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排序方式: 共有794条查询结果,搜索用时 15 毫秒
1.
Homogeneously prepared tosylcelluloses (TC) with degrees of substitution (DS) of DSTos 0.1–1.8 were used as intermediates for the synthesis of methylaminocelluloses (MAC) by nucleophilic substitution with methylamine. TC with DSTos up to 1.1 were shown to be valuable intermediates for selective synthesis of MAC with DSMA varying from 0.1 to approximately 1. No nucleophilic substitution was observed at higher DSTos. At the chosen reaction conditions (60 °C, 48 h) residual tosyl moieties remained unchanged and little hydrolysis took place. The samples obtained were characterized by means of elemental analysis, FTIR and 13C CP/MAS NMR spectroscopy. 13C CP/MAS NMR spectroscopy was found to be an efficient tool for quantification of DSMA. Furthermore, the swelling behaviour in water was investigated and preliminary tests concerning the bilirubin adsorption capacity of MAC were carried out. 相似文献
2.
The analysis of barbiturates in human serum (or plasma) and urine by high-performance capillary electrophoresis-electrokinetic capillary chromatography with on-column fast-scanning multi-wavelength detection is discussed. The use of a buffer of ca. pH 8 and containing sodium dodecyl sulphate provides a medium suitable for fast and high-resolution separations of barbiturates. Seven barbiturates are characterized by their retention and absorption spectra between 195 and 320 nm. Comparison of these computer-stored data with those of unknown samples is shown to allow the identification of barbiturates in samples of patients undergoing pharmacotherapy and in toxicological urine and serum specimens. Three-dimensional electropherograms provide reliable information on the requirement and suitability of sample pretreatment procedures. With urine, extraction of barbiturates prior to analysis is necessary. With human serum several barbiturates, including phenobarbital, are shown to elute in an interference-free window in front of uric acid and the proteins, allowing these substances to be determined by direct sample injection. The need for multi-wavelength detection over a relatively wide wavelength range as a means of peak confirmation in electrokinetic capillary analyses is demonstrated and limitations of this technique for compounds with similar retention behaviour and absorption spectra are discussed. 相似文献
3.
W.P. RDZANEK JR 《Journal of sound and vibration》2002,249(2):307-323
The standardized mutual active and reactive sound power of a clamped plate, representing the energy aspect of the reciprocal interactions of two different in vacuo modes, has been computed. It was assumed that the vibrations are axisymmetric, elastic and time harmonic, the plate's transverse deflection is small as compared with the plate's size, and that the vibration velocity is small as compared with the acoustic wavenumber generated. The Kirchhoff-Love theory of a perfectly elastic plate was used. The integral formulae for the mutual sound power were transformed into their Hankel representations which made possible their subsequent computation. A closed path integral was used to express the integral in its Hankel representation to compute the mutual active sound power. The asymptotic stationary phase method was used to compute the two magnitudes, i.e., the mutual active and reactive sound power. The results obtained are the asymptotic formulae valid for the acoustically fast waves. The oscillating as well as the non-oscillating terms have been identified in the formulae to make possible their further separate analysis. The availability of the asymptotic formulae makes possible some fast numerical computations of the mutual sound power. Moreover, the formulae presented herein, together with those for the individual modes known from the literature, make a complete basis for further computations of the total sound power of the plate's damped and forced vibrations in fluid. 相似文献
4.
P. -M. Binder 《Journal of statistical physics》1992,67(3-4):827-832
Average first-passage times for a single-variable stochastic model with a critical fixed point at the origin are computed by exact enumeration. The numerical measurements show excellent agreement with analytical results. The scaling function approaches the predicted asymptotic dependence. 相似文献
5.
We show that if a polynomial filled Julia set has empty interior, then it is computable. 相似文献
6.
M. Reuhl P. Nielaba K. Binder 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,2(2):225-232
,Static and dynamic properties of the Potts model on the simple cubic lattice with nearest neighbor -interaction are obtained from Monte Carlo simulations in a temperature range where full thermal equilibrium still can be
achieved (). For a lattice size L
= 16, in this range finite size effects are still negligible, but the data for the spin glass susceptibility agree with previous
extrapolations based on finite size scaling of very small lattices. While the static properties are compatible with a zero
temperature transition, they certainly do not prove it. Unlike the Ising spin glass, the decay of the time-dependent order
parameter is compatible with a simple Kohlrausch function, , while a power law prefactor cannot be distinguished. The Kohlrausch exponent y
(
T
) decreases from at [0pt] to at [0pt] however. The relaxation time is compatible with the exponential divergence postulated by McMillan for spin glasses at their lower critical dimension,
but the exponent that can be extracted still differs significantly from the theoretical value, . Thus the present results support the conclusion that the Potts spin glass in d
= 3 dimensions differs qualitatively from the Ising spin glass.
Received: 8 October 1997 / Accepted: 27 November 1997 相似文献
7.
Christian Kluger Wolfgang H. Binder 《Journal of polymer science. Part A, Polymer chemistry》2007,45(3):485-499
Block copolymers on basis of poly(oxanorbornenes) bearing functional moieties in their side‐chains are prepared via a combination of ROMP‐methods and 1,3‐dipolar‐“click”‐reactions. Starting from N‐substituted‐ω‐bromoalkyl‐oxanorbornenes and alkyl‐/perfluoroalkyl‐oxanorbornenes, block copolymers with molecular weights up to 25,000 g mol?1 were generated. Subsequent nucleophilic exchange‐reactions yielded the block‐copolymers functionalized with ω‐azidoalkyl‐moieties in one block. The 1,3‐azide/alkine‐“click” reactions with a variety of terminal alkynes in the presence of a catalyst system consisting of tetrakis(acetonitrile)hexafluorophosphate copper(I) and tris(1‐benzyl‐5‐methyl‐1H‐ [1,2,3]triazol‐4‐ylmethyl)‐amine furnished the substituted block copolymers in high yields, as proven by NMR‐spectroscopy. The resulting polymers were investigated via temperature‐dependent SAXS‐methods, revealing their microphase separated structure as well as their temperature‐dependent behavior. The presented method offers the generation of a large set of different block‐copolymers from only a small set of starting materials because of the high versatility of the “click” reaction, thus enabling a simple and complete functionalization after the initial polymerization reaction. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 485–499, 2007 相似文献
8.
F. Rampf K. Binder W. Paul 《Journal of polymer science. Part A, Polymer chemistry》2006,44(18):2542-2555
We present simulation results for the phase behavior of a single chain for a flexible lattice polymer model using the Wang-Landau sampling idea. Applying this new algorithm to the problem of the homopolymer collapse allows us to investigate not only the high temperature coil–globule transition but also an ensuing crystallization at lower temperature. Performing a finite size scaling analysis on the two transitions, we show that they coincide for our model in the thermodynamic limit corresponding to a direct collapse of the random coil into the crystal without intermediate coil–globule transition. As a consequence, also the many chain phase diagram of this model can be predicted to consist only of gas and crystal phase in the limit of infinite chain length. This behavior is in agreement with findings on the phase behavior of hard-sphere systems with a relatively short-ranged attractive square well. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2542–2555, 2006 相似文献
9.
Wolfgang H. Binder Laura Petraru Robert Sachenshofer Ronald Zirbs 《Monatshefte für Chemie / Chemical Monthly》2006,137(7):835-841
Summary. The surface modification of nanoparticles via azide/alkine-1,3-dipolar cycloaddition-reactions is described. Ligand exchange onto various nanoparticles was monitored by
1H NMR spectroscopy and formed the basis for the attachment of ligands onto the nanoparticles and their subsequent modification
by dipolar cycloaddition reactions. Nanoparticle-surfaces were monitored by binding onto self-assembled monolayers derivatized
with matching supramolecular interactions after derivatization. 相似文献
10.
The analogue of the Edwards-Anderson model for isotropic vector spin glasses, but taking three-component quadrupoles instead of spins at each lattice site, is studied on the square lattice with extensive Monte Carlo calculations, using a nearest-neighbor symmetric gaussian interaction.It is shown that at low temperaturesT the model develops a short range order both with respect to glass like correlations and with respect to ferromagnetic correlations among the quadrupoles. The associated correlation lengths and susceptibilities diverge asT0, and the critical exponents for this zero-temperature phase transition are estimated.Dynamic correlation functions are analyzed as well and it is shown that the dacay of spatially displaced correlations displays a Kohlrausch-Williams-Watts behavior similar to the self-correlation function of the quadrupole moments.Some quantities are compared to their corresponding counterparts on the threedimensional simple cubic lattice, which also has a zero-temperature transition but at corresponding temperatures has stronger short-range-order. 相似文献