The Effect of a Biostimulant Based on a Protein Hydrolysate of Rainbow Trout (Oncorhynchus mykiss) on the Growth and Yield of Wheat (Triticum aestivum L.)

The research object was the liquid protein hydrolysate “AGROMOREE” from the rainbow trout, which was provided by the company “Russian Aquaculture LLC”. The purpose of this study was the evaluation of the effect of the hydrolysate “AGROMOREE” as a biostimulant on the growth and yield of wheat (Triticum aestivum L.). Biometric indicators of wheat (Triticum aestivum L.) growth were determined in the laboratory and in field tests. In the laboratory, the liquid concentrated hydrolysate was dried to facilitate its use. “AGROMOREE” promoted an increase in germination of 2–4% in all samples compared to the control samples, as well as an increase in the length and number of wheat roots. The biostimulant “AGROMOREE” was introduced in the soil in liquid form at about 3000 L/ha and 4000 L/ha in the field tests. This study showed that “ARGOMOREE” contributed to an increase in the length and quantity of wheat ears, the quantity of grains in the ear and the seed weight. At the same time, the quantity of productive stems increased, so that the biostimulant “AGROMOREE” increased the productivity by 3.9–6.3% with respect to the control sample. In general, using the biostimulant “AGROMOREE” on spring wheat seeds from 2019 in the growing season of 2021 provided an increase in yield from 0.21 t/ha to 0.28 t/ha. The maximum value of raw gluten content in the seed was 5.2%, higher than the content in the control. The content of the mass fraction of protein in the seed was in the range of 12.33–12.56%, i.e., 2% higher than that of the control sample. Thus, according to qualitative and quantitative indicators and the total productivity indicators, the biostimulant «AGROMOREE» can be used to increase wheat productivity and reduce the use of nitrogen fertilizers.     

The use of iron carbonyls in the C—C bond formation reactions

Russian Chemical Bulletin - The review systematizes material by key types of reactions promoted by iron carbonyls. The reaction types are subdivided into several principal directions, focusing...     

Novel ligands based on bromosubstituted hydroxycarbonyl [2.2]paracyclophane derivatives: synthesis and application in asymmetric catalysis

New planar-chiral hydroxycarbonyl [2.2]paracyclophane derivatives, 4-acetyl-13-bromo-5-hydroxy[2.2]paracyclophane (Br-АНРС, 63%) and 4-benzoyl-13-bromo-5-hydroxy[2.2]paracyclophane (Br-BHPC, 53%), were synthesized and reacted with the enantiomers of α-phenylethylamine to form corresponding Schiff bases, 12-bromo-4-hydroxy-5[1-(1-phenyl-ethylimino)-ethyl]-[2.2]paracyclophane and 12-bromo-4-hydroxy-5[1-(1-phenyl-ethylimino)-(phenyl)methylen-[2.2]paracyclophane. The diastereomers of the imines were resolved and their absolute configurations and consequently the corresponding configurations of the enantiomers of Br-АНРС were determined by X-ray diffraction. Enantiomerically pure Schiff bases were applied as ligands to form catalysts for the enantioselective addition reaction of diethylzinc with benzaldehyde where 1-phenylpropanol was obtained with 77–91% ee.     

Anisotropy of the ionic conductivity and dielectric response in orthorhombic and monoclinic inorganic fluorides

The anisotropy of the ionic conductivity and permittivity of (1) BaR₂F₈ (R=rare earth element) single crystals with monoclinic BaTm₂F₈ structure and of (2) (β-YF₃ structured) rare earth trifluorides is studied. Single crystals, eutectic composites and ceramics are investigated in a broad temperature range. In the monoclinic BaR₂F₈ crystals, a pronounced anisotropy of the ionic conductivity and a slight anisotropy of the permittivity are found. The fastest ionic transport with the lowest activation energy (0.563 eV) and the highest value of the permittivity are observed along thea axis. The temperature dependencies of the fluoride ion conductivities of various orthorhombic rare earth trifluorides differ only slightly from one another. For the bulky single crystals, the conductivity at 500 °C and the conduction activation enthalpy are equal to 1.1(4)×10⁻⁵ S/cm and 0.75(3) eV, respectively. The ionic conductivity is almost isotropic, but the anisotropy of the permittivity is significant. For the fluorides of both structural types, plausible conduction mechanisms are proposed, networks of most probable conduction paths are presented and the origin of the observed anisotropy of the ionic conductivity is elucidated. Paper presented at the 4th Euroconference on Solid State Ionics, Renvyle, Galway, Ireland, Sept. 13–19, 1997     

Preparation of some derivatives of 3-mercaptopropionic acid,cystamine, and cysteamine and study of their radiation protection properties

Conclusions A number of new derivatives of 3-mercaptopropionic acid, cystamine, and cysteamine were synthesized, and their radiation protection properties were studied.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 334–341, February, 1967.     

Sulfur-containing heterocycles. Communication 10. Synthesis of mixed anhydrides of sulfonic and carboxylic acids

Conclusions A general method was developed for the preparation of previously unreported anhydrides of-sulfinocarboxylic acids, namely, 1,2-oxathiolan-5-one-2-oxides and 2,1-benzoxathibl-3-one-1-oxide (XIV) by the action of disodium salts of-oxysulfinylcarboxylic acids with oxalyl chloride.For Communication 9, see [1]Deceased.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 617–623, March, 1984.