Radical addition fragmentation chain transfer (RAFT) polymerization of ferrocenyl (Meth)acrylates

We report on the controlled free radical homopolymerization of 1‐ferrocenylethyl acrylate as well as of three new ferrocene bearing monomers, namely 4‐ferrocenylbutyl acrylate, 2‐ferrocenylamido‐2‐methylpropyl acrylate, and 4‐ferrocenylbutyl methacrylate, by the RAFT technique. For comparison, the latter monomer was polymerized using ATRP, too. The ferrocene containing monomers were found to be less reactive than their analogues free of ferrocene. The reasons for the low polymerizability are not entirely clear. As the addition of free ferrocene to the reaction mixture did not notably affect the polymerizations, sterical hindrance by the bulky ferrocene moiety fixed on the monomers seems to be the most probable explanation. Molar masses found for 1‐ferrocenylethyl acrylate did not exceed 10,000 g mol^?1, while for 4‐ferrocenylbutyl (meth)acrylate molar masses of 15,000 g mol^?1 could be obtained. With PDIs as low as 1.3 in RAFT polymerization of the monomers, good control over the polymerization was achieved. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012     

Subcentimeter depth resolution using a single-photon counting time-of-flight laser ranging system at 1550 nm wavelength

We demonstrate subcentimeter depth profiling at a stand off distance of 330 m using a time-of-flight approach based on time-correlated single-photon counting. For the first time to our knowledge, the photon-counting time-of-flight technique was demonstrated at a wavelength of 1550 nm using a superconducting nanowire single-photon detector. The performance achieved suggests that a system using superconducting detectors has the potential for low-light-level and eye-safe operation. The system's instrumental response was 70 ps full width at half-maximum, which meant that 1 cm surface-to-surface resolution could be achieved by locating the centroids of each return signal. A depth resolution of 4 mm was achieved by employing an optimized signal-processing algorithm based on a reversible jump Markov chain Monte Carlo method.     

Vectorial Approach to Fast Correlation Attacks

A new, vectorial approach to fast correlation attacks on binary memoryless combiners is proposed. Instead of individual input sequences or their linear combinations, the new attack is targeting subsets of input sequences as a whole thus exploiting the full correlation between the chosen subset and the output sequence. In particular, the set of all the input sequences can be chosen as the target. The attack is based on a novel iterative probabilistic algorithm which is also applicable to general memoryless combiners over finite fields or finite rings. To illustrate the effectiveness of the introduced approach, experimental results obtained for random balanced combining functions are presentedMost of this work was done while he was with Rome CryptoDesign Center, Gemplus, Italy     

On the Motion of a Dynamic System with Minimal Dissipation

The motion of a holonomic scleronomic non-conservative mechanicalsystem with minimal dissipation is considered. As applicationsof the theory several problems are studied in detail.     

Noise from neighbours and the sound insulation of party walls in houses

Nine-hundred-and-seventeen residents in a sample of attached houses constructed since 1970 were interviewed in the course of a national survey dealing with nuisance occasioned by noise from neighbours. The airborne sound insulation of the party walls, measured prior to occupation, ranged from zero to 120 dB AAD. Two-thirds of the respondents heard noise from their neighbours and even at performance levels meeting or exceeding the minimum requirements of the Building Regulations nearly 50% did so. Of the total sample, some 18% were seriously bothered by neighbours' noise. Highly significant relationships were found between physical performance rated in dB AAD (Aggregate Adverse Deviation) and a variety of subjective responses. These include reports of hearing neighbours' noise, of being bothered by it, hearing neighbours' conversation, and, in particular, the direct rating of sound insulation quality by respondents, which last appears to provide the most reliable and consistent indication of the likelihood of experiencing nuisance from neighbours' noise. These results provide, for the first time, empirical validation of the U.K. performance rating procedure. In addition, the survey findings emphasize the importance of impact noises, not included in the standardized performance measurements, but which contribute substantially to nuisance, particularly between houses where airborne sound insulation is comparatively good. Other findings indicate that occupants were very satisfied with their general environment and only slightly less so with their homes. Poor sound insulation was a prominent criticism of the dwellings, being ranked third among spontaneous adverse comments and first in a ranking of nine commonly encountered building defects. These results indicate the importance of sound insulation to occupants of recently built houses, placing this aspect of design and construction within a wider context. The overall results of the survey provide a practical guide to estimating the consequences, in terms of occupants' attitudes to noise from neighbours, of raising or lowering standards of sound insulation performance between houses.     

Energy Exchange at Degenerate Mixing of Four Fast TE 2 Modes of a Thin Left-Handed Film on a Nonlinear Substrate

Frequency-degenerate mixing of forward and backward propagating fast modes is considered in a planar optical waveguide based on a thin left-handed film and a right-handed substrate exhibiting the Kerr effect. Nonlinear coupled-mode equations are solved for the intensities of these modes in the neglect of the contributions of elementary processes that fail to satisfy the phase-matching condition. It is shown that the intramode self-action of four TE modes is accompanied by energy exchange between these modes. The efficiency of energy exchange varies periodically along the propagation direction of modes, thus leading to the inversion of the intensities of forward and backward propagating light fields on the interaction half-period.