations in a subdivided population. The subpopulations
(demes)
can exchange migrants
among their neighbors, in a migration network which is assumed to have either a random graph or a scale-free topology. We
have observed that the migration rate
drastically affects the dynamics of mutation fixation, despite of the fact that the probability of fixation is invariant on
the
migration rate, accordingly to
Maruyama's conjecture. In addition, we have noticed a topological dependence of the adaptive evolution of the population when
clonal interference
becomes effective. 相似文献
7.
J. Salgado E. Martinho I. F. Gonçalves 《Journal of Radioanalytical and Nuclear Chemistry》2004,260(2):317-320
The resonance neutron self-shielding factor, G
res, is required in neutron metrology and activation data analysis. In a previous paper, the authors have shown that a dimensionless
variable can be introduced which converts the dependence of G
res on the physical and nuclear properties of the material samples into an universal curve, valid for the isolated resonances
of any nuclide. This work presents a methodology based on the universal curve, which enables to calculate G
res for a group of isolated resonances by weighting its individual contributions. A good agreement was reached with results calculated
by the MCNP code and with experimental values for Mo foils and wires.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
8.
The general features of two series of sol-gel derived materials, designatedurethanesils (Ut), have been investigated by infrared and Raman spectroscopies with the goal of elucidating the chemical environment of
the Eu3+ cations.
The host frameworks of the two families of ormolytes studied have been represented by m-Ut(350) and d-Ut(300), where m stands
for mono, d stands for di, 350 and 300 are the average molecular weights of the organic precursors (poly(ethylene glycol)
methyl ether, PEGME, and poly(ethylene glycol), PEG, respectively).
The hybrid matrix of the mono-xerogels is composed by a siliceous backbone bonded by means of urethane linkages (-NHC (=O)O-)
to pendant methyl end capped oligopolymer chains with approximately 7 oxyethylene units, whereas that of the di-xerogels is
based on a siliceous network grafted through urethane groups to both ends of poly(oxyethylene) segments containing about 6
(OCH2CH2) repeat units.
Both classes of materials have been doped with europium triflate (Eu(CF3SO3)3). The doped samples have been identified by m-Ut(350)nEu(CF3SO3)3 and d-Ut(300)nEu(CF3SO3), where n is the molar ratio of (OCH2CH2) repeat units per Eu3+ ion. Materials with n ranging from ∞ to 5 have been analyzed. The spectral data obtained provide evidence that the cations
begin to coordinate to the ether oxygen atoms of the oligopolymer chains at n=40 in the mono-urethanesils and at n=10 in the
di-urethanesils. In mono-urethanesils samples with n>40 and in di-urethanesils materials with n>10, the Eu3+ coordinate exclusively to the carbonyl oxygen atoms of the urethane linkages.
Paper presented at the 8th EuroConference on Ionics, Carvoeiro, Algarve, Portugal, Sept. 16–22, 2001. 相似文献
9.
Anisha Gokarna Yong Hwan Kim Yong-Hoon Cho Min Su Lee In Cheol Kang Hyun Kyu Park Min Gon Kim Bong Hyun Chung 《Optical Review》2006,13(4):288-291
We demonstrate the fluorescence mapping of protein microarrays by the technique of scanning near-field optical microscopy
(SNOM) and confocal microscopy. Micron sized spots (300 μm) of human Immunoglobulin G (hIgG) protein with and without a Cy3
dye labeling have been fabricated on glass substrates by an immobilization method which makes use of calixcrown derivatives
termed Prolinker. We have also tried to probe into the well-known “doughnut effect” observed in fluorescence images of proteins
using the SNOM technique. The topographic and fluorescence SNOM images revealed that the number of proteins at the boundary
of the spot were more than at the center in the case of the microarray spot which showed brighter luminescence at the edge
than at the center in the confocal image. 相似文献
10.