全文获取类型
收费全文 | 1921篇 |
免费 | 73篇 |
国内免费 | 8篇 |
专业分类
化学 | 1449篇 |
晶体学 | 8篇 |
力学 | 34篇 |
数学 | 255篇 |
物理学 | 256篇 |
出版年
2023年 | 23篇 |
2022年 | 39篇 |
2021年 | 55篇 |
2020年 | 48篇 |
2019年 | 40篇 |
2018年 | 30篇 |
2017年 | 20篇 |
2016年 | 63篇 |
2015年 | 58篇 |
2014年 | 66篇 |
2013年 | 112篇 |
2012年 | 115篇 |
2011年 | 154篇 |
2010年 | 88篇 |
2009年 | 101篇 |
2008年 | 122篇 |
2007年 | 136篇 |
2006年 | 113篇 |
2005年 | 128篇 |
2004年 | 88篇 |
2003年 | 55篇 |
2002年 | 47篇 |
2001年 | 20篇 |
2000年 | 18篇 |
1999年 | 20篇 |
1998年 | 15篇 |
1997年 | 18篇 |
1996年 | 15篇 |
1995年 | 15篇 |
1994年 | 10篇 |
1993年 | 9篇 |
1992年 | 13篇 |
1991年 | 10篇 |
1990年 | 14篇 |
1989年 | 10篇 |
1988年 | 9篇 |
1987年 | 12篇 |
1986年 | 6篇 |
1985年 | 11篇 |
1984年 | 8篇 |
1983年 | 9篇 |
1982年 | 6篇 |
1981年 | 6篇 |
1980年 | 10篇 |
1978年 | 3篇 |
1977年 | 6篇 |
1976年 | 4篇 |
1975年 | 5篇 |
1968年 | 3篇 |
1967年 | 3篇 |
排序方式: 共有2002条查询结果,搜索用时 140 毫秒
1.
2.
3.
Dr. Carla Carrera Dr. Eleonora Cavallari Dr. Giuseppe Digilio Dr. Oksana Bondar Prof. Silvio Aime Dr. Francesca Reineri 《Chemphyschem》2021,22(11):1042-1048
An efficient synthesis of vinyl-[1-13C]pyruvate has been reported, from which 13C hyperpolarized (HP) ethyl-[1-13C]pyruvate has been obtained by means of ParaHydrogen Induced Polarization (PHIP). Due to the intrinsic lability of pyruvate, which leads quickly to degradation of the reaction mixture even under mild reaction conditions, the vinyl-ester has been synthesized through the intermediacy of a more stable ketal derivative. 13C and 1H hyperpolarizations of ethyl-[1-13C]pyruvate, hydrogenated using ParaHydrogen, have been compared to those observed on the more widely used allyl-derivative. It has been demonstrated that the spin order transfer from ParaHydrogen protons to 13C, is more efficient on the ethyl than on the allyl-esterdue to the larger J-couplings involved. The main requirements needed for the biological application of this HP product have been met, i. e. an aqueous solution of the product at high concentration (40 mM) with a good 13C polarization level (4.8 %) has been obtained. The in vitro metabolic transformation of the HP ethyl-[1-13C]pyruvate, catalyzed by an esterase, has been observed. This substrate appears to be a good candidate for in vivo metabolic investigations using PHIP hyperpolarized probes. 相似文献
4.
5.
P. Mun F. C. Fonseca R. Muccillo R. F. Jardim 《Physica C: Superconductivity and its Applications》2003,390(4):363-373
A systematic study of the magnetic hysteresis in transport properties of polycrystalline YBa2Cu3O7−δ–Ag compounds has been made based on two kinds of measurements at 77 K and under applied magnetic fields up to 30 mT: critical current density Jc(Ba) and magnetoresistance R(Ba). The R(Ba) curves show a minimum in their decreasing branch occurring at B=Bmin which was found to be both the excitation current Iex and the maximum applied magnetic field Bam dependent. In addition, for a certain value of Bam>5 mT, we have observed that Bmin increases with increasing Iex and reaches a saturation value. The Jc(Ba) curves show a maximum in decreasing applied magnetic fields occurring at B=Bmax. We have also found that Bmax increases with increasing Bam and reaches a saturation value. The minimum in the R(Ba) and the maximum in Jc(Ba) curves were found to be related to the trapped flux within the grains. All the experimental results are discussed within the context of the flux dynamics and transport mechanisms in these high-Tc materials. 相似文献
6.
7.
In this paper we report the results of a morphological and structural investigation on film properties of a soluble polydiacetylene, the poly[1,6-bis(3,6-dihexadecyl-N-carbazolyl)-2,4-hexadiyne] (polyDCHD-HS). The red films of this polymer, prepared by standard spin-coating techniques, revealed absence of linear dichroism and birefringence in contrast with the ordered mesophases detected by powder X-ray studies. In order to interpret the optical behavior of this polymer, we performed AFM and SEM studies of polyDCHD-HS films spun on hydrophylic and hydrophobic glass substrates. We found the presence of surfaces organized in rod-like particles, more regularly oriented on the hydrophylic substrate. GIXRD studies, carried out on films sufficiently thick to allow the observation of the diffraction pattern, reveled the presence of a lamellar structure with a spacing of 3.22 nm. The low intensity of the diffraction peaks and the isotropic linear optical properties of the films show that the lamellar mesophases are not extended over large areas. These findings were compared with the data obtained from AFM and SEM studies on films of two other polydiacetylenes, the poly[1-(3,6-dihexadexyl-N-carbazolyl)-6-(N-carbazolyl)-2,4-hexadyine] (polya-DCHD) and the poly[1,6-bis(3,6-dipalmitoyl-N-carbazolyl)-2,4-hexadyine] (polyDPCHD), spun on hydrophylic glass substrate. The results confirmed the presence of nodular morphologies which seem to be a general characteristic of this class of materials. The particles organization appears instead related to the chemical nature of the substituents on the carbazolyl rings. 相似文献
8.
9.
10.
H.D. Fonseca Filho R. Prioli M.P. Pires A.S. Lopes P.L. Souza F.A. Ponce 《Applied Physics A: Materials Science & Processing》2007,89(4):945-949
Atomic-force nanolithography was used to control the nucleation sites of InAs nanostructures on InP substrates. Indentations
with a wide range of dimensions were produced on InP. InAs nanostructures were selectively grown by metal organic vapor phase
epitaxy. It is shown that the number of active nucleation sites depends on the normal force applied during nanoindentation.
Crystalline defects introduced by nanoindentation are shown to be nucleation sites for these nanostructures. The presence
of screw dislocations within the grown nanostructures further supports this observation.
PACS 81.07.-b; 68.37.Ps; 81.16.Nd 相似文献