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1.
Fernaldo Richtia Winnerdy Bla Bakalar Poulomi Das Brahim Heddi Adrien Marchand Frdric Rosu Valrie Gabelica Anh Tun Phan 《Chemical science》2021,12(20):7151
Cations are critical for the folding and assembly of nucleic acids. In G-quadruplex structures, cations can bind between stacked G-tetrads and coordinate with negatively charged guanine carbonyl oxygens. They usually exchange between binding sites and with the bulk in solution with time constants ranging from sub-millisecond to seconds. Here we report the first observation of extremely long-lived K+ and NH4+ ions, with an exchange time constant on the order of an hour, when coordinated at the center of a left-handed G-quadruplex DNA. A single-base mutation, that switched one half of the structure from left- to right-handed conformation resulting in a right–left hybrid G-quadruplex, was shown to remove this long-lived behaviour of the central cation.An extremely long-lived cation has been detected in left-handed G-quadruplexes. 相似文献
2.
Brahim Lakhrissi Mohamed Massoui El Mokhtar Essassi Vincent Lequart Nicolas Joly Patrick Martin Grard Goethals 《Journal of heterocyclic chemistry》2004,41(6):1011-1014
Reaction of 1,5‐benzodiazepin‐2,4‐dione with 3‐O‐substituted‐5,6‐anhydro‐1,2‐isopropylidene‐α‐D‐glucofuranose gave the unexpected N,N'‐di‐glucofuranosyl benzimidazol‐2‐one by a novel rearrangement and ring closure reaction. A mechanism is proposed. 相似文献
3.
Abdellah Ziadi Harald Hillebrecht Brahim Elouadi 《Journal of solid state chemistry》2004,177(12):4777-4784
The crystal structure of Na3DySi6O15 has been solved and refined to an R1=2.97% (wR2=8.25%) for 1311 independent reflections. The compound was found to crystallize within the orthorhombic system with the space group Cmca (Z=8) and the lattice parameters: a=14.590(7) Å, b=17.813(4) Å, c=10.519(2) Å, V=2734.0 Å3, Dcal=3.11 g/cm3. The structure of Na3DySi6O15 is a filled variant of the zektzerite with S like corrugated double chains of [SiO4] tetrahedral, connected via Na+ and Dy3+ cations and running parallel to c-axis. The three-dimensional network results from the packing of these chains along [100] by skewering them in rods represented by the tunnels delimited by the S shape of the silicate chains. One of the main peculiar features of the Na3DySi6O15 structure is the location of Na+ in tetrahedral sites with rather short Na-O bond lengths (2×2.243 and 2×2.262 Å). 相似文献
4.
5.
Carlo Massobrio Brahim Nacer 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1997,40(1):526-529
By means of molecular dynamics simulations based on realistic n-body potentials we investigate structural and dynamical features inherent to the energetic collision of a silver cluster (Ag19) on the Pd(100) substrate. Both the system and the impact energy (Ei = 95 eV) adopted have been chosen to parallel an experimental study of size selected Ag cluster deposition on Pd(100). Our results indicate that the experimental cross section obtained via thermal energy atom scattering at the same collision energy is well reproduced by the simulations.The modeling allows to rationalize the collision outcome in terms of defect production and cluster atoms implantation. The adsorbed structures have an heterogenous nature and are mostly two-dimensional. 相似文献
6.
An inorganic compound formulated as K3.31(NH4)0.69[Se2Mo5O21]·2H2O has been synthesized by conventional solution method and characterized by scanning electron microscopy, IR, UV-Vis spectroscopies behaviors. The structure of the title compound has been determined from a single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P21/n, with a?=?9.9371(2) ?, b?=?23.3545(2) ?, c?=?10.5179(2) ?, β?=?114.12(3)°, V?=?2227.7(5) ?3 and Z?=?4. It was revealed that the Strandberg-type polyoxoselenomolybdate cluster can be considered as a ring formed by five distorted edge- and corner-sharing MoO6 octahedra, capped on both poles by a selenate pyramids sharing three vertices with the ring molybdenum centers. The Strandberg clusters are connected with ammonium ions and water molecules through hydrogen-bonding interactions which ensure the cohesion of the structure into a three-dimensional network. 相似文献
7.
8.
S. B. Vakhrushev A. P. Shaganov B. Dkhil D. Lebolock K. Ouvada 《Physics of Particles and Nuclei Letters》2011,8(10):1061-1062
We present the results of an investigation into processes of formation of polar nanoregions and the relaxation dynamics of
a cubic relaxor ferroelectric (PbMg1/3Nb2/3O3)0.9-(pbTiO3)0.1 (PMNPT10), selected to be studied as a model compound. 相似文献
9.
Brahim Alouini 《Mathematical Methods in the Applied Sciences》2021,44(1):91-103
In this article, we present, throughout two basic models of damped nonlinear Schrödinger (NLS)–type equations, a new idea to bound from above the fractal dimension of the global attractors for NLS‐type equations. This could answer the following open issue: consider, for instance, the classical one‐dimensional cubic nonlinear Schrödinger equation “How can we bound the fractal dimension of the associate global attractor without the need to assume that the external forcing term f has some decay at infinity (that is belonging to some weighted Lebesgue space)?” 相似文献
10.
Fayçal Boukhari Nacéra Tigrine‐Kordjani Brahim Youcef Meklati 《Helvetica chimica acta》2013,96(6):1168-1175
Walnut (Juglans regia L.) leaves are used traditionally as an herbal tea indicated for non‐insulin‐dependent diabetics. In recent years, the type‐II diabetes is occurring worldwide with increasing frequency. Thus, there is an urgent need to explore the new beneficial biomolecules on the human health. Our objective was to investigate, for the first time, the volatiles profile of Juglans regia L. leaves from Algiers region. The extraction of essential oil of fresh plant material was performed by microwave‐assisted hydrodistillation (MAHD), for the first time, a relatively recent method, then by the conventional hydrodistillation technique (HD) for comparison. The collected extracts were analyzed by GC‐FID and GC/MS using two capillary columns with different polarity. Extraction time of 1 h by MAHD provided higher yields (0.050±0.001% (w/w)) than by HD (0.030±0.006% (w/w)) after 3 h. A total of 38 compounds were identified using both techniques. Essential oils had similar qualitative but different quantitative composition in terms of chemical compounds. The MAHD method improved yield while reducing the extraction time. The sesquiterpenes were the dominant family in both MAHD and HD essential oils with β‐caryophyllene being the major constituent. Monoterpenes, including hydrocarbon and oxygenated, prevail in HD volatile fraction with β‐pinene and eucalyptol, respectively, as major components. 相似文献