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1.
Design theory crosses the boundary between mathematics and statistics, and includes a wide range of disparate types of design. In this paper we present a classification scheme which aims to include as many important types as possible, based on a balance among concept, representation and use. 相似文献
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We wish to report synthesis of perfluorinated functionalized, branched ethers from their hydrocarbon analogues by direct fluorination. Yields up to 90%, with high purities, have been obtained at ambient temperature and pressure. This technique will likely develop into a new general method for producing perfluorinated, hyperbranched and dendritic polymers. 相似文献
4.
Peter J. Cameron 《组合设计杂志》2005,13(6):466-470
It is shown that there is a function g on the natural numbers such that a partial Steiner triple system U on u points can be embedded in a Steiner triple system V on ν points, in such a way that all automorphisms of U can be extended to V, for every admissible ν satisfying ν > g(u). We find exponential upper and lower bounds for g. © 2005 Wiley Periodicals, Inc. J Combin Designs. 相似文献
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Peter J. Cameron 《Probability Theory and Related Fields》1987,76(4):523-531
Summary There is a natural probability measure on the set of all sum-free sets of natural numbers. If we represent such a set by its characteristic functions, then the zero-one random variabless(i) are far from independent, and we cannot expect a law of large numbers to hold for them. In this paper I conjecture a decomposition of into countably many more tractible pieces (up to a null set). I prove that each piece has positive measure, and show that, within each piece, a random set almost surely has a density which is a fixed rational number depending only on the piece. For example, the first such piece is made up of sets consisting entirely of odd numbers; it has probability 0.218 ..., and its members almost surely have density 1/4. 相似文献
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Summary Polymerisation of bicontinuous microemulsions yields porous monolithic structures with well defined pore sizes that are potentially
suitable for use as stationary phases for capillary electrochromatography (CEC). A variety of pore sizes can be achieved by
altering the composition of the microemulsion, which typically consists of butyl methacrylate (BMA) and ethylene glycol dimethacrylate
(EGDMA) as the polymerisable oil phase. The aqueous phase consists of water, a surfactant (sodium dodecyl sulphate, SDS) and
a co-surfactant (1-propanol). 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS) is also added to provide charges along
the polymer backbone to allow electroosmotic flow (EOF) to occur. SEM analysis shows that in-situ polymerisation yields a
monolithic structure with a porous topography. Investigations have shown that these monoliths are easy to prepare, robust
and suitable for the separation of phthalates. They generate higher linear velocities than are achieved using the silica based
HPLC packings normally used for CEC. 相似文献
9.
Sharon E. Davis A. Cameron Church Rebecca C. Tummons Charles F. Beam 《Journal of heterocyclic chemistry》1997,34(4):1159-1162
C(α)-Carboxylic acid esters were treated with excess lithium diisopropylamide, condensed with methyl salicylates or methyl thiosalicylate, followed by acid cyclization to either 4-hydroxy-3-substituted, 2H-1-benzopyran-2-ones (coumarins), or 2H-1-benzothiopyran-2-ones (thiocoumarins). 相似文献
10.
K. Yuvaraj Iskander Douair Dafydd D. L. Jones Laurent Maron Cameron Jones 《Chemical science》2020,11(13):3516
An extremely bulky, symmetrical three-coordinate magnesium(i) complex, [{(TCHPNacnac)Mg}2] (TCHPNacnac = [{(TCHP)NCMe}2CH]−, TCHP = 2,4,6-tricyclohexylphenyl) has been prepared and shown to have an extremely long Mg–Mg bond (3.021(1) Å) for such a complex. It was shown not to react with either DMAP (4-dimethylaminopyridine) or CO. Three unsymmetrical 1 : 1 DMAP adducts of less bulky Mg–Mg bonded species have been prepared, viz. [(ArNacnac)Mg–Mg(DMAP)(ArNacnac)] (ArNacnac = [(ArNCMe)2CH]− Ar = 2,6-xylyl (Xyl), mesityl (Mes) or 2,6-diethylphenyl (Dep)), and their reactivity toward CO explored. Like the previously reported bulkier complex, [(DipNacnac)Mg–Mg(DMAP)(DipNacnac)] (Dip = 2,6-diisopropylphenyl), [(DepNacnac)Mg–Mg(DMAP)(DepNacnac)] reductively trimerises CO to give a rare example of a deltate complex, [{(DepNacnac)Mg(μ-C3O3)Mg(DMAP)(DepNacnac)}2]. In contrast, the two smaller adduct complexes react with only two CO molecules, ultimately giving unusual ethenediolate complexes [{(ArNacnac)Mg{μ-OC(H) C(DMAP−H)O}Mg(ArNacnac)}2] (Ar = Xyl or Mes). DFT calculations show the latter reactions to proceed via reductive dimerizations of CO, and subsequent intramolecular C–H activation of Mg-ligated DMAP by “zig–zag” [C2O2]2− fragments of reaction intermediates. Calculations also suggest that magnesium deltate complexes are kinetic products in these reactions, while the magnesium ethenediolates are thermodynamic products. This study shows that subtle changes to the bulk of the reacting 1 : 1 DMAP–magnesium(i) adduct complexes can lead to fine steric control over the products arising from their CO reductive oligomerisations. Furthermore, it is found that the more activated nature of the adduct complexes, relative to their symmetrical, three-coordinate counterparts, [{(ArNacnac)Mg}2], likely derives more from the polarisation of the Mg–Mg bonds of the former, than the elongated nature of those bonds.Subtle changes to the bulk of 1 : 1 adducts of DMAP with magnesium(i) complexes leads to steric control over the products arising from their reductive oligomerisations of carbon monoxide. 相似文献