全文获取类型
收费全文 | 254篇 |
免费 | 22篇 |
国内免费 | 1篇 |
专业分类
化学 | 164篇 |
力学 | 16篇 |
数学 | 38篇 |
物理学 | 59篇 |
出版年
2022年 | 3篇 |
2021年 | 2篇 |
2020年 | 2篇 |
2018年 | 6篇 |
2017年 | 2篇 |
2016年 | 9篇 |
2015年 | 6篇 |
2014年 | 13篇 |
2013年 | 6篇 |
2012年 | 8篇 |
2011年 | 21篇 |
2010年 | 10篇 |
2009年 | 4篇 |
2008年 | 16篇 |
2007年 | 10篇 |
2006年 | 9篇 |
2005年 | 10篇 |
2004年 | 8篇 |
2003年 | 4篇 |
2002年 | 14篇 |
2001年 | 5篇 |
2000年 | 8篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1993年 | 2篇 |
1992年 | 5篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 5篇 |
1987年 | 5篇 |
1985年 | 6篇 |
1983年 | 2篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 8篇 |
1978年 | 3篇 |
1977年 | 8篇 |
1976年 | 5篇 |
1975年 | 4篇 |
1974年 | 3篇 |
1973年 | 2篇 |
1968年 | 2篇 |
1966年 | 2篇 |
1940年 | 2篇 |
1936年 | 2篇 |
1924年 | 1篇 |
1923年 | 1篇 |
1917年 | 1篇 |
1905年 | 2篇 |
1890年 | 2篇 |
排序方式: 共有277条查询结果,搜索用时 15 毫秒
1.
Paul A. Binding Patrick J. Browne Bruce A. Watson 《Journal of Mathematical Analysis and Applications》2004,291(1):246-261
Three inverse problems for a Sturm-Liouville boundary value problem −y″+qy=λy, y(0)cosα=y′(0)sinα and y′(1)=f(λ)y(1) are considered for rational f. It is shown that the Weyl m-function uniquely determines α, f, and q, and is in turn uniquely determined by either two spectra from different values of α or by the Prüfer angle. For this it is necessary to produce direct results, of independent interest, on asymptotics and oscillation. 相似文献
2.
3.
4.
Di Pietro C Serroni S Campagna S Gandolfi MT Ballardini R Fanni S Browne WR Vos JG 《Inorganic chemistry》2002,41(11):2871-2878
The synthesis and characterization of two dinuclear ruthenium polypyridyl complexes based on the bridging ligands 5,5'-bis(pyridin-2' '-yl)-3,3'-bis(1H-1,2,4-triazole) and 5,5'-bis(pyrazin-2' '-yl)-3,3'-bis(1H-1,2,4-triazole) and of their mononuclear precursors are reported. The dinuclear compounds have been prepared by a Ni(0) catalyzed coupling of a mononuclear ruthenium(II) polypyridyl complex containing a brominated triazole moiety. Electrochemical and photophysical studies indicate that, in these dinuclear complexes, the protonation state of the bridge may be used to tune the intercomponent interaction between the two metal centers and that these species act as proton driven three-way molecular switches that can be read by electrochemical or luminescence techniques. 相似文献
5.
The use of stable isotope-labeled tracer compounds is the safest and most effective method to perform many steady state pharmacokinetic and drug interaction studies. We describe a method by which the heavily deuterated 2H10 analogues of carbamazepine (2H10 CBZ) and phenytoin (2H10 PHT) can be chromatographically separated by high-performance liquid chromatography from unlabeled CBZ and PHT. All compounds are quantitated against an internal standard (IS) (10,11-dihydrocarbamazepine) and measured using conventional UV detection rather than mass spectrometry. Baseline resolution of extracted serum containing 2H10 CBZ, CBZ, 2H10 PHT, PHT and IS is achieved on a heated (55 degrees C) 25 cm x 4.6 mm BioAnalytical Systems Phase II 5 microns ODS column with an isocratic mobile phase consisting of water-acetonitrile-tetrahydrofuran (80:16:4, v/v/v) at 1.2 ml/min. Eluting compounds were monitored at a UV wavelength of 214 nm. Calculated resolution of 2H10 CBZ from CBZ and of 2H10 PHT from PHT were 1.3. Serum standard curves were linear (R greater than or equal to 0.999) over a range of 0.5-14 micrograms/ml for 2H10 CBZ, 0.5-20 micrograms/ml for CBZ, 0.5-20 micrograms/ml for 2H10 PHT, and 0.5-30 micrograms/ml for PHT. Within-day percent relative standard deviations (precision) were less than 6% in all cases. 相似文献
6.
Accurate urinary measurements of the two major metabolites of phenytoin, 5-(p-hydroxyphenyl)-5-phenylhydantoin (p-HPPH) and 5-(3,4-dihydroxy-cyclohexa-1,5-dienyl)-5-phenylhydantoin (dihydrodiol, DHD), are necessary for pharmacokinetic and drug-interaction studies of this commonly used antiepileptic drug. We describe a simple, rapid, acid hydrolysis, with liquid-liquid extraction and simultaneous isocratic reversed-phase high-performance liquid chromatography of p-HPPH and 5-(m-hydroxyphenyl)-5-phenylhydantoin (m-HPPH) (hydrolytic end product of DHD). p-HPPH and m-HPPH were quantitated against their separate respective internal standards of alphenal and tolylbarb. The mobile phase consisted of water-dioxane-tetrahydrofuran (80:15:5, v/v/v) at 2 ml/min and at 50 degrees C, with detection at 225 nm. Baseline separation was achieved by use of a 16 cm x 3.9 mm Nova-Pak C18 column and total analysis time of 12 min. p-HPPH and m-HPPH concentrations ranged from 10 to 200 and from 2 to 30 micrograms/ml, respectively, with between-day coefficients of variations of 3.3-4.5% and 2.2-5.1% for controls. All standard curves were linear with r values greater than 0.993. The DHD concentration was determined by multiplying m-HPPH concentrations by 2.3. 相似文献
7.
8.
9.
Patrick J Browne 《Journal of Differential Equations》1977,23(2):285-292
In this paper we study the linked nonlinear multiparameter system , where xr? [ar, br], yr is subject to Sturm-Liouville boundary conditions, and the continuous functions ars satisfy ¦ . Conditions on the polynomial operators Mr, Prs are produced which guarantee a sequence of eigenfunctions for this problem yn(x) = Πr=1kyrn(xr), n ? 1, which form a basis in . Here [a, b] = [a1, b1 × … × [ak, bk]. 相似文献
10.
Isolation of teratogenic alkaloids by reversed-phase high-performance liquid chromatography 总被引:1,自引:0,他引:1
Reversed-phase high-performance liquid chromatography was used for both analytical and preparative separations of several steroidal alkaloids which occur in extracts of Veratrum californicum. The inclusion of 0.1% trifluoroacetic acid in the mobile phase improved the efficiency of the chromatography and the solubility of the compounds in aqueous acetonitrile. Nuclear magnetic resonance was used to assist the identification of the isolated steroidal alkaloids. The effect of the interaction of trifluoroacetic acid with the alkaloids could be clearly seen by changes in the chemical shifts in the nuclear magnetic resonance spectra. 相似文献