全文获取类型
收费全文 | 130篇 |
免费 | 1篇 |
专业分类
化学 | 94篇 |
力学 | 1篇 |
数学 | 5篇 |
物理学 | 31篇 |
出版年
2022年 | 1篇 |
2021年 | 2篇 |
2020年 | 3篇 |
2019年 | 1篇 |
2018年 | 7篇 |
2017年 | 2篇 |
2016年 | 4篇 |
2014年 | 2篇 |
2013年 | 4篇 |
2012年 | 8篇 |
2011年 | 4篇 |
2009年 | 8篇 |
2008年 | 1篇 |
2007年 | 5篇 |
2006年 | 2篇 |
2004年 | 2篇 |
2003年 | 2篇 |
2002年 | 2篇 |
1999年 | 1篇 |
1992年 | 1篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1984年 | 4篇 |
1982年 | 2篇 |
1980年 | 4篇 |
1979年 | 9篇 |
1978年 | 2篇 |
1977年 | 4篇 |
1976年 | 6篇 |
1975年 | 3篇 |
1974年 | 7篇 |
1973年 | 5篇 |
1972年 | 4篇 |
1971年 | 3篇 |
1970年 | 2篇 |
1969年 | 1篇 |
1968年 | 4篇 |
1967年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有131条查询结果,搜索用时 15 毫秒
1.
Glezer A.M. Blinova E.N. Pozdnyakov V.A. Shelyakov A.V. 《Journal of nanoparticle research》2003,5(5-6):551-560
Journal of Nanoparticle Research - It was shown that the thermoelastic martensite transformation B2 ? B19 inside nanoparticles surrounded by amorphous matrix in Ni–Ti–Cu alloys as... 相似文献
2.
Aniline and pyrrole have been oxidized with ammonium peroxydisulfate in aqueous solutions, in the presence of equimolar quantities of hydrochloric acid. The oxidation of pyrrole was faster; the induction period typical of aniline oxidation was absent in the case of pyrrole. As the proportion of oxidant-to-monomer molar concentration increased up to 1.5, the yield increased in both cases. Similarities between the two oxidations are illustrated and discussed. The oxidant-to-monomer molar ratio 1.25 is proposed to be the optimum stoichiometry, in the accordance with the data published in the literature. The conductivities of the polymers prepared were only slightly dependent on the oxidant-to-monomer ratio in the range 0.3-1.5, and were of the order of 100 S cm−1 for polyaniline and ∼10−2-10−1 S cm−1 for polypyrrole. Outside this interval, the conductivity of both polymers was reduced. Polyaniline having conductivity ∼10 S cm−1 was produced in solutions of phosphoric acid of various concentrations. On the contrary, the conductivity of polypyrrole was reduced as the concentration of phosphoric acid became higher. The type of protonation is discussed with the help of FTIR spectra by analyzing the ammonium salts obtained after deprotonation. Sulfate or hydrogen sulfate anions produced from peroxydisulfate always constitute a part of the counter-ions. 相似文献
3.
Borodina Y Rudik A Filimonov D Kharchevnikova N Dmitriev A Blinova V Poroikov V 《Journal of chemical information and computer sciences》2004,44(6):1998-2009
A new approach is described that is able to predict the most probable metabolic sites on the basis of a statistical analysis of various metabolic transformations reported in the literature. The approach is applied to the prediction of aromatic hydroxylation sites for diverse sets of substrates. Training is performed using the aromatic hydroxylation reactions from the Metabolism database (Accelrys). Validation is carried out on heterogeneous sets of aromatic compounds reported in the Metabolite database (MDL). The average accuracy of prediction of experimentally observed hydroxylation sites estimated for 1552 substrates from Metabolite is 84.5%. The proposed approach is compared with two electronic models for P450 mediated aromatic hydroxylation: the oxenoid model using the atomic oxygen and the model using the methoxy radical as a model for the heme active oxygen species. For benzene derivatives, the proposed method is inferior to the oxenoid model and as accurate as the methoxy-radical model. For hetero- and polycyclic compounds, the oxenoid model is not applicable, and the statistical method is the most accurate. Broad applicability and high speed of calculations provide the basis for using the proposed statistical approach for high-throughput metabolism prediction in the early stages of drug discovery. 相似文献
4.
Quantum yields () for the generation of singlet oxygen sensitized by Pd(II) complexes of water-soluble porphyrins: meso-tetrakis(4-N-methylpyridyl)porphine [PdTMPyP]4+ ( = 0.9), meso-tetrakis(4-N,N,N-trimethylaminophenyl)porphine [PdTTMAPP]4+ ( = 0.8), meso-tetrakis(4-carboxyphenyl)porphine [PdTCPP]4– ( = 0.7), and meso-tetrakis(4-sulfonatophenyl)porphine [PdTSPP]4– ( = 0.5) were determined using a chemical method. It was found that the dimerization and aggregation of metalloporphyrins greatly influence the value. The quantum yields evaluated for the formation of singlet oxygen sensitized by metalloporphyrin monomeric and dimeric forms are , M 0.9 and , D 0.2, respectively, and do not depend on the porphyrin nature. 相似文献
5.
6.
7.
I. V. Blinova I. Yu. Popov M. M. Sandler 《Russian Journal of Mathematical Physics》2007,14(4):388-396
A continuous model of the Sierpinski gasket (SG) is suggested. The Laplace operator on the SG is defined. An effective computational
algorithm for solving the scattering problem is suggested. The self-similarity of the graph of transmission coefficient via
the wave number k is observed. A violation of symmetry of the SG is considered. The results are compared with the discrete SG model.
In memoriam V. A. Geyler 相似文献
8.
9.
10.
Dehydrochlorination of polychloroalkanes and 1,1-diaryl-2,2-dichloroethanes by the action of Mo(CO)6
N. V. Blinova N. A. Kuz'mina E. Ts. Chukovskaya L. V. Vakhtagishvili A. L. Rusanov 《Russian Chemical Bulletin》1988,37(8):1609-1612
Conclusions Chloroolefins or -chlorostilbenes were synthesized by the dehydrochlorination of polychloroalkanes or 1,1-diaryl-2,2-dichloroethanes catalyzed by Mo(CO)6.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1803–1806, August, 1988. 相似文献