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Electrical resistivity of U3Tein4, U2Te3 (cubic) and UTe3 has been measured over temperature range 4.2–300 K. The two former compounds appear to be semimetallic conductors while the last one has semiconducting character. The results are discussed in the terms of available magnetic data. 相似文献
4.
Abstract During these last twenty five years a great efforts have been made in the Laboratoire de Chimie du Solide du CNRS in order to develop high oxygen pressure for the stabilization of unusual oxidation state of transition elements. The aims of such research works was to correlate the increase of the Mn+-O bond covalency versus the increase of the oxidation state n+ to the physicochemical properties of resulting oxides [1]. Iridium was an interesting element due to its position (5d) in the Periodic Table. In 1980 Ir(V) (d4) was stabilized in La2LiIrO6 in the perovskite structure [2]. Such a study had underlined the strong value of the spin-orbit coupling associated to Ir(V) [3]. The stabilization of Ir(VI) is interesting from two points of view : (i) its isotropic electronic configuration (d3), (ii) such a high oxidation state could lead to the strongest M-O bond in an oxygen lattice. Selecting, through a specific methodology, the most appropriate local structural and chemical factors and with the help of high oxygen pressure, Ir(V1) was stabilized in the perovskite Ba2CaIrO6. Structural, magnetic and Mössbauer studies have been carried out in order to characterize the physicochemical properties induced by this unusual oxidation state. 相似文献
5.
Q. Liu B. Poumellec C. Haut D. Dragoe R. Blum G. Girard J.-E. Bourée A. Kudlinski Y. Quiquempois G. Blaise 《Applied Physics A: Materials Science & Processing》2005,81(6):1213-1219
Amorphous N- or Ge-doped H:SiO2 films deposited on silica by the matrix distributed electron cyclotron resonance-PECVD method were irradiated by an electron-beam with different doses in order to pole the material and induce second harmonic generation (SHG). SHG was measured using the Maker-fringe method. When irradiated at an acceleration voltage of 25 kV, an incident current of 5 nA during 480 s, the N-doped H:SiO2 films exhibited a maximum second harmonic signal in the order of 0.003 pm/V, but when irradiated with an acceleration voltage of 30 kV, at 5 nA during 240 s, the films exhibited a maximum second harmonic signal of 0.006 pm/V. With a smaller current of 0.5 nA during 25 s and 25 kV acceleration voltage, the Ge-doped H:SiO2 films (3.8 at. % Ge) showed a maximum second-order nonlinearity of 0.0005 pm/V. But an H:SiO2 films with a smaller Ge content (1.0 at. % Ge), showed a large SHG: d33=0.09 pm/V when irradiated at 25 kV, 0.5 nA during 15 s. PACS 78.66.J; 42.65.K; 68.60.D 相似文献
6.
Basavarajeshwari M. Baraker Blaise Lobo 《Journal of Thermal Analysis and Calorimetry》2018,132(2):879-893
Core/shell composites of CuC2O4·2H2O@AP and ZnC2O4·2H2O@AP were prepared from metal oxalates on suspended AP particles in ethanol. CuO and ZnO nano-metal oxides as the nano-catalysts were made from CuC2O4·2H2O and ZnC2O4·2H2O simultaneously by thermal decomposition of AP. The particle size of CuO nano-particles was very finer, and the ZnO particles showed a considerable growth during formation. The kinetic triplet of activation energy, frequency factor, and model of thermal decomposition of pure AP, CuC2O4·2H2O@AP, and ZnC2O4·2H2O@AP composites were estimated by applying three model-free (FWO, KAS, and Starink) and model-fitting (Starink) methods. Based on the thermal analysis, the CuC2O4@AP composite has better catalytic performance and the thermal decomposition temperature of AP decreased to about 126.44 °C. 相似文献
7.
The synthesis of mixed alcohols (C1-C5) from syngas has been studied at 6. 0 MPa over modified Co/CuLaZr catalysts. The molybdenum addition enhanced greatly the activity and the selectivity to alcohols. The improvement of hydrogenation capacity of the system via a reversible spillover effect of hydrogen could explain this effect, together with a great capacity of CO insertion, illustrated by the effect of C2H4 addition as a probe to syngas. Under our experimental conditions, a mixed alcohol production of 147.1g/kg. cat/h containing a proportion of 33. 1% of higher alcohols (C2 OH) was obtained with a selectivity to ROH of 52. 8%. 相似文献
8.
This paper reports a new, simple, rapid and economical method for routine determination of 24 amino acids and biogenic amines in grapes and wine. No sample clean-up is required and total run time including column re-equilibration is less than 40min. Following automated in-loop automated pre-column derivatisation with an o-phthaldialdehyde, N-acetyl-l-cysteine reagent, compounds were separated on a 3mm×25cm C(18) column using a binary mobile phase. The method was validated in the range 0.25-10mg/l; repeatability was less than 3% RSD and the intermediate precision ranged from 2 to 7% RSD. The method was shown to be linear by the 'lack of fit' test and the accuracy was between 97 and 101%. The LLOQ varied between 10μg/l for aspartic and glutamic acids, ethanolamine and GABA, and 100μg/l for tyrosine, phenylalanine, putrescine and cadaverine. The method was applied to grapes, white wine, red wine, honey and three species of physalis fruit. Grapes and physalis fruit were crushed, sieved, centrifuged and diluted 1/20 and 1/100, respectively, for analysis; wines and honeys were simply diluted 10-fold. It was shown using this method that the amino acid content of grapes was strongly correlated with berry volume, moderately correlated with sugar concentration and inversely correlated with total acidity. 相似文献
9.
Blaise Heider 《代数通讯》2013,41(5):2156-2162
To describe the representation theory of the quantum Weyl algebra at an lth primitive root γ of unity, Boyette, Leyk, Plunkett, Sipe, and Talley found all nonsingular irreducible matrix solutions to the equation yx ? γxy = 1, assuming yx ≠ xy. In this note, we complete their result by finding and classifying, up to equivalence, all irreducible matrix solutions (X, Y), where X is singular. 相似文献
10.
Blaise Faugeras Jé rô me Pousin Franck Fontvieille. 《Mathematics of Computation》2006,75(253):209-222
A numerical scheme based on an operator splitting method and a dense output event location algorithm is proposed to integrate a diffusion-dissolution/precipitation chemical initial-boundary value problem with jumping nonlinearities. The numerical analysis of the scheme is carried out and it is proved to be of order 2 in time. This global order estimate is illustrated numerically on a test case.