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1.
We study spectral properties of discrete Schrödinger operators with potentials obtained via dimerization of a class of aperiodic sequences. It is shown that both the nature of the autocorrelation measure of a regular sequence and the presence of generic (full probability) singular continuous spectrum in the hull of primitive and palindromic (four block substitution) potentials are robust under dimerization. Generic results also hold for circle potentials. We illustrate these results with numerical studies of the quantum mean square displacement as a function of time. The numerical techniques provide a very fast algorithm for the time evolution of wave packets. 相似文献
2.
U. Täuber C.E.M. Carvalho R.F. dos Santos C.G. Carvalhaes C.E. Fellows 《Applied physics. B, Lasers and optics》2007,87(3):475-481
A six level rate equation system was used to investigate the impact of photodepletion to amplified spontaneous emission (ASE)
of intramolecular proton-transfer (IPT) dyes incorporated into polymeric hosts. The model includes the most important transitions
for the normal and tautomer form of the molecule as well as intersystem crossing and triplet–triplet transitions. The experimentally
observed pulse shape as well as photodepletion phenomena, i.e. a first order exponential decay of the ASE intensity and a
shortening in ASE pulse width, have been simulated successfully. Additionally, the model was used to propose an explanation
of the unexpected high photodepletion of proton-transfer dyes in solids. The results show that the emission cross section
and reabsorption cross section of the tautomer form of the molecule are the most important parameter not only for efficiency
but also for photodepletion. The model was tested by comparison with experimental results of 2-(2’-hydroxyphenyl)benzimidazole
in polymethylmethacrylate (PMMA), polystyrene (PS) and a 1:1 alternating copolymer matrix PS-co-PMMA.
PACS 78.45.th; 42.55.Mv; 42.70.Jk 相似文献
3.
Marcos Almeida Bezerra Sérgio Mitihiro do Nascimento Maêda Eliane Padua Oliveira Maria de Fátima Batista de Carvalho Ricardo Erthal Santelli 《Spectrochimica Acta Part B: Atomic Spectroscopy》2007
In the present paper a procedure is proposed for the determination of traces of Cd, Co, Mn and Cr in petroleum industry produced water by inductively coupled plasma optical emission spectrometry. The procedure is based on cloud point extraction of these metals, as their dithizonate complexes, into the surfactant-rich phase of octylphenoxypolyethoxyethanol surfactant (Triton X-114). Extractions were carried out in solutions with salinities between 10‰ and 70‰. Since residual salinity in the surfactant-rich phase caused differences in its transport to the plasma, yttrium was used as an internal standard to correct for this effect. The simultaneous metal extraction procedure was optimized by response surface methodology using a Doehlert design and desirability function. Enhancement factors of 21, 21, 9 and 19, along with limits of quantification of 0.093, 0.20, 0.73 and 1.2 μg L− 1, and precision expressed as relative standard deviation (n = 8, 20.0 μg L− 1) of 5.8, 1.2, 1.7 and 5.7% were obtained for Cd, Co, Mn and Cr, respectively. The accuracy was evaluated by spike recovery tests on the high salinity water samples with salinity of 40 and 63‰. 相似文献
4.
Alexandre N. Carvalho German Lozada-Cruz 《Journal of Mathematical Analysis and Applications》2007,325(2):1216-1239
We obtain existence of asymptotically stable nonconstant equilibrium solutions for semilinear parabolic equations with nonlinear boundary conditions on small domains connected by thin channels. We prove the convergence of eigenvalues and eigenfunctions of the Laplace operator in such domains. This information is used to show that the asymptotic dynamics of the heat equation in this domain is equivalent to the asymptotic dynamics of a system of two ordinary differential equations diffusively (weakly) coupled. The main tools employed are the invariant manifold theory and a uniform trace theorem. 相似文献
5.
6.
J. M. Godoy M. L. Godoy Z. L. Carvalho D. C. Lauria 《Journal of Radioanalytical and Nuclear Chemistry》1994,183(1):19-26
A short overview of HPLC column packings is presented. The properties of chromatographic carriers and the possibilities to combine the solid matrices with organic polymeric stationary phases are elucidated in detail. The latest achievements and anticipated future developments in the area are outlined. 相似文献
7.
L.A. Carvalho dos Santos J. Hounie 《Journal of Mathematical Analysis and Applications》2004,299(2):465-493
We study Hardy spaces on the boundary of a smooth open subset or Rn and prove that they can be defined either through the intrinsic maximal function or through Poisson integrals, yielding identical spaces. This extends to any smooth open subset of Rn results already known for the unit ball. As an application, a characterization of the weak boundary values of functions that belong to holomorphic Hardy spaces is given, which implies an F. and M. Riesz type theorem. 相似文献
8.
In this work we display a numerical comparison, under statistical and computational point of view, between semi-analytical Eulerian and Lagrangian dispersion models to simulate the ground-level concentration values of a passive pollutant released from a low height source. The Eulerian approach is based on the solution of the advection–diffusion equation by the Laplace transform technique. The Lagrangian approach is based on solution of the Langevin equation through the Picard’s Iterative Method. Turbulence inputs are calculated according to a parameterization capable of generating continuous values in all stability conditions and in all heights of the Planetary Boundary Layer (PBL). Numerical simulations and comparisons show a good agreement between predicted and observed concentrations values. The comparison reveals the main advantages and disadvantages between the models. 相似文献
9.
Large-scale production of cellulose-binding domains. Adsorption studies using CBD-FITC conjugates 总被引:1,自引:0,他引:1
Ricardo Pinto Joana Carvalho Manuel Mota Miguel Gama 《Cellulose (London, England)》2006,13(5):557-569
A method for the gram-scale production of cellulose-binding domains (CBD) through the proteolytic digestion of a commercial enzymatic preparation (Celluclast) was developed. The CBD obtained, isolated from Trichoderma reesei cellobiohydrolase I, is highly pure and heavily glycosylated. The purified peptide has a molecular weight of 8.43 kDa, comprising the binding module, a part of the linker, and about 30% glycosidic moiety. Its properties may thus be different from recombinant ones expressed in bacteria. CBD-fluorescein isothiocyanate conjugates were used to study the CBD-cellulose interaction. The presence of fluorescent peptides adsorbed on crystalline and amorphous cellulose fibers suggests that amorphous regions have a higher concentration of binding sites. The adsorption is reversible, but desorption is a very slow process. 相似文献
10.
The determination of polar and nonpolar organophosphorus compounds, triazines and their metabolites, molinate and chlorothalonil in 1 l water samples was investigated using off-line solid-phase extraction followed by gas chromatography with nitrogen-phosphorus and flame photometric detection. The ethylvinylbenzene-divinylbenzene copolymer (LiChrolut EN) and the commercial graphitized carbon black (GCB) of Envi-Carb were tested as solid-phase sorbents. The matrix effect was studied by extracting the compounds spiked in water samples of different types (Milli-Q, tap, salted tap water, river and sea water). The polymeric sorbent LiChrolut EN allowed the determination at low ng/l of all 40 compounds tested, except the very polar atrazine-desethyl-deisopropyl (DDA). Recoveries of compounds from the Envi-Carb sorbent are comparable to those obtained for LiChrolut EN with the exception of chlorothalonil and the more hydrophobic organophosphorus compounds (coumaphos, leptophos), which were strongly sorbed in the Envi-Carb cartridges. Envi-Carb, however, enabled the determination of DDA with a limit of detection of 14 ng/l. 相似文献