太阳风等离子体输出流量的全日面二维结构

本文根据1983年十个 Carrington 周(1733—1742)期间的 K-日冕亮度、行星际闪烁(IPS)观测和光球磁场观测,首次探讨了太阳风等离子体质量、动量和能量输出流量 F_M,F_P 和 F_E 的全日面二维平均结构及其与光球磁场结构的关系.     

Extension of multivariate regression trees to interval data. Application to electricity load profiling

Summary  Several data can be presented as interval curves where intervals reflect a within variability. In particular, this representation is well adapted for load profiles, which depict the electricity consumption of a class of customers. Electricity load profiling consists in assigning a daily load curve to a customer based on their characteristics such as energy requirement. Within the load profiling scope, this paper investigates the extension of multivariate regression trees to the case of interval dependent (or response) variables. The tree method aims at setting up simultaneously load profiles and their assignment rules based on independent variables. The extension of multivariate regression trees to interval responses is detailed and a global approach is defined. It consists in a first stage of a dimension reduction of the interval response variables. Thereafter, the extension of the tree method is applied to the first principal interval components. Outputs are the classes of the interval curves where each class is characterized both by an interval load profile (e.g. the class prototype) and an assignment rule based on the independent variables.     

Chimie des complexes de metaux de transition avec des hydrocarbures cyanes : III. Quelques observations sur la conformation et la reactivite de complexes dicyclopentadienyles du molybdene et du tungstene

A new class of cyclic telluronium salts has been prepared. All the salts are stable in solution in CHCl₃ or dimethylsulphoxide (DMSO). Conductivity measurements in DMSO and dimethylformamide (DMF) have shown that considerable ion pairing occurs in solution. Infrared, ¹H, ¹³C, ¹²⁵Te NMR, and mass spectra are reported and discussed.     

Does charge carrier dimensionality increase in mixed-valence salts of tetrathiafulvalene-terminated dendrimers?

[structure: see text] In four new dendrimers terminated by 12 electroactive tetrathiafulvalenyl substituents, the tridimensional character of the inter- and intradendrimeric charge and electron transfer, and hence of the electroconductivity, is evidenced by examination of the electronic spectra of their corresponding neutral state and cation radical, dication, and mixed-valence salts, including a closed-shell anion.     

Photoinduced Aerobic Iodoarene‐Catalyzed Spirocyclization of N‐Oxy‐amides to N‐Fused Spirolactams**

Iodoarene catalysis is a powerful methodology that usually requires an excess of oxidant, or of redox mediator if the terminal oxidant is dioxygen, to generate the key hypervalent iodine intermediate to proceed efficiently. We report that, using the spiro‐cyclization of amides as a benchmark reaction, aerobic iodoarene catalysis can be enabled by relying on a pyrylium photocatalyst under blue light irradiation. This unprecedented dual organocatalytic system allows the use of low catalytic loading of both catalysts under very mild operating conditions.     

锂离子电池硅基负极材料的研究进展

硅基材料是新一代高容量锂离子蓄电池负极材料的典型代表,近年来已成为理论研究和应用研究的热点.本文介绍了锂离子电池硅基负极材料的制备方法、电化学性能及其研究现状,分析了硅材料作为锂离子电池负极材料存在的问题;讨论了硅材料作为锂离子电池负极材料的研究前景.并指出若能克服目前存在问题,将有望成为新一代锂离子电池负极材料.     

Influence of the solvent quality on the AhR mediated Procept assay measurement of dioxin and dioxin-like compounds

Polychlorodibenzo-p-dioxins, polychorodibenzofurans and “dioxin-like” polychlorinated biphenyls are widespread persistent organic pollutants sharing a similar toxicological pathway mediated by the aryl-hydrocarbon receptor (AhR). Since the confirmatory method for their measurement at trace levels in complex matrices (using isotopic dilution and gas chromatography-high resolution mass spectrometry) remains time and cost-consuming, growing efforts of the scientific community have been focused on the development of screening approaches, including AhR mediated assays. Unfortunately, AhR ligands are highly diverse and agonistic/antagonistic effects can be observed on procedural blanks and/or sample extracts. In this study, the influence of solvent grade quality on the response of a DNA-binding AhR mediated assay used for screening dioxins has been investigated. Our results demonstrated a very critical impact of this parameter with both strong agonistic and antagonistic effects observed for any tested solvent lot. A small silver nitrate silica column removed partly these interfering compounds and then can be recommended as final purification step. Some preferable grades can be identified and selected in order to guarantee the best possible performances. However, it appears necessary to test every new lot, even if a grade appeared previously compliant.     

Decomposition algorithm of an experimental Mueller matrix

This study deals with the interpretation of experimental Mueller matrices. The understanding of such a matrix is not straightforward in the case, in particular, of a strongly depolarizing medium, which is therefore disturbed and where relevant pieces of information are often distributed among its various elements. As a result, information data need to be extracted by a decomposition of any Mueller matrix into simple elements to uncouple the existing polarimetric effects. This led us to develop an algorithm in order to characterize any depolarizing, or not, polarimetric system. In addition to differentiating the experimental noise from the intrinsic depolarization of the optical system under study, this algorithm proved to: (i) separate depolarization from birefringence and dichroism and (ii) characterize the isotropic or anisotropic nature of the depolarization. At last, this algorithm was validated through the study of several optical systems with different polarimetric properties.     

PtCl2-catalyzed cycloisomerizations of 5-en-1-yn-3-ol systems

5-En-1-yn-3-ol substrates bearing a free hydroxyl group or an acyl group are highly versatile partners for PtCl2-catalyzed cycloisomerizations. Electrophilic activation of the alkyne moiety triggers at wish a hydride or an O-acyl migration yielding at the end to regioisomeric keto derivatives. The efficient preparation of Sabina ketone, an important monoterpene precursor, has been worked out.