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1.
Thomas M. F. Case G. S. Bland J. Herring A. D. F. Stirling W. G. Tixier S. Boni P. Ward R. C. C. Wells M. R. Langridge S. 《Hyperfine Interactions》2002,141(1-4):471-476
Hyperfine Interactions - Multilayers of Ce/Fe and U/Fe were fabricated by sputtering and studied by X-ray diffraction and reflectivity, Mössbauer spectroscopy and polarised neutron... 相似文献
2.
T. Case K. M. Crowe K. Lou C. Petitjean W. H. Breunlich M. Jeitler P. Kammel B. Lauss J. Marton W. Prymas J. Zmeskal D. V. Balin V. N. Baturin Yu. S. Grigoriev A. I. Ilyin E. M. Maev G. E. Petrov G. G. Semenchuk Yu. V. Smirenin A. A. Vorobyov N. I. Voropaev P. Baumann H. Daniel F. J. Hartmann M. Mühlbauer W. Schott P. Wojciechowski 《Hyperfine Interactions》1993,82(1-4):295-302
Starting in 1989 an experiment was run at PSI to directly measure the final sticking probability in muon catalyzed dt fusion. This experiment was based on an active-target ionization chamber (IC) built at Gatchina, Russia, and an array of plastic neutron counters. In three runs approximately 5×106 isolated alpha signals were recorded with around one half of these occurring in the inner chamber region where we have more complete understanding of the systematic errors. Particularly from a long run in 1992 we were able to obtain a very clean sticking peak of some 5000 events. However, to reach an accurate value of sticking, all systematic effects and several major backgrounds had to be understood in detail. To this end a Monte Carlo code was written to simulate the full electrostatic environment of the IC and to recreate completely each signal type including the actual tritium decay noise from the live experiment. A slightly model dependent value of approx. 0.56±0.04% is obtained for final sticking. 相似文献
3.
W. Schott V. N. Baturin W. H. Breunlich T. Case H. Daniel F. J. Hartmann M. Jeitler P. Kammel K. Lou E. M. Maev J. Marton M. Mühlbauer C. Petitjean G. E. Petrov Yu. V. Petrov G. G. Semenchuk Yu. V. Smirenin A. A. Vorobyov P. Wojciechowski J. Zmeskal 《Hyperfine Interactions》1993,82(1-4):471-481
The triton energy of the muon capture reaction 3He t+v, where 3 He is the ground state of muonic3He, has been measured in order to investigate a possible heavy v admixture into the flavour with high sensitivity. 3 He has been formed via the pd fusion reaction by stopping – in an ionization chamber (IC) filled with an H/D gas mixture of 3% D concentration at a pressure of 161 bar. In a first short experiment 650 triton events were observed yielding an upper limit for the -heavy v mixing strength of 2.3×10–3 atE
0v=60 MeV. 相似文献
4.
P. Ackerbauer W. H. Breunlich M. Fuchs S. Fussy M. Jeitler P. Kammel B. Lauss J. Marton W. Prymas J. Werner J. Zmeskal K. Lou C. Petitjean P. Baumann H. Daniel F. J. Hartmann W. Schott T. von Egidy P. Wojciechowski D. Chatellard J. P. Egger E. Jeannet T. Case K. M. Crowe R. H. Sherman V. Markushin 《Hyperfine Interactions》1993,82(1-4):243-258
Complementary to the investigations of the most efficient dt cycle, also the other muon-induced fusion cycles in mixtures of hydrogen isotopes have been studied. The results of these dedicated experiments provide rich information about muon-induced few-body reactions and contribute significantly to a better overall understanding of CF. A summary of the recent progress will be presented. Special emphasis will be put on two characteristic examples, namely a new experimental approach to study the muonic cascade in H-D mixtures and the systematic study of hyperfine effects in muon-induced reactions. 相似文献
5.
2,2′-Biquinoline dioxide and 4,4′-dichloro-2,2′-biquinoline have been used for the preparation of the following 4,4′-disubstituted-2,2′-biquinolines: dimethoxy, diethoxy, dihydroxy, dipiperidino, dipyrrolidino, dibromo, diphenoxy, dithiophenoxy, di(p-chloro-phenoxy), di(p-bromophenoxy), di(p-fluorophenoxy), di(β-naphthoxy) and the dinitro dioxide. Molar extinction coefficients have been determined for several of the copper (I) complexes of these compounds. 相似文献
6.
South MS Case BL Dice TA Franklin GW Hayes MJ Jones DE Lindmark RJ Zeng Q Parlow JJ 《Combinatorial chemistry & high throughput screening》2000,3(2):139-151
A parallel solution-phase library synthesis of functionalized diaminobenzamides is described. The four-step library synthesis is accomplished using polymer-assisted solution-phase (PASP) synthesis techniques. This high-yielding, multi-step sequence utilizes sequestering resins for the removal of reactants, reactant by-products, and employs a resin capture/release strategy as a key library synthesis step. Step one of the sequence relies on the displacement of an activated fluoro-group from the aromatic ring of 1a, b with a variety of primary amines to introduce the first diversity position. Step two is hydrolysis of the benzoate ester to a benzoic acid which is subsequently captured on a polyamine resin, washed, and released to give 4a, b in pure form. Step three utilizes PASP resins to mediate the amide coupling of a benzoic acid with a variety of primary amines to give the aminonitrobenzamides 5a, b and introduces the second diversity position. Step four is the parallel reduction of the aminonitrobenzamides 5a, b to the functionalized diaminobenzamides 6a, b. This library synthesis proceeds with high overall purities which average 80 % over the 4-step sequence. 相似文献
7.
Cooper HJ Case MA McLendon GL Marshall AG 《Journal of the American Chemical Society》2003,125(18):5331-5339
The application of electrospray ionization (ESI) Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry to the investigation of the relative stabilities (and thus packing efficiencies) of Fe-bound trihelix peptide bundles is demonstrated. Small dynamic protein libraries are created by metal-ion assisted assembly of peptide subunits. Control of the trimeric aggregation state is coupled to stability selection by exploiting the coordination requirements of Fe(2+) in the presence of bidentate 2,2'-bipyridyl ligands covalently appended to the peptide monomers. At limiting metal-ion concentration, the most thermodynamically stable, optimally packed peptide trimers dominate the mass spectrum. The identities of optimally stable candidate trimers observed in the ESI FT-ICR mass spectra are confirmed by resynthesis of exchange-inert analogues and measurement of their folding free energies. The peptide composition of the trimers may be determined by infrared multiphoton dissociation (IRMPD) MS(3) experiments. Additional sequence information for the peptide subunits is obtained from electron capture dissociation (ECD) of peptides and metal-bound trimers. The experiments also suggest the presence of secondary structure in the gas phase, possibly due to partial retention of the solution-phase coiled coil structure. 相似文献
8.
Solutions to some practical problems that arise in multiple scattering calculations on large molecules are discussed. (1) Numerical instabilities near the zero of energy can be removed by rescaling the secular matrix. (2) The calculation of structure factors can be made much more efficient by the application of symmetry projection operators. (3) An energy search procedure is described that ensures that no states are inadvertently neglected. Test calculations incorporating these changes illustrate the improved numerical stability, and show decreases in computation time of 30–60%, when compared to previous codes. The procedures suggested here are applicable to both relativistic and nonrelatitistic calculations. 相似文献
9.
Andreev VA Banks TI Case TA Chitwood DB Clayton SM Crowe KM Deutsch J Egger J Freedman SJ Ganzha VA Gorringe T Gray FE Hertzog DW Hildebrandt M Kammel P Kiburg B Knaack S Kravtsov PA Krivshich AG Lauss B Lynch KL Maev EM Maev OE Mulhauser F Ozben CS Petitjean C Petrov GE Prieels R Schapkin GN Semenchuk GG Soroka MA Tishchenko V Vasilyev AA Vorobyov AA Vznuzdaev ME Winter P;MuCap Collaboration 《Physical review letters》2007,99(3):032002
The rate of nuclear muon capture by the proton has been measured using a new technique based on a time projection chamber operating in ultraclean, deuterium-depleted hydrogen gas, which is key to avoiding uncertainties from muonic molecule formation. The capture rate from the hyperfine singlet ground state of the microp atom was obtained from the difference between the micro(-) disappearance rate in hydrogen and the world average for the micro(+) decay rate, yielding Lambda(S)=725.0+/-17.4 s(-1), from which the induced pseudoscalar coupling of the nucleon, g(P)(q(2)=-0.88m(2)(micro))=7.3+/-1.1, is extracted. 相似文献
10.