全文获取类型
收费全文 | 2128篇 |
免费 | 65篇 |
国内免费 | 5篇 |
专业分类
化学 | 1573篇 |
晶体学 | 12篇 |
力学 | 38篇 |
数学 | 279篇 |
物理学 | 296篇 |
出版年
2023年 | 18篇 |
2022年 | 51篇 |
2021年 | 68篇 |
2020年 | 56篇 |
2019年 | 52篇 |
2018年 | 33篇 |
2017年 | 33篇 |
2016年 | 66篇 |
2015年 | 57篇 |
2014年 | 56篇 |
2013年 | 124篇 |
2012年 | 120篇 |
2011年 | 164篇 |
2010年 | 110篇 |
2009年 | 99篇 |
2008年 | 135篇 |
2007年 | 144篇 |
2006年 | 116篇 |
2005年 | 144篇 |
2004年 | 101篇 |
2003年 | 53篇 |
2002年 | 48篇 |
2001年 | 32篇 |
2000年 | 32篇 |
1999年 | 29篇 |
1998年 | 14篇 |
1997年 | 16篇 |
1996年 | 23篇 |
1995年 | 13篇 |
1994年 | 14篇 |
1993年 | 9篇 |
1992年 | 11篇 |
1991年 | 10篇 |
1990年 | 16篇 |
1989年 | 9篇 |
1988年 | 7篇 |
1987年 | 7篇 |
1986年 | 5篇 |
1985年 | 9篇 |
1984年 | 5篇 |
1983年 | 9篇 |
1982年 | 6篇 |
1981年 | 14篇 |
1980年 | 11篇 |
1979年 | 8篇 |
1978年 | 4篇 |
1977年 | 4篇 |
1976年 | 8篇 |
1973年 | 6篇 |
1972年 | 4篇 |
排序方式: 共有2198条查询结果,搜索用时 15 毫秒
1.
Condeixa Lucas Dias Silva Pierry Moah Diego Farias Brenda Leiras Adriana 《Central European Journal of Operations Research》2022,30(3):921-940
Central European Journal of Operations Research - Societal awareness and legislation changes concerning sustainability have affected how organizations generate value for stakeholders, as well as... 相似文献
2.
Dr. Carla Carrera Dr. Eleonora Cavallari Dr. Giuseppe Digilio Dr. Oksana Bondar Prof. Silvio Aime Dr. Francesca Reineri 《Chemphyschem》2021,22(11):1042-1048
An efficient synthesis of vinyl-[1-13C]pyruvate has been reported, from which 13C hyperpolarized (HP) ethyl-[1-13C]pyruvate has been obtained by means of ParaHydrogen Induced Polarization (PHIP). Due to the intrinsic lability of pyruvate, which leads quickly to degradation of the reaction mixture even under mild reaction conditions, the vinyl-ester has been synthesized through the intermediacy of a more stable ketal derivative. 13C and 1H hyperpolarizations of ethyl-[1-13C]pyruvate, hydrogenated using ParaHydrogen, have been compared to those observed on the more widely used allyl-derivative. It has been demonstrated that the spin order transfer from ParaHydrogen protons to 13C, is more efficient on the ethyl than on the allyl-esterdue to the larger J-couplings involved. The main requirements needed for the biological application of this HP product have been met, i. e. an aqueous solution of the product at high concentration (40 mM) with a good 13C polarization level (4.8 %) has been obtained. The in vitro metabolic transformation of the HP ethyl-[1-13C]pyruvate, catalyzed by an esterase, has been observed. This substrate appears to be a good candidate for in vivo metabolic investigations using PHIP hyperpolarized probes. 相似文献
3.
Jerry Ray Dias 《Molecular physics》2020,118(12)
Cycloparaphenylene ([r]CPP) and cyclacene ([r]CA) series are models for short carbon nanotubes. It is shown that armchair edges in model cycloparaphenylenes possess greater aromaticity and cyclic conjugation than do zigzag edges in model cyclacenes. According to Aihara’s bond resonance energy (BRE) and Bosanac and Gutman energy effect (ef) measurements, cycloparaphenylenes are twice as aromatic as cyclacenes. The general solution of all eigenvalues of all members of the cycloparaphenylene series is given. The origin of the recurrence of some eigenvalues are determined. 相似文献
4.
Various physical systems of dispersive waves admit solutions in the form of generalized solitary waves. Such waves result from the resonance between a long localized wave and short periodic oscillations. Many estimates (rigorous and numerical) have been given for the amplitude of the ripples in the tail of the generalized solitary wave when its central part has a sech2 shape. This Note provides estimates (not yet rigorous) for the ripple amplitude when the central part is flat and wide. To cite this article: C. Fochesato, F. Dias, C. R. Acad. Sci. Paris, Ser. I 337 (2003). 相似文献
5.
6.
7.
In this paper we report the results of a morphological and structural investigation on film properties of a soluble polydiacetylene, the poly[1,6-bis(3,6-dihexadecyl-N-carbazolyl)-2,4-hexadiyne] (polyDCHD-HS). The red films of this polymer, prepared by standard spin-coating techniques, revealed absence of linear dichroism and birefringence in contrast with the ordered mesophases detected by powder X-ray studies. In order to interpret the optical behavior of this polymer, we performed AFM and SEM studies of polyDCHD-HS films spun on hydrophylic and hydrophobic glass substrates. We found the presence of surfaces organized in rod-like particles, more regularly oriented on the hydrophylic substrate. GIXRD studies, carried out on films sufficiently thick to allow the observation of the diffraction pattern, reveled the presence of a lamellar structure with a spacing of 3.22 nm. The low intensity of the diffraction peaks and the isotropic linear optical properties of the films show that the lamellar mesophases are not extended over large areas. These findings were compared with the data obtained from AFM and SEM studies on films of two other polydiacetylenes, the poly[1-(3,6-dihexadexyl-N-carbazolyl)-6-(N-carbazolyl)-2,4-hexadyine] (polya-DCHD) and the poly[1,6-bis(3,6-dipalmitoyl-N-carbazolyl)-2,4-hexadyine] (polyDPCHD), spun on hydrophylic glass substrate. The results confirmed the presence of nodular morphologies which seem to be a general characteristic of this class of materials. The particles organization appears instead related to the chemical nature of the substituents on the carbazolyl rings. 相似文献
8.
The computation of long wave propagation through the ocean obviously depends on the initial condition. When the waves are generated by a moving bottom, a traditional approach consists in translating the ‘frozen’ sea bed deformation to the free surface and propagating it. The present study shows the differences between the classical approach (passive generation) and the active generation where the bottom motion is included. The analytical solutions presented here exhibit some of the drawbacks of passive generation. The linearized solutions seem to be sufficient to consider the generation of water waves by a moving bottom. To cite this article: D. Dutykh et al., C. R. Acad. Sci. Paris, Ser. I 343 (2006). 相似文献
9.
R. S. Dias A. P. Roque D. M. S. S. Vitti 《Journal of Radioanalytical and Nuclear Chemistry》2006,269(3):661-663
Summary The objective of this study was to determine endogenous phosphorus excretion in sheep fed with different diets. Sixteen male
growing sheep, received a basic diet with: 42% hydrolyzed sugarcane bagasse (HSB), 45% lucerne hay (LH) plus 14% hydrolyzed
sugarcane bagasse, and 30% citrus pulp (CTP) plus 40% hydrolyzed sugarcane bagasse. A dose of 7.7 MBq 32P was injected into the left jugular vein of each animal. The P endogenous fecal losses were: 1.69, 2.50, 2.33 and 1.45 g/animal
for treatments HSB, LH, and CTP respectively (P>0.05). The type of diet influenced slight endogenous P excretion but altered
excretion of P in urine. Endogenous P excreted in feces (PF) comes mainly from saliva and represents an important loss of P. The estimation of net requirements of phosphorus (P) for
ruminants includes endogenous losses, which is also essential for calculating true absorption of this mineral. Physical structure
of the feed may influence endogenous losses, altering the metabolism of P and also the demand of this mineral, therefore being
important to know how different feeds affect endogenous P losses. 相似文献
10.