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Menéndez FE Espina Aránzazu Trobajo Camino García José R. Rodríguez Julio 《Journal of inclusion phenomena and macrocyclic chemistry》1993,15(3):215-230
Journal of Inclusion Phenomena and Macrocyclic Chemistry - The intercalation reactions betweenn-alkylamines and α-titanium phosphate in aqueous media have been investigated. The compounds with... 相似文献
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FE Menéndez Aránzazu Espina Camino Trobajo José R. García Julio Rodríguez 《Journal of inclusion phenomena and macrocyclic chemistry》1994,15(3):215-230
The intercalation reactions betweenn-alkylamines and -titanium phosphate in aqueous media have been investigated. The compounds with the maximum intercalation have the formula -Ti(HOPO3)2 · 2 C
n
H
2n+1
NH2 · H2O (n=1–10). Defined crystalline phases with lower amine content are described, the general formula being -Ti(HOPO3)2 ·
m
C
n
H
2n+1
NH2 ·pH2O (m=1.0 1.3, 1.5, 1.7). Whenm=1.0 then-alkylamines form a monomolecular layer. Whenm>1.0 the layer is bimolecular. The inclination angle and the packing density of then-alkylamines in the interlayer space is determined. 相似文献
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