排序方式: 共有48条查询结果,搜索用时 15 毫秒
1.
Poon T Turro NJ Chapman J Lakshminarasimhan P Lei X Jockusch S Franz R Washington I Adam W Bosio SG 《Organic letters》2003,5(26):4951-4953
Oxazolidinone-substituted enecarbamates represent a mechanistically rich system for the study of stereoelectronic, steric, and conformational effects on stereoselectivity and mode selectivity in (1)O(2) [2 + 2] and ene reactions. Photooxygenation of these enecarbamates with (1)O(2) leads to diastereomerically pure dioxetanes that decompose to yield an oxazolidinone carbaldehyde and one of the two enantiomers of methyldesoxybenzoin in enantiomeric excess. Stereoselectivity originates at the allylic stereocenter, a result supported by quenching studies, computational analysis, and deuterium solvent isotope effects. [reaction: see text] 相似文献
2.
Adam W Bargon RM Bosio SG Schenk WA Stalke D 《The Journal of organic chemistry》2002,67(20):7037-7041
The direct molybdenum-catalyzed sulfuration of a variety of isonitriles with elemental sulfur or propene sulfide as sulfur donors affords the corresponding isothiocyanates in good yields and under mild reaction conditions. A catalytic cycle is suggested, in which the molybdenum oxo disulfur complex operates as the active sulfur-transferring species. A novel adduct between the isonitrile and the molybdenum complex has been characterized by X-ray analysis and its association constant determined by UV-vis spectroscopy, but this adduct appears not to be involved in the sulfur-transfer process. 相似文献
3.
J. Dorenbosch F. Udo J. V. Allaby U. Amaldi G. Barbiellini M. Baubillier F. Bergsma A. Capone W. Flegel F. Grancagnolo M. Jonker L. Lanceri M. Metcalf C. Nieuwenhuis J. Panman R. Plunkett C. Santoni K. Winter I. Abt F. W. Büsser H. Daumann P. D. Gall T. Hebbeker F. Niebergall P. Stähelin P. Gorbunov E. Grigoriev V. Kaftanov V. Khovansky A. Rosanov A. Baroncelli L. Barone B. Borgia C. Bosio M. Diemoz U. Dore F. Ferroni E. Longo L. Luminari P. Monacelli S. Morganti F. de Notaristefani L. Tortora V. Valente CHARM Collaboration 《Zeitschrift fur Physik C Particles and Fields》1989,41(4):567-589
A determination of sin2 θ w based on measurements of elastic scattering of muon-neutrinos and muon-anti-neutrinos on atomic electrons is described. These purely leptonic processes were studied using the CHARM calorimeter exposed to neutrino and antineutrino wide-band beams at the CERN super proton synchrotron. A total of 83±16 neutrino-electron and 112±21 antineutrino-electron events have been detected. From the measurement of the ratio of muon-neutrino and muon-antineutrino cross-sections a value of sin2 θ w =0.211±0.037 was obtained. 相似文献
4.
5.
Steffen Borchers Sandro Bosio Rolf Findeisen Utz-Uwe Haus Philipp Rumschinski Robert Weismantel 《Mathematical Methods of Operations Research》2011,73(3):381-400
This paper focuses on combinatorial feasibility and optimization problems that arise in the context of parameter identification
of discrete dynamical systems. Given a candidate parametric model for a physical system and a set of experimental observations,
the objective of parameter identification is to provide estimates of the parameter values for which the model can reproduce
the experiments. To this end, we define a finite graph corresponding to the model, to each arc of which a set of parameters
is associated. Paths in this graph are regarded as feasible only if the sets of parameters corresponding to the arcs of the
path have nonempty intersection. We study feasibility and optimization problems on such feasible paths, focusing on computational
complexity. We show that, under certain restrictions on the sets of parameters, some of the problems become tractable, whereas
others are NP-hard. In a similar vein, we define and study some graph problems for experimental design, whose goal is to support
the scientist in optimally designing new experiments. 相似文献
6.
Phthalocyanines R, PcM (R = alkyl, M = H, Ni, Cu) substituted with alkyl chains have been synthesized and their liquid crystalline properties studied by differential scanning calorimetry and X-ray diffraction at small angles. The influence of the chain length on the mesomorphic properties has been determined. A model is proposed to rationalize the structural modifications induced by varying the nature of the connecting link between the macrocycle and the side chains (alkyl, alkoxymethyl, alkoxy). 相似文献
7.
M. Jonker F. Udo J. V. Allaby U. Amaldi G. Barbiellini A. Capone W. Flegel M. Metcalf J. Meyer F. L. Navarria J. Panman A. M. Wetherell K. Winter F. W. Büsser H. Daumann P. D. Gall E. Metz F. Niebergall K. H. Ranitzsch P. Stähelin E. Grigoriev V. Kaftanov V. Khovansky A. Rosanov A. Baroncelli B. Borgia C. Bosio F. Ferroni E. Longo P. Monacelli F. de Notaristefani P. Pistilli C. Santoni V. Valente 《Zeitschrift fur Physik C Particles and Fields》1983,17(3):211-217
The question whether scalar-type interactions contribute to weak interactions at large momentum transfer has been investigated by a measurement of the longitudinal polarization of positive muons produced in charged-current interactions of high-energy antineutrinos with iron. At an average momentum transfer <Q 2>=4 GeV2 the muon spin is found to be oriented forward with respect to the muon momentum vector, with an average polarization of 1.10±0.24, consistent with positive helicity. A limit on scalar contributions of σs, p/σtot <7% at the 95% confidence level can be deduced. A search for violation of time reversal invariance which could manifest itself by a polarization component perpendicular to the muon production plane gave a limit of σtv/σtot <16% (95% c.l.). It is concluded that the weak leptonic charged current retains its dominant vector and axial vector structure at large momentum transfers. 相似文献
8.
U. Amaldi G. Cocconi A.N. Diddens R.W. Dobinson J. Dorenbosch W. Duinker D. Gustavson J. Meyer K. Potter A.M. Wetherell A. Baroncelli C. Bosio 《Physics letters. [Part B]》1977,66(4):390-394
The real part of the proton proton elastic scattering amplitude has been determined from its interference with the Coulomb amplitude at total centre-of-mass energies up to 62 GeV. The observed steady increase of ? with energy indicates that the total proton proton cross section continues to increase well beyond this energy. 相似文献
9.
Lipase from Brevibacillus agri 52 was found stable up to 90% diethylenglycol (DEG), glycerol (GLY), and 1,2 propanediol (1,2 PRO) at 37 degrees C for 1 h and the stability was reduced only approximately 20% after 12 h incubation, but in 40% dimethylsulfoxide (DMSO), lipase activity was stable only for 1 h. Inhibition of the biocatalysts with dimethylformamide (DMF) was detected at 20% solvent concentration. In water immiscible systems, the stability of lipase in n-hexane, n-tetradecane and n-heptane resembles the water activity, but in the presence of isobutanol, 1-hexanol, and butylbutirate, the stability was significantly reduced. Lipase 52 precipitates in the presence of 50% acetone or ethanol/water mixtures, but enzymatic activity was partially recovered by adding 20% GLY, DEG, 1,2 PRO, or DMSO to the reaction mixture. Furthermore, by increasing DEG in 70% DMF/DEG mixtures, the lipase activity was protected. Encapsulation of lipase in pectin gels cross-linked with calcium ions brings three to four times more enzymatic activity in 70% water miscible organic solvents compared to aqueous systems. 相似文献
10.
Theoretical and experimental investigation on the oxidation of gallic acid by sulfate radical anions
Caregnato P Gara PM Bosio GN Gonzalez MC Russo N Michelini Mdel C Martire DO 《The journal of physical chemistry. A》2008,112(6):1188-1194
By monitoring the decay of SO4*- after flash photolysis of aqueous solutions of S2O82- at different pH values, the kinetics of the reaction of SO4*- radicals with gallic acid and the gallate ion was investigated. The bimolecular rate constants for the reactions of the sulfate radicals with gallic acid and the gallate ion were found to be (6.3 +/- 0.7) x 10(8) and (2.9 +/- 0.2) x 10(9) M(-1) s(-1), respectively. On the basis of the oxygen-independent second-order decay kinetics and on their absorption spectra, the organic radicals formed as intermediates of these reactions were assigned to the corresponding phenoxyl radicals. DFT calculations in the gas phase and aqueous solution support formation of the phenoxyl radicals by H abstraction from the phenols to the sulfate radical anion. The observed recombination of the phenoxyl radicals of gallic acid to yield substituted biphenyls and quinones is also supported by the calculations. HPLC/MS product analysis showed formation of one of the predicted quinones. 相似文献