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排序方式: 共有176条查询结果,搜索用时 15 毫秒
1.
CV Tomy D Pal SS Banerjee S Ramakrishnan AK Grover S Bhattacharya MJ Higgins G Balakrishnan McK Paul 《Pramana》2002,58(5-6):925-935
The weakly pinned single crystals of the hexagonal 2H-NbSe2 compound have emerged as prototypes for determining and characterizing the phase boundaries of the possible order-disorder
transformations in the vortex matter. We present here a status report based on the ac and dc magnetization measurements of
the peak effect phenomenon in three crystals of 2H-NbSe2, in which the critical current densities vary over two orders of magnitude. We sketch the generic vortex phase diagram of
a weakly pinned superconductor, which also utilizes theoretical proposals. We also establish the connection between the metastability
effects and pinning. 相似文献
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Abstract. The aerobic oxidation of saturated long chain fatty acids to the lower aldehyde and CO2 catalyzed by the α-oxidase system of young leaves from germinating Pisum sativum results in concomitant excitation of the chloroplasts or/and fractions present in the α-oxidase preparation. The excitation is attested to by both chlorophyll emission and Hill activity. This is the first case of photobiochemistry without light within a natural system. 相似文献
4.
Alberti G Brunet E Dionigi C Juanes O de La Mata MJ Rodríguez-Ubis JC Vivani R 《Angewandte Chemie (International ed. in English)》1999,38(22):3351-3353
The hydrophilic oxygen atoms of polyethylenoxide chains inserted as pillars in gamma-zirconium phosphate form hydrogen bonds with the acid groups of the host. As a result the pillars are almost perpendicular to the gamma layers. Upon changing the pH level of the supernatant solution the hydrogen bonds are broken and the pillars become almost perpendicular to the layers (shown schematically). Thus there is a reversible enlargement-shortening of the interlayer space. 相似文献
5.
Highly reliable and accurate analytical methods are needed for the determination of magnetic resonance imaging (MRI) contrast agents in complex matrices of clinical interest. We demonstrate the reliability of capillary zone electrophoresis (CZE) coupled with electrospray ionization-mass spectrometry (ESI-MS) for the analysis of MultiHance (gadobenate dimeglumine), a gadolinium-based MRI agent. A sheath liquid interface connected the CE system with an electrospray mass spectrometer equipped with an ion-trap analyzer. CZE with ultraviolet (CZE-UV) and with mass detection (CZE-MS) were compared by analyzing gadobenate dimeglumine and the free ligand diluted in water and in biological fluids (i.e., human serum and urine). The optimization of some relevant CZE-MS parameters was accomplished, like CE buffer composition, sheath liquid composition and flow, and type and length of the separation capillary. CZE-UV was highly influenced by the biological sample components, which hindered a reliable quantification of both gadobenate and free ligand in serum and urine. In CZE-MS, on the other hand, the electrophoretic runs turned out to be independent of the clinical matrices, due to the informative potential and to the selectivity of MS detection. 相似文献
6.
Aluminium reacts with 7-iodo-8-quinolinol-5-sulphonic acid (Ferron) in cetyltrimethylammonium bromide (CTAB) micelles to form a highly phosphorescent complex at room temperature. Suitable experimental conditions and the phosphorescent characteristics of the complex are described. Comparison with the results obtained for the phosphorescent niobium-Ferron complex in CTAB micelles helps to elucidate the mechanism of this type of phosphorescence. For aluminium the detection limit is 5.4 ng ml?1; the relative standard deviation is 4.5% for 20 μg Al. The method is applied to aluminium determination in waters and dialysis fluids. 相似文献
7.
Campa C Oust A Skjåk-Braek G Paulsen BS Paoletti S Christensen BE Ballance S 《Journal of chromatography. A》2004,1026(1-2):271-281
The average degree of polymerisation (DP) and distribution of oligosaccharides in partially acid hydrolysed mannuronans were quantitatively evaluated by 1H NMR, electrospray ionisation mass spectrometry (ESI-MS), micellar electrokinetic capillary chromatography with UV detection (MEKC-UV), and high-pressure anion-exchange chromatography with pulsed amperometric detection (HPAEC-PAD). Our investigation shows that 1H NMR, MEKC-UV and, in particular, HPAEC-PAD can be used as quantitative tools to aid the investigation of polysaccharide structure, function and synthesis. For the latter two techniques, especially, this represents a significant new development as it enables calculation of the quantity of individual oligomers of nominal DP by direct analysis of a defined oligomer mixture. Appropriate statistical averages of number and weight distributions were also calculated and found to fit very well to predicted Kuhn distributions that assume random depolymerisation. 相似文献
8.
E. Ferrero J. F. Espeso J. G. de la Campa J. de Abajo A. E. Lozano 《Journal of polymer science. Part A, Polymer chemistry》2002,40(21):3711-3724
A series of polyisophthalamides containing pendent phthalimido groups and flexible side spacers were prepared from four novel diacids and three commercial aromatic diamines. These polyamides were prepared in high yields and with high molecular weights by direct polycondensation with triphenyl phosphite and pyridine as condensing agents. The weight‐average and number‐average molecular weights, measured by gel permeation chromatography, were 70,000–137,000 and 47,000–86,000 g/mol, respectively. The novel polyamides were amorphous and readily soluble and showed glass‐transition temperatures of 150–240 °C, as measured by differential scanning calorimetry. Thermogravimetric analysis showed that the 10% weight‐loss temperatures in nitrogen were 355–430 °C, a significant improvement in thermal stability having been observed with the increase in the side‐chain length. A theoretical quantum mechanical study was successfully carried out to explain these results. Flexible and tough films, cast from polymer solutions, showed tensile strengths of 50–125 MPa. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 3711–3724, 2002 相似文献
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