全文获取类型
收费全文 | 75篇 |
免费 | 16篇 |
国内免费 | 20篇 |
专业分类
化学 | 49篇 |
晶体学 | 1篇 |
力学 | 1篇 |
数学 | 10篇 |
物理学 | 50篇 |
出版年
2018年 | 1篇 |
2017年 | 1篇 |
2016年 | 3篇 |
2013年 | 5篇 |
2012年 | 4篇 |
2011年 | 3篇 |
2010年 | 2篇 |
2009年 | 5篇 |
2008年 | 4篇 |
2007年 | 1篇 |
2006年 | 2篇 |
2004年 | 6篇 |
2003年 | 9篇 |
2002年 | 13篇 |
2001年 | 7篇 |
2000年 | 10篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 1篇 |
1993年 | 1篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1989年 | 5篇 |
1988年 | 3篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1983年 | 2篇 |
1982年 | 4篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有111条查询结果,搜索用时 171 毫秒
1.
[reaction: see text] 5,10,15,20-Tetrakis(m-hydroxyphenyl)porphyrin (m-THPP) yielded novel quinonoid porphyrins upon irradiation in aqueous methanol. True photobleaching was observed for 5,10,15,20-tetrakis(m-hydroxyphenyl)chlorin (m-THPC) and 5,10,15,20-tetrakis(m-hydroxyphenyl)bacteriochlorin (m-THPBC) under the same conditions; several fragmentation products (imides, methyl p-hydroxybenzoate, dipyrrin derivatives) were recognized. 相似文献
2.
PHOTOPHYSICAL PROPERTIES OF meso-TETRAPHENYLPORPHYRIN and SOME meso-TETRA(HYDROXYPHENYL)PORPHYRINS 总被引:3,自引:0,他引:3
R. Bonnett D. J. McGarvey A. Harriman E. J. Land T. G. Truscott U-J. Winfield 《Photochemistry and photobiology》1988,48(3):271-276
Abstract— The o-, m-, and p-isomers of 5, 10, 15, 20- tetra(hydroxyphenyl)-porphyrin have been of recent interest as potential second-generation sensitisers in tumour phototherapy. Fluorescence spectroscopy, nanosecond laser flash photolysis and pulse radiolysis have been used to characterise the singlet and triplet excited states of tetraphenylporphyrin and the o, m-, and p-isomers of tetra(hydroxyphenyl)porphyrin. This has included evaluation of fluorescence yields and lifetimes, triplet spectra, lifetimes, oxygen quenching rate constants, extinction coefficients, and yields and singlet oxygen yields. Whilst the fluorescence quantum yields were low, the triplet yields were all 0.7 ± 10% and the singlet oxygen yields 0.6 ± 10%: all these parameters are in the ranges shown by other efficient porphyrin photosensitisers. The similar photophysical properties found for these compounds suggest that their differing tumour sensitising efficiencies are likely to be due to other factors. 相似文献
3.
S. G. Yunusova S. D. Gusakova A. I. Glushenkova U. K. Nadzhimov Sh. Turabekov SA. Musaev 《Chemistry of Natural Compounds》1991,27(2):147-150
A comparative analysis has been made of the amounts of lipids and their fatty-acid compositions in the seeds of the lines of agenetic collection of cotton plants of the speciesGossypium hirsutum and their hybrids and the variety Tashkent-1. The results obtained on the fatty-acid compositions of some hybrids make it possible to recommend the use of individual lines of cotton plants as donors for improving the food-value indices of cottonseed oil.Institute of Chemsitry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. V. I. Lenin Tashkent State University. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 173–176, March–April, 1991. 相似文献
4.
Far-infrared laser magnetic resonance spectra of NHD (X 2A′') (0,0,0) have been observed. Data are presented for the rotational transitions 313 ← 202 and 413 ← 322 observed at wavelengths of 211.3 and 374.1 μm respectively. Theoretical values of the transition magnetic field strengths have been calculated using the best available molecular constants. The agreement between theory and experiment confirms our spectroscopic assignments, but indicates that with further experimental data, considerable refinement of the molecular constants will be obtained. 相似文献
5.
Richard Bonnett Robert G. Guy David Lanigan 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-3):95-103
Abstract Thiocyanogen reacts slowly with alkenes, in the presence of a radical inhibitor in benzene or acetic acid in the dark at 25°, to yield α,β-dithiocyanates, α-isothiocyanates-β-thiocyanates and, in acetic acid, α-acetoxy-β-thiocyanates in varying proportions. The additions to alkyl alkenes are trans-stereospecific, and, in the case of the α-isothiocyanato-β-thiocyanates, non-regiospecific. The additions to aryl alkenes are trans-stereoselective and regiospecific, yielding the Markownikov-orientated α-isothiocyanato-β-thiocyanates. A heterolytic mechanism involving a two-step, kinetically controlled addition, with the formation of a cyano-sulfonium ion intermediate, e.g., 35, in the case of alkyl alkenes and an open carbonium ion, e.g., 36, in the case of aryl alkenes, is suggested. The diothiocyanate: isothiocyanato-thiocyanate ratios are discussed in terms of kinetic and steric control of reaction. 相似文献
6.
Bonnett PE Carpenter KJ Dawson S Davey RJ 《Chemical communications (Cambridge, England)》2003,(6):698-699
In many situations the process of crystallisation from solution is known to occur via metastable crystalline states (polymorphs or solvates). Here we present what we believe to be a novel example of small molecule crystallisation in which the initial separation of a solute rich liquid phase precedes the crystallisation event. We believe this occurs because a submerged liquid-liquid phase boundary is accessible within the metastable zone of the crystal nucleation process. 相似文献
7.
8.
利用溶液聚合和成酰胺反应合成了多功能梳状两亲性共聚物,聚(甲基丙烯酸-co-甲基丙烯酸十八酯)-(乙醇胺-乙二胺叶酸)(PSM-EE-FA).用红外光谱(FTIR),核磁共振(1H-NMR)及凝胶渗透色谱(GPC)表征了该聚合物的结构及分子量分布.实验结果证明合成了该聚合物,其数均分子量(Mn)为28600,多分散性为1.375.用该两亲梳状聚合物包覆油溶性CdSe/ZnS量子点,通过相转移作用,得到水溶性靶向量子点(PSM-EE-FA-QDs).该水溶性量子点溶液具有较好的稳定性.通过紫外-可见(UV-Vis)及荧光发射光谱分析对该量子点的光学性质进行研究.结果表明,PSM-EE-FA-QDs的紫外-可见光谱及荧光发射光谱峰形与原量子点基本一致.由于量子点表面聚合物层的形成,峰位发生少量红移.该量子点水溶液的荧光强度是原量子点氯仿溶液的98%,荧光产率是原量子点氯仿溶液的95%.动态光散射(DLS)及透射电镜(TEM)测试结果表明水溶性量子点分布均匀.合成的水溶性量子点不但光学性能稳定,而且聚合物及水溶性量子点的合成方法较为简便. 相似文献
9.
10.
以LCD为目标的自动定焦判据选择 总被引:2,自引:0,他引:2
在光学综合自动测量中 ,使用液晶显示屏作为分划板可以大大简化结构 ,提高效率 ,真正地实现自动测量。由于液晶显示具有对比度低、噪声大等特点 ,所以根据液晶的这些特点以及图像处理和CCD信号接收的特点选择两种适用的判据进行了分析和试验比较 ,并给出了结果。结果表明 ,这两种判别函数都适用于以液晶显示屏为目标和用图像处理方法进行光学参数测量的系统 ,其中锐度判别函数更优于信息熵判别函数 ,前者具有更好的抗干扰性和稳定性 ,而且其判定结果更接近目视清晰度判别 相似文献