SPECTRAL CHARACTERISTICS OF THE EXCITED STATES OF THE PRODUCT OF THE CHEMILUMINESCENCE OF LUMINOL*

Abstract— In dimethylsulfoxide the emission spectrum of luminol chemiluminescence is red-shifted by 300 cm^-1 from the photoexcited fluorescence of the product 3-aminophthalate dianion, while in aqueous solvent the two spectra are identical. The spectral properties of the product dianion have been measured in aqueous solvent and in a number of aprotic solvents, both at room temperature and at 77°K. The ground states and the excited states from which emissions are observed are characterized. Two alternatives are presented to explain the aprotic emission spectra.     

垃圾气化分析及其对中国实现碳中和与无废城市建设的贡献

气化是实现化学利用碳资源(尤其是煤)生产化学品和燃料的关键工艺.目前,全球拥有超过272套气化装置,主要应用于煤化工,尤其在中国.由于在一个化工厂通过技术集成达到工业规模的集中生产可实现减少二氧化碳排放并促进碳密集型行业的循环经济,如废物管理、化学和交通行业,因此,近年来全球对垃圾气化的兴趣日益浓厚,尤其是那些在煤气化...     

掺Ba对Bi系2212相超导电性的影响

研究了掺Ｂａ对Bi₂Sr_2-xBa_xCaCu₂O_y（０≤ｘ≤０．１５，０．３）单晶和多晶样品超导电性的影响，结果表明，有少量Ｂａ^２＋离子进入了超导相，且有固溶度极限．对于２２１２相单晶，ｃ轴参数和Ｔ_c均随Ｂａ含量增加而增加；对于慢冷多晶样品，掺Ｂａ可明显提高Ｔ_c；然而对于淬大多晶样品，Ｔ_c没有明显变化，用掺Ｂａ 关键词：     

DYNAMIC STABILITY OF SKEW PLATES SUBJECTED TO AERODYNAMIC AND RANDOM IN-PLANE FORCES

This paper presents an investigation into the dynamic stability of skew plates acted upon simultaneously by an aerodynamic force in the chordwise direction and a random in-plane force in the spanwise direction. Due to this random in-plane force, the plate may become unstable before the aerodynamic force reaches its critical value. In this work, the finite element formulation is applied to obtain the discretized system equations. The system equations are then partially uncoupled and reduced in size by the modal truncation method. Finally, the unsmoothed and the smoothed versions of the stochastic averaging are used to calculate the system response, and the second-moment stability criterion is utilized to determine the stability boundary of the system. Numerical results show that the stability boundary obtained by the smoothed stochastic averaging is less conservative than that obtained by the unsmoothed version, and the former is the tangent of the latter at zero spectral density of the random in-plane force.     

在铅板里发生的电子光子簇射

关于把电子光子簇射的实验与理论相比较的工作,还是非常的少。我们在用云雾室研究穿透簇射和星芒的过程中,也获得一些电子光子簇射的照片。从中选择了适合于研究条件的一部分,加以分析,与理论作比较。     

The Properties of Surface Polaron in the Semi-Infinite Polar Crystal

The effective Hamiltonian and the renormalized mass of surface polaron, where the electron is strongly coupled with the surface optical (SO) phonons but weakly or intermediately coupled with the bulk longit udinal-optical (LO) phonons, were first reviewed. The self-energy and the renormalized mass of the polaron for the polar crystals of potassium iodide, silver chloride and silver bromide are evaluated as a function of the depth Gom the crystal surface. Results of our calculation indicate that the effect of the electron-SO phonon interaction is dominant only within a very small layer from the crystal surface. Its justification awaits further experimental results.     

Prolongation Approach to the Liouville Equation and Its Algebraic Structures

The Riccati type equation, the Biicklund transformation and the Lax pair of the Liouville equation are obtained by using the prolongation theory. It is shown that the prolongation structures generate the SL(2,R) Lie algebra.     

锗酸锌锰荧光体发光学与荧光瞬态衰减研究

制备一系列锗酸锌锰荧光体,并探讨其发光特性、瞬态荧光衰减与色度值与所掺杂锰离子含量之间的相互关系.本系列荧光体锰离子发射峰波长,随Mn²⁺含量由0增加0.05,由527nm红移至534nm.实验表明这可能与Mn²⁺所占据的四面体格位,遭扭曲而导致晶场强度变弱有关.本系列荧光体的CIE色度坐标值,则随所掺杂Mn²⁺含量,仅有微小改变.锗酸锌锰荧光体瞬态荧光衰减的研究结果表明:锗酸锌基质的衰减生命期在纳秒范围;随Mn²⁺掺杂量增加,在毫秒范围的锰离子荧光衰减生命期逐渐缩短.此现象可能与Mn²⁺-Mn²⁺离子对中,Mn²⁺的自旋交换相互作用有密切关系.     

基于熵条件二阶差分格式的嵌套网格分区算法

以带熵条件的二阶TVD格式为基本格式,设计了三维曲线坐标下的Euler方程数值计算方法.对多个物体使用分区嵌套网格设计了相应的分区算法.所建立的算法适用于处理物体相互分离以及相互接触的定常与非定常流动问题.给出了绕两圆柱的超声速流动在两圆柱处于不同位置时的详细结果,并模拟了装配鸭舵火箭弹在超声速旋转飞行时的气动特性.     

ON THE ACOUSTIC ABSORPTION OF MULTI-LAYER ABSORBERS WITH DIFFERENT INNER STRUCTURES

A rigorous finite element analysis procedure is developed to study the effect of the inner structures on the acoustic absorption of multi-layer absorbers. To do this, four types of basic inner structure compartments adopted in the multi-layer absorbers are selected for analysis. These compartments are composed of porous materials inlaid with perforated plates of various shapes, say, triangle, semicircle, convex rectangle and plate shapes. As it is different from the conventional finite element analysis for the acoustic system in the literature, the perforated plates are simulated by appropriate equivalent boundary conditions, depending on their thickness, hole radius, hole pitch and porosity and the air contained in the holes. A large number of total degrees of freedom generated from meshing the air in the holes of perforated plates are thus avoided. The results reveal that the inner structures of the multi-layer absorbers will influence the acoustic absorption at some frequency bands significantly. Based on those features, the multi-layer absorber with a novel inner structure is then designed and manufactured. Both the finite element and experimental results show that its acoustic absorption would be distinctly promoted.